Progress in additive manufacturing on new materials: A review

Recent efforts and advances in additive manufacturing (AM) on different types of new materials are presented and reviewed. Special attention is paid to the material design of cladding layers, the choice of feedstock materials, the metallurgical behavior and synthesis principle during the AM process, and the resulted microstructures and properties, as well as the relationship between these factors. Thereafter, the trend of development in the future is forecasted, including: Effects of the particles size and size distribution of powders; Approaches for producing fine microstructures; Opportunities for creating new materials by AM; Wide applications in reconditioning of damaged components; Challenges for deep understanding and applications of the AMed new materials. The idea of “Develop Materials” or “Create Materials” by AM is highlighted, but a series of scientific, technological and engineering problems remain to be solved in future.     

2.5D机织复合材料经向和纬向振动疲劳行为对比

2.5D机织复合材料抗分层、耐冲击,在航空发动机结构上具有巨大的应用前景。本文对一种2.5D机织碳纤维增强双马树脂基复合材料经向和纬向试件,开展了不同名义应力水平下的一阶弯曲共振疲劳试验。试验结果表明：经向试件的振动疲劳性能优于纬向试件,随着应力水平的提高,经向和纬向试件的寿命明显缩短,而固有频率下降百分比增加,试件内部的损伤严重程度和损伤扩展速度都随之提高。2.5D机织复合材料经向和纬向试件在共振疲劳试验过程中的主要失效模式是纱线与基体之间脱粘造成的结构完整性丧失,从而导致试件的刚度持续下降。试件内部损伤的三维电子计算机断层扫描(Computerized tomography,CT)重构图像表明,损伤散布于试件工作段区域,应力水平越高,2.5D机织复合材料经向和纬向试件内部损伤范围越大,损伤程度越高,而且纬向试件内部损伤状态比经向试件严重。利用双对数线性寿命模型,对经向和纬向试件在不同名义应力水平下的共振疲劳试验数据进行拟合,得到2.5D机织复合材料经向和纬向试件共振疲劳应力-寿命(Stress-life,S-N)曲线的数学模型,得到的S-N曲线可用于预测2.5D机织复合材料的寿命。     

天然橡胶的疲劳特性研究进展

叙述了天然橡胶的疲劳特性，着重归纳了天然橡胶的破坏机理及影响其疲劳破坏的主要因素。     

Effects of submicron diamonds on the growth of copper in Cu-diamond co-deposition

Submicron diamonds were co-deposited on aluminum substrates with copper from the acid copper sulfate electrolyte by electrolyte-suspension co-deposition.After submicron diamonds were added to the electrolyte,the shape of copper grains transformed from oval or round to polyhedron,the growth mode of copper grains transformed from columnar growth to gradual change in size,and the preferred orientation of copper grains transformed from (220) to (200).Analyzing the variation of cathodic overpotential,it was found that the cathodic overpotential tended to remain unchanged when copper plane (220) grew in the process of electrodepositing pure copper,while it tended to decrease with time when copper plane (200) grew m the process of co-deposition.It was inferred that copper plane (200) was propitious to the deposition of submicron diamonds.     

均匀化和均匀化后处理对GH742合金γ′相的影响

采用电子探针(EPMA)对GH742铸锭未经任何处理和均匀化后两种状态下的主要合金元素做了定量分析,并使用SEM扫描电镜对GH742铸锭三种不同状态下γ′相作了比较.结果表明:铸锭原始态存在偏析,γ′相在枝晶间和枝晶干处形状、尺寸差别较大,总体上尺寸较小;经均匀化后无粗大γ′相存在;均匀化后特殊处理部分γ′相尺寸增大,热加工塑性有明显提高.     

Fatigue crack growth property of laser beam welded 6156 aluminium alloy

Fatigue crack growth behaviours in different welding zones of laser beam welded specimens were investigated using central crack tension specimens for 6156 aluminium alloy under constant amplitude loading at nominal applied stress ratio R = 0.5, 0.06, ?1. The experimental results showed that base metal (BM) exhibited superior fatigue crack resistance compared to weld metal (WM) and heat‐affected zone (HAZ). Crack growth resistance of WM was the lowest. The exponent m values for BM and HAZ at different stress ratios are close and around 2.6, while m for WM at different stress ratio is around 4.7. The discrepancy between crack growth rates for WM and BM is more evident with increasing stress ratio, while it is a little change for HAZ and BM. Change of the microstructure in WM deteriorates the resistance of fatigue crack growth compared to BM. It was mainly due to grain boundary liquation and dissolving of second‐phase particles in the weld region. It was also found that the variety of fatigue crack resistance for different welding zones is in conformity with the change of hardness. BM with the highest hardness exhibited the maximum resistance for fatigue crack, and WM with the lowest hardness exhibited the minimum fatigue crack resistance.     

水淘洗法分离镍基高温合金粉末中陶瓷类夹杂物

详细介绍了水淘洗方法分离固体颗粒的原理,从实践上建立了镍基高温合金粉末陶瓷类夹杂物的分级分离法,进行实验验证,并分析了水淘洗方法的可靠性。     

Sensitivity of a solid Eu(III) complex towards acetonitrile vapor: Structural and spectroscopic characterization

The Eu(III) nitrate complex of the meso- N,N′-bis(2-pyridylmethylene)-1,2-(R,S)-cyclohexanediamine ligand was synthesized and characterized by single crystal and powder X-ray diffraction. The crystal lattice of the complex is capable of absorbing and desorbing selectively acetonitrile molecules, at 293 K upon an acetonitrile vapor pressure of ∼0.1 × 10⁵ Pa. This process, which is partially reversible, can be easily followed by both powder X-ray diffraction (P-XRD) and Eu(III) luminescence spectroscopy. The acetonitrile molecule, located in the outer coordination sphere of the metal ion, does not affect the radiative transition probability of ⁵D₀ level of Eu(III) and also it does not activate further non-radiative channels from this level. On the other hand, this molecule is capable of affecting the energy position and intensities of the crystal field components of the ⁵D₀→⁷F₂ transition. The complex in solid form can be considered a promising material for the optical sensing of acetonitrile vapors.     

梦·热处理

评述了钢中马氏体相变、铝合金中时效析出相变、高温合金表层组织再造改性微观机理研究进展,及其对先进热处理发展的推动作用。认为先进热处理赋予材料极限性能和构件极限服役行为,是先进材料和高端机械制造的核心技术。转变观念,快速、高效发展先进热处理,是发展先进材料和高端制造、建设材料和机械制造强国的必由之路。提出了中国热处理技术发展路线图架构设想。