Thermodynamic modeling of Cr–Nb and Zr–Cr with extension to the ternary Zr–Nb–Cr system

The total energies of Laves phases in the Cr–Nb and Zr–Cr systems have been calculated by the pseudo-potential VASP code with a full relaxation of all structural parameters. The special quasirandom structures (SQSs) have been constructed and their total energies have been calculated by the VASP code to predict the enthalpies of mixing for bcc and hcp solid solution phases. The phonon calculations for the C14 and C15 Laves phases have been performed to analyze the phase stability at elevated temperatures. The experimental study on the Zr–Cr system has been carried out at different temperatures to determine the phase boundaries. Based on these results, thermodynamic models of Cr–Nb and Zr–Cr with extension to the ternary Zr–Nb–Cr systems have been developed in this work by using the CALPHAD approach.     

Hydrothermal synthesis of 3D NixCo1−xS2 particles/graphene composite hydrogels for high performance supercapacitors

In this work, three dimensional (3D) Ni_xCo_1−xS₂/graphene composite hydrogels with different Ni contents (denoted as Ni_xCo_1−xS₂/GH (x = 0, 0.31, 0.56, 0.66, 1)) have been synthesized by a simple one-step hydrothermal method and utilized as the active materials of supercapacitors. The as-prepared samples present a 3D interconnected porous network with the pore sizes in the range of several to tens micrometers. Interestingly, the Ni_xCo_1−xS₂ particles are uniformly located on the graphene network and the particle size is evolved from ∼50 nm to ∼1.5 μm with the increase of Ni content. The electrochemical measurements revealed that the specific capacitance, rate capability and cyclability of different Ni_xCo_1−xS₂/GH electrodes are strongly affected by their different Ni content. Among these, the 3D Ni_0.31Co_0.69S₂/GH composite has the highest specific capacitance of 1166 F/g at a current density of 1 A/g. Furthermore, a specific capacitance of 559 F/g can be still maintained at high current density of 20 A/g. After 1000 charge–discharge cycles at 5 A/g, the specific capacitance remains a high value of 755 F/g.     

基于储能型柔性多状态开关的直流微电网与交流配电网柔性互联策略

柔性多状态开关大多采用"刚性"的变流控制策略,导致其端口惯性与阻尼不足,直流微电网通过其接入时难以与交流配电网进行柔性互联,无法响应交流配电网调频调压.为此,提出一种基于储能型柔性多状态开关的直流微电网与交流配电网柔性互联策略,交直流端口统一采用虚拟电机控制,通过模拟电机的惯性和阻尼特性使交直流端口呈现柔性特性,同时针对馈线负荷不均衡问题提出一种考虑直流微电网功率交互的负荷均衡策略.仿真结果表明,所提策略能够降低直流微电网波动对交流配电网的冲击,增强直流母线电压的稳定性,主动响应交流配电网调频调压,实现了馈线负荷均衡,提升了柔性多状态开关的调控灵活性.     

乳液共混法制备水性阻尼涂料

通过乳液共混法将不同Tg的丙烯酸酯乳液进行共混,并加入填料和助剂配制成涂料。动态力学谱结果表明,当乳液按照丙烯酸乳液与苯乙烯-丙烯酸酯乳液比为40∶10共混时,阻尼温域得以拓宽,并达到Tg与室温一致的使用温域。     

一种拟合误差驱动的自适用隐式曲面重建算法

针对散乱数据,提出一种拟合误差驱动的自适应隐式曲面重建算法。算法根据二次曲面的拟合误差进行自适应拟合,改变了传统方法从八叉树中顶层节点开始拟合,减少了拟合次数,加快了重建速度;并修正权函数,加入密度函数,削弱由于散乱数据密度的不一致对重建曲面影响。实验结果表明,该算法原理简单,重建速度快,重建效果良好。     

不同填充率时三组元声子晶体缺陷态

运用基于平面波的超元胞方法,研究作为缺陷引入第三组元材料(四氯化碳)对二维二组元声子晶体(水/水银)带结构的影响。结果表明:当缺陷柱填充率发生变化时,原带隙的位置、宽度变化不大;缺陷带频率主要受第三组元材料物性参数的影响;当正常插入体填充率发生变化时,原带隙的位置、宽度都发生了改变,同时也影响缺陷带的出现,且这些缺陷态都是局域化的。因此,在具有宽带隙的二组元体系中引入适当的第三组元线缺陷,让缺陷带频率落在二组元体系的带隙中,就可以形成特殊的波导态。声子晶体的这一特性对于声波/弹性波的传播和新的声学应用具有重要意义。     

纸质基材抗菌包装及性能研究

以纳米银为抗菌剂、聚乙烯醇为黏结剂处理普通成纸,制备了包装用抗菌纸。采用抑菌圈法评价了该抗菌纸对大肠杆菌的抑制效果,研究了聚乙烯醇和纳米银的含量对抗菌纸抗菌性能、抗张强度和伸长率的影响。结果表明:抗菌纸的抗张强度及伸长率均能满足包装需求,且具有良好的抗菌性能,其抗菌效果随纳米银和聚乙烯醇含量的增加而增强。     

芯子开槽工艺对蜂窝纸板缓冲性能的影响

为解决蜂窝纸板初始缓冲性能差、干燥速度慢、易发霉等问题,对蜂窝纸芯采用开槽工艺处理,在不显著降低蜂窝纸板平压强度的前提下,尽可能地改善其缓冲性能。采用正交试验方法对30 mm厚蜂窝纸板进行静态压缩试验,以考察芯子槽形的宽度、深度和槽间距3个工艺参数对蜂窝纸板性能的影响。实验结果表明:当采用槽宽2.5 mm、槽深3 mm、槽间距32 mm的开槽方式时,蜂窝纸板具有较优的抗压与缓冲综合性能。