Growth,mechanical properties,and tribological performance of TiAlN/NbN and NbN/TiAlN bilayer coatings

Three different coatings, namely TiAlN, TiAlN (external)/NbN (internal) and NbN (external)/TiAlN (internal), were deposited on cemented carbides by arc ion plating. The comparative investigation conducted in this study elucidates the effect of the NbN layer and coating systems on the growth, mechanical properties, and tribological performance of the coatings. The results showed that the surface of the TiAlN and TiAlN/NbN coatings was smoother when TiAlN served as the external layer. The NbN/TiAlN coating, wherein NbN formed the external layer, had a much rougher but more symmetrical surface. With the introduction of the NbN layer, the increased micro stress induced a lower adhesion strength in the TiAlN/NbN and NbN/TiAlN coatings. The TiAlN/NbN and NbN/TiAlN coatings exhibited higher hardness and hardness/effective elastic modulus (H/E*). During the friction test, when the temperature was elevated to 700 °C, the tribological performance of the monolayer TiAlN coating was the lowest because of the TiO₂-induced breakage of the dense tribo-oxide film. The NbN layer participated in the formation of a NbO_x film at elevated temperatures, which was responsible for the high tribological performance of the two bilayer coatings. When the NbN layer was on the outermost layer and in direct contact with the elevated temperature atmosphere, the NbN/TiAlN coating generated a tribo-oxide film with high integrity, and its coefficient of friction decreased by 27% of that at room temperature. Therefore, the NbN/TiAlN coating exhibited the highest wear resistance at 700 °C.     

Influence of SiO2 and CaO additions on the microstructure and magnetic properties of sintered Sr-hexaferrite

The effect of simultaneous addition of CaO and SiO₂ on the microstructure and magnetic properties of sintered SrO-excess Sr-hexaferrites was studied. Both additives markedly affect the grain growth behavior and the magnetic properties. CaO-additions promote densification, which results in increased remanence, but due to simultaneuous grain growth the coercivity drops to <100 kA/m. SiO₂ additions are known to suppress grain growth. Simultaneous addition of CaO and SiO₂ is shown to be very beneficial in tailoring a dense microstructure with relatively small grains. The ratio of CaO/SiO₂ was found to be optimum at about 1, and magnets with a remanence of 430 mT and a coercivity of 300 kA/m were obtained. Transmission electron microscopy (TEM) studies and investigations by energy-dispersive analysis of X-rays (EDX) in the scanning TEM (STEM) mode show that both CaO and SiO₂ are concentrated at grain boundaries and grain junctions forming an amorphous secondary phase.     

UO2-Gd2O3芯块密度的影响因素研究

对UO2-Cd2O3可燃毒物芯块密度的影响因素进行了详细研究。试验表明：烧结时间、烧结温度、生坯密度、Gadox（含Gd的U3O8）、A．O（草酸铵）等条件与UO2-Gd2O3芯块密度存在一定关系。     

混流,定浆式转轮特性参数的计算机处理

本文根据混流、定浆式转轮特性多数的特点建立了一种能将高维特性多数用一个具有二阶连续导数且保形的函数给予表达的方法，它的精度高，且能方便生成满足各种用途的特性曲线。     

Noble metal water gas shift catalysis: Kinetics study and reactor design

Based on the water gas shift (WGS) catalytic mechanism on precious metal catalyst, a Langmuir–Hinshelwood (LH) kinetics model was derived for the operating conditions of syngas from natural gas reforming at near-ambient pressure. A power law kinetics model was also presented for comparative purpose. These two kinetics models were integrated in a dynamic distributed reactor model for design of full-scale WGS reactors for a natural gas fuel processing system. Modeling results indicated that the LH kinetics model gives predictions of reactor performance closer to the experimental data. Using the LH kinetics model, optimization of operating conditions for the high-temperature shift (HTS) and low-temperature shift (LTS) reactors was also attempted.     

利用开源系统优化数字图书馆的高级应用

在信息急剧膨胀的今天,中国图书馆界已跨入数字图书馆阶段,但图书馆的技术力量相对薄弱,其服务手段和技术仍不能满足需要速成服务的读者,数字图书馆不能仅仅以搜索框的形式被动出现,图书馆人必须改善条件,应用新的技术来应对新的需求。本文将介绍一种技术:Drupal,并在此基础上优化数字图书馆的高级应用。     

基于BP网络模型的水合肼合成收率预测及参数优杞

采用BP算法建立了水合肼合成收率的神经网络模型，所建网络有良好的回想和泛化性能，对水合肼合成收率预测的平均相对误差小于0．5％。运用网络模型考察了反应温度、物料配比、次氯酸钠流量等操作参数对水合肼合成收率的影响，同时确定了获得较高合成收率时各操作参数的优化值。     

炭纤维载体表面快速固着机理研究

采用炭纤维作为生物膜载体材料进行了污水处理实验,对炭纤维载体表面快速固着机理进行了研究。研究发现,炭纤维能够在水中快速且大量的固着活性污泥微生物。采用表面积测定仪、扫描电镜和XPS研究了炭纤维的表面特征。结果显示,炭纤维的表面形貌、表面官能团及表面活性碳原子是影响炭纤维表面微生物快速且大量固着的主要因素。     

种模拟电路参数型故障诊断新方法

模拟电路参数型故障诊断一直是电路与系统无法回避的难题。该文基于被测电路主输出电压信号的时间序列值,建立了一种基于本征值和相位差的模拟电路参数型故障诊断模型。该模型利用故障电路的电压输出时间序列值获取电路的故障相位偏移信息,同时,该模型把电压时间序列变换成一个方阵,并求取该方阵的最大本征值。将故障相位偏移信息和故障最大本征值与通过前期仿真获得的每种器件相对应的无故障最大相位偏移和无故障最大本征值的变化趋势进行比较,实现故障定位和参数辨识。实测实验结果表明:该方法具有定位准确、计算效率高,所需测试点少、参数辨识精度高,易于工程实施等优点。