Synergistic inhibition between o-phenanthroline and chloride ion for steel corrosion in sulphuric acid

The corrosion inhibition of cold rolled steel in 0.5 M sulphuric acid in the presence of o-phenanthroline and sodium chloride (NaCl) has been investigated by using weight loss and electrochemical techniques. The experimental data suggest that the inhibition efficiency increases with increasing NaCl concentration in the presence of 0.0002 M o-phenanthroline, but decreases with increasing temperature. A synergistic effect is observed when o-phenanthroline and chloride ions are used together to prevent cold rolled steel corrosion in 0.5 M sulphuric acid. The polarization curves showed that the complex of o-phenanthroline and NaCl acts as a mixed type inhibitor. The experimental results suggested that the presence of chloride ions in the solution stabilized the adsorption of o-phenanthroline molecules on the metal surface and improved the inhibition efficiency of o-phenanthroline. The adsorption of the complex accords with the Langmuir adsorption isotherm. Some thermodynamic parameters such as adsorption heat, adsorption entropy and adsorption free energy have been calculated by employing thermodynamic equations. Kinetic parameters such as apparent activation energy and pre-exponential factor have been calculated and discussed.     

云荞水库面板堆石坝震后安全检测及整治研究与实践

云南省永善县云荞水库自建成蓄水以来运行良好,2008年5月12日,四川省汶川县发生8.0级地震,云荞水库震感强烈,水库内水浪约1.0m高,水库受损,面板裂缝加大;震后云荞水库工程管理局高度重视云荞水库的安全问题,特请某水利水电勘测设计研究院对面板进行健全性检测,管理局根据检查单位对大坝面板的整体性能做出的评价及提出相应的处理意见,对面板裂缝进行了化学灌浆和表面封闭处理,至今运行良好。     

煅烧温度对ATO/TiO2粉体表面晶化及电导率的影响

用湿化学法在TiO2颗粒表面包覆ATO制得ATO/TiO2复合导电粉;运用TG-DSC、XRD、XPS、SEM、和电导率测试等手段对ATO/TiO2导电粉进行了表征.结果表明:煅烧温度对SnO2的晶化程度、Sb的价态、ATO/TiO2导电粉的导电性产生影响.电导率-温度(lnσ-T)关系呈抛物线(100～900℃):上坡段(150～400℃),温度增加,无定形SnO2逐渐晶化,电导率增加,导电性上升,溶入SnO2的Sb3+→Sb5+转变,载流子浓度加大,包膜层多孔结构逐渐致密化;底部平台(400～600℃),SnO2晶化结束,Sb3+→Sb5+转变趋于完成,电子散射趋于最低,电导率最大,导电性达到最佳;下坡段(600～900℃),Sb3+→Sb5+转变发生逆转,TiO2基体颗粒长大,锐态型向金红石型转变,破坏包膜结构,电导率上升,导电性恶化.     

古木建筑榫卯连接M-θ相关曲线模型研究

通过对木结构榫卯连接模型试验及其试验结果分析,得出影响连接刚度的主要因素是替木尺寸,榫头尺寸和卯孔对柱的削弱程度.利用最小二乘法对试验数据进行处理,得出榫头尺寸及卯孔对刚度影响的规律.在原有的3参数幂函数模型的基础上,建立适合木结构榫卯连接的4参数幂函数弯矩-转角的相关曲线模型.本文基本结论可以为古木结构的研究和修缮工作提供一些理论帮助.     

层状淤沙对混凝土重力坝地震响应的影响分析

本文研究了不同厚度淤沙对混凝土重力坝地震响应的影响以及一定厚度层状淤沙的不同分布形式对混凝土重力坝的地震响应的影响。基于饱和多孔液固两相介质的压力波动方程,设层状淤沙各层厚度不同,将层状淤沙分为三种不同分布形式,在每种分布形式每层的物理参数相同和物理参数不同两种情况下,确定了淤沙对混凝土重力坝地震响应的影响大小。通过算例分析表明,相同物理性质不同的分布形式对地震响应的影响不显著,而不同的分布形式对坝体的地震响应影响较大。     

碾压混凝土中石粉含量精确控制研究与应用

通过在碾压混凝土中掺入工业化粉磨加工的石粉代替部分砂,使砂中石粉总含量满足碾压混凝土的要求,从而改善碾压混凝土的性能,保证其质量.从不同石粉含量的碾压棍凝土试验研究结果分析,以及金安桥水电站大坝碾压混凝土施工质量控制结果分析可知,混凝土生产时必须对外掺石粉量进行精确控制,确保掺入代砂石粉后石粉总量不变,才能确保碾压混凝土的质量稳定.     

中缅伊江上游电源电站孤网运行探讨

近年中缅两国合作开发伊洛瓦底江上游水电,成为举世瞩目的能源合作工程。但由于当地电能匮乏,无法为大电站施工提供电能,须先期建设1座施工电源电站。由此,组成一个孤网供电系统,鉴于缅甸的环境特点,这种孤网运行缺点和困难也是少见的,笔者就这种电网运行作分析探讨。     

Testing the equality of proportions for correlated otolaryngologic data

In otolaryngologic (or ophthalmologic) studies, each subject usually contributes information for each of two ears (or eyes), and the values from the two ears (or eyes) are generally highly correlated. Statistical procedures that fail to take into account the correlation between responses from two ears could lead to incorrect results. On the other hand, asymptotic procedures that overlook small sample designs, sparse data structures, or the discrete nature of data could yield unacceptably high type I error rates even when the intraclass correlation is taken into consideration. In this article, we investigate eight procedures for testing the equality of proportions in such correlated data. These test procedures will be implemented via the asymptotic and approximate unconditional methods. Our empirical results show that tests based on the approximate unconditional method usually produce empirical type I error rates closer to the pre-chosen nominal level than their asymptotic tests. Amongst these, the approximate unconditional score test performs satisfactorily in general situations and is hence recommended. A data set from an otolaryngologic study is used to illustrate our proposed methods.     

浅谈网页设计中Flash与ASP技术的结合

Flash是美国Macromedia公司推出的一款非常优秀的基于矢量图形的交互式动画设计软件。利用Flash可制作出各种类型的多媒体课件,如:演示型、练习型、学习型、游戏型、资料型等等。由此可以看出Flash已成为当前应用最方便、最快捷、最宜上手的多媒体课件开发软件。而ASP技术的出现,则使动态交互式Web主页的设计成为了一件轻松愉快的工作。该文提出把Flash与ASP二者功能结合起来的想法,有效的解决ASP网页单调的缺点,其次Flash与数据库的连接技术的应用能使我们的工作、生活和学习更加方便和生动。