Photocatalytic degradation of methyl tert‐butyl ether (MTBE) in contaminated water by ZnO nanoparticles

BACKGROUND: Over the past several decades methyl tert‐butyl ether (MTBE) as additive to gasoline, intended to either boost ratings of fuel or to reduce air pollution, has been accepted worldwide. Since MTBE has high water solubility, the occurrence of fuel spills or leaks from underground storage tanks or transferring pipeline has led to the contamination of natural waters. In this study the degradation of aqueous MTBE at relatively high concentrations was investigated by a UV‐visible/ZnO/H₂O₂ photocatalytic process. The effects of important operational parameters such as pH, amount of H₂O₂, catalyst loading and irradiation time were also investigated. Concentration of MTBE and intermediates such as tert‐butyl formate and tert‐butyl alcohol were measured. RESULTS: Time required for complete degradation increased from 20 to 150 min when the initial concentration was increased from 10 to 500 mg L^?1. The first‐order rate constants for degradation of MTBE were estimated to be 0.183–0.022 min^?1 as the concentration increased from 10 to 500 mg L^?1. Study of the overall mineralization monitored by total organic carbon analysis showed that at an initial concentration of 100 mg L^?1 MTBE complete mineralization was obtained after 100 min under UV‐visible/ZnO/H₂O₂ photocatalysis. CONCLUSION: The data presented in this paper clearly indicated that UV‐visible/ZnO/O₂ as an advanced oxidation process provides an efficient treatment alternative for the remediation of MTBE‐contaminated waters. Copyright © 2008 Society of Chemical Industry     

Forest harvesting in rural properties: Risks and worsening to the worker’s health under the ergonomics approach

Through an ergonomic approach, this study aimed to evaluate whether workers involved in forest harvesting activities in rural properties are subject to the development of work-related diseases, as well as their consequences. A cross-sectional study with 267 forest workers in rural properties in the Brazilian Central region was used. The following evaluations were performed for each of the activities (felling, delimbing, tracing, manual extraction and manual loading): physical workload evaluation; biomechanical evaluation; risk of repetitive strain injuries/work-related musculoskeletal disorders; environmental noise and vibration factors, where relevant, and thermal overload through the Wetbulb Globe Temperature index. The results showed that in general the physical workload was very high, exceeding the cardiovascular load limits and adding to the need for work reorganization. All activities exposed workers to serious and imminent risks of developing injuries to the spine and lower limbs. Likewise, in general the risk of the appearance of RSI/WMSDs was very high for all activities evaluated. Such results are due to the combination of organizational work factors and factors of the work environment such as exposure to bad weather, uneven terrain, lifting and handling loads above tolerable limits, excessive noise and thermal overload. All of this allows to conclude that ergonomic risks and workers’ health hazards in forest harvesting in rural properties are latent and very worrying, and that these workers are exposed to a form of labor exploitation that invariably leads to physical and emotional exhaustion and therefore to their decreased labor capacity and useful working life.     

Non-insulin dependent diabetes mellitus in Psammomys obesus is independent of changes in tissue fatty acid composition

Recently it has been postulated that membrane fatty acid composition may be involved in the pathogenesis of insulin resistance and non-insulin dependent diabetes mellitus (NIDDM). The aim of this study was to determine whether alterations in tissue phospholipid (PL) fatty acids are present in hyperglycemic and hyperinsulinemic Psammomys obesus. On a native diet of salt bush, P. obesus (Israeli sand rat) remains lean and free of diabetes; however, when placed on a normal laboratory chow, a significant proportion of these animals develops a number of metabolic disorders associated with NIDDM, providing an ideal animal model of obesity and NIDDM. Four groups of mature P. obesus were studied: group A; normoglycemic and normoinsulinemic; group B: normoglycemic and hyperinsulinemic; group C: hyperglycemic and hyperinsulinemic; and group D: hyperglycemic hypoinsulinemic. In liver and red gastrocnemius muscle, there were no significant differences between groups, A, B, and in fatty acid composition of PL. Minor differences in individual fatty acids were demonstrated in group D animals (increased liver 20∶4n-6 and increased muscle 22∶5n-3); however, the unsaturation indices in liver and muscle were not significantly different between any of the groups. In considering that the minor changes in group D animals were not demonstrated in hyperinsulinemic group B animals or hyperglycemic, hyperinsulinemic group C animals, it is likely that the differences in group D animals were secondary to the more severe disturbances in glucose homeostasis and hypoinsulinemia present in these animals. The results of this study suggest that in this rodent diabetic model significant disturbances in glucose homeostasis and hyperinsulinemia may develop independently of changes in tissue fatty acid composition.     

Auxiliary tumour diagnosis image with deep learning technology

The Journal of Supercomputing - In order to analyse the application value of U-Net neural network in reconstruction and diagnosis of computed tomography (CT) scanning image of lung cancer and...     

Rejoinder on: Some recent work on multivariate Gaussian Markov random fields

I thank the discussants, Miguel A. Martinez-Beneito, Fedel Greco, Carlo Trivisano, Stephan R Sain, and Reinhard Furrer, for their insightful and stimulating commentary. The rejoinder is organized in five sections: (1) the M-based models, (2) posterior sensitivity to prior choices for \({\varvec{C}}\) and \({\varvec{\varSigma }}\), (3) stationary and non-stationary (M)GMRFs, (4) various approaches to model formulation and related applications, and (5) statistical computation.     

Cognitive performance-altering effects of electronic medical records: an application of the human factors paradigm for patient safety

According to the human factors paradigm for patient safety, health care work systems and innovations such as electronic medical records do not have direct effects on patient safety. Instead, their effects are contingent on how the clinical work system, whether computerized or not, shapes health care providers’ performance of cognitive work processes. An application of the human factors paradigm to interview data from two hospitals in the Midwest United States yielded numerous examples of the performance-altering effects of electronic medical records, electronic clinical documentation, and computerized provider order entry. Findings describe both improvements and decrements in the ease and quality of cognitive performance, both for interviewed clinicians and for their colleagues and patients. Changes in cognitive performance appear to have desirable and undesirable implications for patient safety as well as for quality of care and other important outcomes. Cognitive performance can also be traced to interactions between work system elements, including new technology, allowing for the discovery of problems with “fit” to be addressed through design interventions.     

An application of the technology acceptance model to the level of Internet usage by older adults

In this cross-sectional study, the principles of a technology acceptance model were used to identify variables related to the level of Internet usage by older adults. Community-dwelling older adults aged 60–88 years completed a postal questionnaire survey that elicited responses on the use of the Internet. Out of a sample of 592 older adults (236 males and 356 females), 50.7% used the Internet. A multiple linear regression analysis was carried out on the Internet users sample using the self-reported number of hours of Internet usage per week as the dependent variable. The results indicated that attitude toward using the Internet and good health status were statistically significant predictors of the level of Internet usage. A second multiple regression analysis using Internet activity as the dependent variable showed that attitude, usefulness, good health, and gender (males) were significant predictor variables.