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排序方式: 共有4905条查询结果,搜索用时 31 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(57):23994-24003
Hydrogenation of dibenzyltoluene (DBT) is of great significance for the application in liquid organic hydrogen carriers (LOHCs). We successfully develop Mg-based metal hydrides (Mg2NiH4, MgH2, and LaH3) reactive ball-milling for the hydrogenation of DBT. Mg-based metal hydrides milled with 500 min exhibit the best catalytic activity, the hydrogen uptake of DBT can reach 4.63 wt% at the first 4 h and finally achieve 5.70 wt% through 20 h, which is the first time to use hydrogen storage material as a catalyst for the hydrogenation of DBT. The excellent catalytic hydrogenation performance of Mg-based metal hydrides mostly originates from numerous catalytic activity centers formed at the surfaces of Mg2NiH4 nanoparticles in the MgH2 matrix. Inspired by this mechanism, more general metal hydrides can be explored for catalyzing the hydrogenation of LOHCs. The new application of Mg-based metal hydrides is beneficial to developing efficient LOHC based hydrogen storage systems and offers novel insights to hydride-based catalysts. 相似文献
2.
基于图像处理的方法,采用了由粗及精的瞳孔定位思想,提出了一种高精度的瞳孔定位算法。该算法首先利用瞳孔区域的直方图,采用改进的最大类间方差法自适应地分割瞳孔区域,实现粗略定位,然后利用瞳孔灰度的梯度特性来精确定位瞳孔边缘点,最后在像素级瞳孔边缘点的基础上,采用亚像素定位方法,更精确地求得亚像素级瞳孔边缘点,并通过椭圆拟合的方法来精确确定瞳孔的中心位置。另外,针对瞳孔被遮挡的情况,本文提出了一种等距离补偿瞳孔的方法。多次实验结果证明了该算法对遮挡瞳孔的定位有较强的鲁棒性,可以准确地定位瞳孔的位置。 相似文献
3.
《Calphad》2015
The total energies of Laves phases in the Cr–Nb and Zr–Cr systems have been calculated by the pseudo-potential VASP code with a full relaxation of all structural parameters. The special quasirandom structures (SQSs) have been constructed and their total energies have been calculated by the VASP code to predict the enthalpies of mixing for bcc and hcp solid solution phases. The phonon calculations for the C14 and C15 Laves phases have been performed to analyze the phase stability at elevated temperatures. The experimental study on the Zr–Cr system has been carried out at different temperatures to determine the phase boundaries. Based on these results, thermodynamic models of Cr–Nb and Zr–Cr with extension to the ternary Zr–Nb–Cr systems have been developed in this work by using the CALPHAD approach. 相似文献
4.
《Ceramics International》2021,47(23):33057-33063
In this study, a chelating agent is introduced to prepare CeO2–ZrO2 nano-composite through a precipitation process. The physicochemical properties of the oxide precursors, nano composite materials are strongly dependent on the preparation method and whether a chelating agent is used. Adding an appropriate quantity of chelating agent SO42− can facilitate thermal stability and phase structure uniformity of CeO2–ZrO2 mixed oxides. The calculation results showed that the Gibbs free energy of chelating complex of [ZrSO4]2+ (ΔG = −127.2469 kJ/mol) is higher than the [Ce(III)SO4]+ (ΔG = -29.8279 kJ/mol). The precipitation chemical potential of Zr4+ moves close to the precipitation chemical potential of Ce3+. The novel and low-cost chelating precipitation method can modify the homogeneity of the compounds at the atomic scale, which can offer a powerful opportunity for, and provide direction in, the design of materials with exceptional properties. 相似文献
5.
Measuring nonlinear optical response of a specific material in a mixture, not only leads to investigate the behavior of a particular component in various circumstances, but also can be a way to select suitable combination and optimum concentration of additives and therefore obtaining the maximum nonlinear optical signals. In this work, by using dual-arm Z-scan technique, the nonlinear refractive index of Disperse Red1 (DR1) organic dye molecules inside the core of prepared polymeric nanocapsules was measured among various materials which prepared nanocapsules were made of them. Then the measured value was compared with nonlinear refractive index of DR1 solved in dichloromethane. 相似文献
6.
《International Journal of Hydrogen Energy》2020,45(3):1435-1443
The size-controlled preparation of Mo powders is always a challenge and important task in the molybdenum metallurgy. In the current study, Mo powders with controllable sizes are synthesized by hydrogen reduction of MoO2 powders with the assistance of Mo nuclei in the range of 900–1100 °C. The influences of the particle sizes of Mo nuclei, the additive amount as well as reaction temperature on the morphology and particle sizes of the final products are studied. For the hydrogen reduction of MoO2 without any additive, the obtained Mo powders always have large particle sizes. However, the addition of small amounts of nuclei in MoO2 can help Mo nucleate dispersedly, and the growth of Mo could be also controlled by adjusting the sizes of added nuclei, amount of addition and the reaction temperature. With the addition of Mo nuclei, the different sizes of Mo powders with the good dispersity can be prepared. As adding commercial Mo powders with the particle size of about 2.03 μm, the micron-sized Mo powders ranged from 2.11 μm to 3.25 μm could be prepared. While for the case of adding ultrafine Mo nuclei of about 170 nm, Mo powders from 0.28 μm to 0.88 μm can be obtained. Moreover, the more the amounts of nuclei added and the lower the reaction temperature (in the range of 900–1100 °C) is, the smaller the particle size of the prepared Mo powder will be. The current method is a facile and feasible method, and is potential to be used for industrial production of Mo powder with controllable particle sizes. 相似文献
7.
解决高速公路沥青路面早期损坏的技术途径 总被引:2,自引:0,他引:2
在对国内大量高速公路调查研究的基础上,论述了我国高速公路沥青路面早期损坏的两种类型:属于短时期内发生的水损坏、车辙、开裂损坏,以及沥青路面的耐久性差、使用寿命短的深层次早期损坏。针对水损坏、车辙、裂缝等局部性质的早期损坏,从路面结构、材料、施工、设计、管理等各方面分析了原因,提出了一系列有效防治高速公路早期损坏的技术措施。 相似文献
8.
Level set and geodesic active contours based measurement of material removal between serial sections
Xiuyang Zhao Yansheng Yin Bo Yang Baohong Zhu Xiaofeng Tian 《Computational Materials Science》2007,39(4):857-861
The measurement of the thickness of material removed between serial sections is a crucial step of three-dimension reconstruction. Geodesic active contours is an efficient method for contour detection of objects on an image. The indents on the SiC/Al composite micrographs are segmented by using level set and geodesic active contours. After getting the contours of the indents, we calculate the distance from the uppermost pixel to the lowermost pixel to get the vertical diagonal length, and calculate the distance from the leftmost pixel to the rightmost pixel to get the horizontal diagonal length of each contour. Then the final length of each diagonal is acquired by averaging the vertical diagonal length and the horizontal diagonal length, respectively. The Vickers’ indenter is made by a square pyramidal-shaped diamond with opposite faces at an angle of 136°, so the thickness of material removed between two serial sections and the length difference of the diagonals on the two serial sections has a definite geometrical relation. Thus the thickness of material removed between two serial sections is acquired using the geometrical relation. 相似文献
9.
美国高能激光技术2005年主要进展 总被引:12,自引:3,他引:9
高能激光武器技术在2005年取得了重大进展。介绍了机载兆瓦级化学氧碘激光器的关键试验和束控-火控系统的飞行试验。评论和讨论了高功率固体激光器、光纤激光器、超高效率二极管源和中继镜技术的重大进展。 相似文献
10.