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排序方式: 共有509条查询结果,搜索用时 156 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(100):42280-42292
In this study, the separation of hydrogen from gas mixtures using a palladium membrane coupled with a vacuum environment on the permeate side was studied experimentally. The gas mixtures composed of H2, N2, and CO2 were used as the feed. Hydrogen permeation fluxes were measured with membrane operating temperature in the range of 320–380 °C, pressures on the retentate side in the range of 2–5 atm, and vacuum pressures on the permeate side in the range of 15–51 kPa. The Taguchi method was used to design the operating conditions for the experiments based on an orthogonal array. Using the measured H2 permeation fluxes from the Taguchi approach, the stepwise regression analysis was also employed for establishing the prediction models of H2 permeation flux, followed by the analysis of variance (ANOVA) to identify the significance and suitability of operating conditions. Based on both the Taguchi approach and ANOVA, the H2 permeation flux was mostly affected by the gas mixture composition, followed by the retentate side pressure, the vacuum degree, and the membrane temperature. The predicted optimal operating conditions were the gas mixture with 75% H2 and 25% N2, the membrane temperature of 320 °C, the retentate side pressure of 5 atm, and the vacuum degree of 51 kPa. Under these conditions, the H2 permeation flux was 0.185 mol s?1 m?2. A second-order normalized regression model with a relative error of less than 7% was obtained based on the measured H2 permeation flux. 相似文献
2.
《Ceramics International》2020,46(12):19835-19842
The present work focused on the effect of Y2O3 co-doping on the phase composition, microstructure, ionic conductivity and thermal shock resistance of 8 mol% MgO stabilized ZrO2 (Mg-PSZ) electrolyte ceramics for high temperature applications. The addition of Y2O3 could promote the process of monoclinic-to-cubic/tetragonal phase transformation and became the metastable phase at room temperature. Meanwhile, the grain size of Mg-PSZ decreased. It was demonstrated that an appreciable increase in the ionic conductivity and compressive strength occurred on substituting MgO with Y2O3 in the Mg-PSZ electrolyte ceramics across the measured temperature range. Moreover, the Y2O3 addition could restrain the adverse effect of the cyclic thermal shock on the ionic conductivity and compressive strength of Mg-PSZ. The main reason was that the increase of the amount of monoclinic phase caused by cubic/tetragonal-to-monoclinic phase transformation by the cyclic thermal shock was restrained after the Y2O3 addition. 相似文献
3.
This study used different metals to modify Rh/Al2O3 catalysts for NO reduction in a simulated waste incineration flue gas containing 6% O2. The characteristics of the modified catalysts were analyzed using BET, TEM and XRD. The results of the experiment reveal that Na addition can significantly affect the properties of Rh/Al2O3 catalysts on the BET surface area and Rh metal dispersion. Furthermore, Na addition was found to significantly enhance the NO conversion of Rh/Al2O3 at 250–350 °C. On the contrary, Cu, Ni, and Co addition was found to have slight suppression effects. 相似文献
4.
T. -Y. Chen 《Structural and Multidisciplinary Optimization》1992,4(3-4):179-185
A design optimization procedure using a sequential linear programming technique is proposed in this paper to design minimum weight structures subjected to frequency response and static displacement constraints. The merit of the proposed approach is that the reanalyses of the static and dynamic responses, as well as the computations of the static and dynamic sensitivity data, are performed in a reduced approximate model. A significant saving of computer time for large scale structures is expected. Two numerical examples show good results of this method. 相似文献
5.
《International Journal of Hydrogen Energy》2005,30(11):1259-1264
Based on the water gas shift (WGS) catalytic mechanism on precious metal catalyst, a Langmuir–Hinshelwood (LH) kinetics model was derived for the operating conditions of syngas from natural gas reforming at near-ambient pressure. A power law kinetics model was also presented for comparative purpose. These two kinetics models were integrated in a dynamic distributed reactor model for design of full-scale WGS reactors for a natural gas fuel processing system. Modeling results indicated that the LH kinetics model gives predictions of reactor performance closer to the experimental data. Using the LH kinetics model, optimization of operating conditions for the high-temperature shift (HTS) and low-temperature shift (LTS) reactors was also attempted. 相似文献
6.
P.L. Lin P.Y. Huang P.W. Huang H.C. Hsu C.C. Chen 《Computer methods and programs in biomedicine》2014
Teeth segmentation for periapical raidographs is one of the most critical tasks for effective periapical lesion or periodontitis detection, as both types of anomalies usually occur around tooth boundaries and dental radiographs are often subject to noise, low contrast, and uneven illumination. In this paper, we propose an effective scheme to segment each tooth in periapical radiographs. The method consists of four stages: image enhancement using adaptive power law transformation, local singularity analysis using Hölder exponent, tooth recognition using Otsu's thresholding and connected component analysis, and tooth delineation using snake boundary tracking and morphological operations. Experimental results of 28 periapical radiographs containing 106 teeth in total and 75 useful for dental examination demonstrate that 105 teeth are successfully isolated and segmented, and the overall mean segmentation accuracy of all 75 useful teeth in terms of (TP, FP) is (0.8959, 0.0093) with standard deviation (0.0737, 0.0096), respectively. 相似文献
7.
Activated carbon-supported copper, iron, or vanadium oxide catalysts were exposed to incineration flue gas to investigate the simultaneous catalytic oxidation of sulfur dioxide/hydrogen chloride and selective catalytic reduction of nitrogen oxide by carbon monoxide. The results show that AC-supported catalysts exhibit higher activities for SO2 and HCl oxidation than traditional γ-Al2O3-supported catalysts and the iron and vanadium catalysts act as catalysts instead of sorbents, and can decompose sulfate with evolution of SO3 and then regenerate for more SO2 adsorption to take place. The AC-supported catalysts also display a high activity for NO reduction with CO generated from a flue gas incineration process and the presence of SO2 in the incineration flue gas can significantly promote catalytic activity. Using CO as the reducing agent for NO reduction is more effective than using NH3, because NH3 may be partially oxidized in the presence of excess O2 (12 vol%. in the incineration flue gas used) to form N2, which can decrease the overall extent of NO reduction. 相似文献
8.
In 2010, Shiu et al. proposed three DNA-based reversible data hiding schemes with high embedding capacity. However, their schemes were not focused on DNA modification rate or the expansion problem. Therefore, we propose a novel reversible data hiding scheme based on histogram technique to solve the weaknesses of Shiu et al.’s schemes. The proposed scheme transforms the DNA sequence into a binary string and then combines several bits into a decimal integer. These decimal integers are used to generate a histogram. Afterwards, the proposed scheme uses a histogram technique to embed secret data. The experimental results show that the modification rate of our proposed scheme is 69 % lower than that of Shiu et al.’s schemes for the same embedding capacity. In addition, the length of the DNA sequence remains unchanged in the proposed scheme. 相似文献
9.
Study of SO2 adsorption and thermal regeneration over activated carbon-supported copper oxide catalysts 总被引:2,自引:0,他引:2
Hui-Hsin Tseng 《Carbon》2004,42(11):2269-2278
The mechanisms of SO2 adsorption and regeneration over activated carbon-supported copper oxide sorbent/catalysts were analyzed. Studies were carried out in a fixed-bed reactor equipped with a non-dispersive infrared gas analyzer to detect the reaction products and by using X-ray powder diffraction (XRPD) and temperature-programmed desorption (TPD) experiments to characterize the nature of the sulfate species and surface oxygen complexes. The results indicate that SO2 was catalytically oxidized to SO3 over a copper phase in the presence of gaseous oxygen, and then reacted with a copper site to form a sulfate linked to copper without desorption into the gas phase. The activated carbon support did not participate in this sulfation reaction. After the adsorption of SO2, the exhausted sorbent/catalysts could be regenerated by direct heat treatment in inert gas at temperatures between 260 and 480 °C, while the neighboring surface oxygen complexes on the carbon surface were acting as the reducing agents to reduce CuSO4 to Cu. During the subsequent adsorption process, the copper is rapidly oxidized by oxygen in the flue gas. 相似文献
10.
Polyether-polyester block copolymers having various polyetheramide contents were synthesized. Single glass transition intermediated in temperature between the glass transition temperatures of polyester and polyetheramide components was found for all of polyether-polyesters. The compositional variation of glass transition exhibited a similar trend to the predicted result of thermodynamic theory for compatible polymer blends. The incompatible pair of homopolyester and homopolyether was forced to be compatible after copolymerization. A modified theoretical prediction for the glass transition of copolymers based on the thermodynamic theory is proposed. Consistent results between theoretical prediction and experimental measurements were found. Unlike homopolyesters, the glass transition temperature of copolymer amorphous domains gradually decreases with crystallization time. An exclusion model for the crystallization of polyester segments in copolymers is proposed. The temperature width of the glass transition increases with crystallization time. The broadening towards the low temperature side in glass transition is interpreted as the evidence of crystallization-induced partial phase separation. Instead of forming macroscopic segregation, the excluded polyether segments resided in-between crystalline polyester lamellae and mix with amorphous polyesters to generate amorphous domains exhibiting concentration gradient along the lamellar basal surface normal. Further increasing the polyetheramide segment content brings the excluded polyetheramide segments to form domains among the crystallized polyester spherulites so as to inhibit the occurrence of spherulitic impingement. 相似文献