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《Ceramics International》2021,47(23):32747-32755
To investigate the nonstoichiometric effect of (Bi0.5Na0.5)TiO3 (BNT) ceramics on their properties, we propose a novel chemical expression, (Bi0.5+xNa0.5−3x)TiO3. The nonstoichiometric effect of BNT can be explored in compounds with this composition without being hampered by the charge imbalance problem. With x ranging from −0.02 to 0.02, we find that the morphological, dielectric, ferroelectric, and electrostrain properties differ considerably between Na-rich and Bi-rich ceramic samples. The average grain size (AGS) increased significantly in Na-rich samples compared to that in stoichiometric BNT, while it decreased slightly in Bi-rich samples. The dielectric characteristics measured from 30 °C to 500 °C indicate that conductivity is activated in Na-rich nonstoichiometric samples but is effectively suppressed in Bi-rich nonstoichiometric samples. The ferroelectric properties also show the same trend. In Na-rich samples, elliptical polarization against electric field (P-E) hysteresis loops were detected, indicating a conductive character induced by high electric field loading. However, saturated P-E loops are observed in Bi-rich samples with well-inhibited conductivity. Furthermore, compared to stoichiometric BNT and nonstoichiometric x = 0.02 Bi-rich samples, (Bi0.5+xNa0.5−3x)TiO3 samples with x = 0.01 exhibit higher electrostrain from 30 °C to 150 °C. Based on the assumption of charge balance, our findings indicated that the presence of 1 mol% excess Bi would facilitate significant improvement in the dielectric, ferroelectric, and electrostrain properties of BNT and BNT-based systems. 相似文献
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《Journal of the European Ceramic Society》2019,39(4):1251-1256
MgAl2-2xMn2xO4 (MAMO) with x = 0-0.12 was synthesized in a single-phase form by solid-state reaction. XRD analysis showed that the samples had the cubic center structure of the Fd-3 m space group. Electrical properties of the samples were studied over the temperature range of 300 K∼1073 K. The results showed that the DC conductivity (σDC) increased from 10−11S/cm at 300 K (MAMO, x = 0) to 10-3S/cm at 1073 K (MAMO, x = 0.12). The equivalent circuit of the complex impedance spectra suggested that the relaxation of charge carriers was of non-Debye type. The conduction was mainly caused by grain boundaries and the capacitance was mainly attributed to polarization. The complex permittivity values (ε’ and ε’’) were increased by two orders of magnitude with the increase in Mn content and temperature over the measured frequency range (1 Hz-1 MHz). Therefore, doping with Mn could be applied to modify the electrical properties of MAMO at high temperature. 相似文献
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针对高速公路高峰期拥挤产生的垃圾等问题,设计一种轨道式垃圾回收机器人,由光伏发电装置、机器人壳体、末端手爪、关节臂以及控制系统等组成,主体结构采用双臂三关节结构,采用西门子PLC控制系统,通过控制关节臂的旋转以及偏转、末端手爪的旋转及开合等动作来实现工作的目的。结合外场作业的特殊性,采用光伏能源装置,对其结构及控制系统进行设计,通过对机器人进行三维建模、运动和控制仿真分析,验证系统的可行性及有效性。 相似文献
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采用封闭网络模型,按照电路元件参数,采用开路、短路和着色运算,将电路图逐层分解,得到网络展开图.给出网络展开图的概念和运算规则,指出网络展开图中从根到末稍每个路径的值就是网络行列式展开式中的一个有效项,从而由网络展开图得到符号网络函数.该方法直接对电路图进行运算,不需要建立任何形式的电路方程和行列式,适用于一般的有源电路,而且能生成各种类型的网络函数. 相似文献
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《中国科学:信息科学(英文版)》2012,(11):2590-2603
We introduce the compressive sensing(CS) theory for waveform design of cognitive radar,and then propose an algorithm for the high-resolution radar signal waveform and its corresponding imaging method based on the sparse orthogonal frequency division multiplexing-linear frequency modulation(OFDM-LFM) signal.We first present the principle of spectrum synthesis and high-resolution imaging based on OFDM-LFM signals.Then,we propose the spectrum-sparse waveform design criterion and the reconstruction algorithm for a highresolution range profile(HRRP) based on CS.Based on this,we analyze in detail the relationship between the scattering characteristics of the target and the parameters of the designed signal,and we construct the feedback of the target characteristics on the waveforms.Therefore,the "cognitive" function of radar can be achieved by adaptively adjusting the waveform with the target characteristics.Simulations are given to validate the effectiveness of the proposed algorithm. 相似文献
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针对某型控制器设计的双余度DSP数据采集装置,采用以双端口RAM方式进行数据交换。结果表明,此数据采集装置既能快速完成模拟数据的采样,又能快速地在DSP间进行高速数据交换,同时,还能够满足基于DSP数据采集装置的高精度与小型化要求。 相似文献
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针对多进制正交幅度调制(Multiple quadrature amplitude modulation,MQAM)信号在低信噪比条件下估计精度不高的问题,提出了一种基于综合利用高阶统计信息的信噪比估计改进算法。根据所选高阶统计量最高阶数的不同,建立了3种信噪比与多种高阶统计量运算式之间的线性关系,利用全回归线性分析方法将3种线性关系转化为3种全回归模型,并求解模型系数。该算法充分利用了多种高阶统计量的有用信息,提高了信噪比估计精度。MQAM的仿真结果表明:在低信噪比条件下,该算法减小了信噪比估计误差,其估计性能明显优于传统的其他算法,且3种模型估计性能依次增加,可依据不同的信噪比要求对3种模型进行选取。 相似文献