Fe(III) grafted MoO3 nanorods for effective electrocatalytic fixation of atmospheric N2 to NH3

Electrocatalytic nitrogen reduction reaction (ENRR) offers a carbon-neutral process to fix nitrogen into ammonia, but its feasibility depends on the development of highly efficient electrocatalysts. Herein, we report that Fe ion grafted on MoO₃ nanorods synthesized by an impregnation technique can efficiently enhance the electron harvesting ability and the selectivity of H⁺ during the NRR process in neutral electrolyte. In 0.1 M Na₂SO₄ solution, the electrocatalyst exhibited a remarkable NRR activity with an NH₃ yield of 9.66 μg h^?1 mg^?1_cat and a Faradaic efficiency (FE) of 13.1%, far outperforming the ungrafted MnO₃. Density functional theory calculations revealed that the Fe sites are major activation centers along the alternating pathway.     

Irradiation-induced large bubble formation and grain growth in super nano-grained ceramic

In this work, 0.5TRPO•0.5Gd₂Zr₂O₇ ceramic with an average grain size of only ∼15 nm was prepared by a high pressure (5 GPa/520 °C) sintering method. Phase evolutions and microstructure changes of the as-fabricated super nano and micron-grained ceramics under a high-dose displacement damage induced by 300 keV Kr²⁺ ions were investigated. The results show that the super nano-grained ceramic has low degree of amorphization, obvious grain growth (2–3 times in grain size) and big Kr bubbles (10–68 nm) formation after irradiation. The micron-grained ceramic was severely amorphized after irradiation and many microcracks were formed parallel to its surface. The formation mechanism of Kr bubbles in the super nano-grained ceramic is on account of grain boundary diffusion and migration induced by the accumulation of the injecting Kr ions and irradiation defects. Nevertheless, microcracks formed in the micron-grained sample are caused by the accumulation of Kr atoms.     

Relationships among boredom proneness,sensation seeking and smartphone addiction among Chinese college students: Mediating roles of pastime,flow experience and self-regulation

Smartphones are indispensable for many young people, which in turn increases the risk of smartphone addiction. Previous studies have discovered significant and positive influences of boredom proneness, sensation seeking and smartphone addiction. This study further explored these influences, their underlying mechanisms, and the mediating effects of pastime, flow experience and self-regulation on smartphone addiction. A total of 442 Chinese college students completed a survey focusing on boredom proneness, sensation seeking, pastime, flow experience, self-regulation and smartphone addiction. The results indicated that boredom proneness positively affects smartphone addiction. Contrary to expectations, the results showed that there is no significant relationship between sensation seeking and smartphone addiction. Moreover, pastime and self-regulation have partial mediation effects on the relationship between boredom proneness and smartphone addiction, while the effect of sensation seeking on smartphone addiction is completely transmitted with the help of flow experience and self-regulation. The findings and their implications are discussed.     

基于温差发电的车载手机充电装置设计

本文计以温差发电为基础,汽车热源（如发动机,排气管）为载体,AT89C52单片机为控制核心,设计了一款车载手机充电装置。该装置主要由温差发电片、LM2577升压稳压电路、AT89C52、MAXl898充电电路和DS2438检测电路等模块组成。该装置通过温差模块直接将汽车余热转换成电能,通过以AT89C52单片机为核心的充电模块对手机电池进行充电。     

行政事业海量题库管理系统设计

提出了行政事业单位海量题库管理系统,给出了系统总体架构设计思路,论述了各主要功能模块的实现。着重讨论了题目重复度判别、题目难度系数调整等关键算法的实现,给出了系统部署、配置与应用实例。     

PSONN在可编程控制系统PID参数优化中的应用

研究可编程控制系统优化问题,可编程控制系统具有非线性、时变性等特点,传统PID控制器优化方法难以建立精确的数学模型,使得系统参数设定困难,导致可编程控制系统的控制效果不理想。为了解决传统的PID算法所带来的问题,利用RBF神经网络非线性、自学习能力,提出一种基于粒子群神经网络的PID参数优化算法。将粒子群和神经网络相结合,形成了一种智能控制算法,并将应用于可编程控制系统。测试结果表明,粒子群神经网络提高了PID控制参数优化速度,提高了可编程控制系统可靠性和鲁棒性,具有一定的理论和实用价值。     

Effect of LiAl5O8 additions on the sintering and optical transparency of LiAlON

LiAl₅O₈ (zeta alumina) was reaction sintered with α-Al₂O₃ and AlN to produce γ-LiAlON. Zeta alumina transforms from a primitive to a face-centered cubic structure above 1290 °C with a lattice parameter similar to γ-AlON. Weight loss measurements combined with XRD suggest solubility of Li in the spinel structure at elevated temperatures. The Vickers hardness, at a 1-kg load, of the pressureless sintered LiAlON was 16.5 ± 0.5 GPa, independent of the grain size or amount of zeta alumina added, for LiAl₅O₈ additions ranging between 0 and 16 wt.%. In-line transmission in the visible and near-IR regions increased with increasing grain size, most likely due to pore coalescence.     

前视探地雷达波速估计及合成孔径成像研究

前视探地雷达的成像处理和地下电磁波的速度估计是前视探地雷达应用中两个重要研究课题。该文利用非平稳滤波矩阵将雷达接收数据经频率域非平稳卷积滤波,实现了目标图像的重建;通过波速扫描和合成孔径成像处理,利用目标图像聚焦的锋利性测度-图像灰度方差估计地下电磁波的速度。对仿真数据和实测数据进行处理,证明了所提方法的有效性。     

餐饮业应急体系的建立与循环经济发展刍议

以循环经济导向餐饮业,是国家旅游餐饮事业进步的重要标志和必然趋势。2008年突发"5.12"汶川特大地震,给餐饮业应对危机、坚持可持续发展提出新的要求。本文提倡从餐饮业的应急储备、供给、安全、健康等方面综合布局,构建能够预防突发性地质、自然灾害的循环经济运行模式,巩固绿色健康的节约型餐饮消费观。