Enhanced properties for visible-light-driven photocatalysis of Ag nanoparticle modified Bi2MoO6 nanoplates

The visible light driven Bi₂MoO₆ photocatalyst doped with different contents of Ag nanoparticles was successfully synthesized by a combination of hydrothermal and sonochemical methods. The as-synthesized samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning and transmission electron microscopy (SEM and TEM) and UV–visible spectroscopy to investigate crystalline structure, morphology, composition and photocatalytic properties. XRD patterns and TEM images of the samples revealed pure phase orthorhombic Bi₂MoO₆ nanoplates without any detection of Ag dopant due to its low concentration and very tiny particle size. TEM images showed that Ag nanoparticles with the size of 10–15 nm were dispersed randomly on the surface of Bi₂MoO₆. The XPS analysis of Ag/Bi₂MoO₆ nanocomposites revealed the presence of additional metallic Ag. Photocatalytic activities of the Ag/Bi₂MoO₆ nanocomposites were evaluated by determining the degradation of rhodamine B (RhB) under visible light radiation. In this research, the 10 wt% Ag/Bi₂MoO₆ nanocomposites showed the best photocatalytic activity. The results suggest that the dispersion of Ag nanoparticles on the surface of Bi₂MoO₆ significantly enhances its photocatalytic activity.     

Nickel foam-supported Fe,Ni-Polyporphyrin microparticles: Efficient bifunctional catalysts for overall water splitting in alkaline media

Developing highly active, stable and sustainable electrocatalysts for overall water splitting is of great importance to generate renewable H₂ for fuel cells. Herein, we report the synthesis of electrocatalytically active, nickel foam-supported, spherical core-shell Fe-poly(tetraphenylporphyrin)/Ni-poly(tetraphenylporphyrin) microparticles (FeTPP@NiTPP/NF). We also show that FeTPP@NiTPP/NF exhibits efficient bifunctional electrocatalytic properties toward both the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER). Electrochemical tests in KOH solution (1 M) reveal that FeTPP@NiTPP/NF electrocatalyzes the OER with 100 mA cm⁻² at an overpotential of 302 mV and the HER with 10 mA cm⁻² at an overpotential of 170 mV. Notably also, its catalytic performance for OER is better than that of RuO₂, the benchmark OER catalyst. Although its catalytic activity for HER is slightly lower than that of Pt/C (the benchmark HER electrocatalyst), it shows greater stability than the latter during the reaction. The material also exhibits electrocatalytic activity for overall water splitting reaction at a current density of 10 mA cm⁻² with a cell voltage of 1.58 V, along with a good recovery property. Additionally, the work demonstrates a new synthetic strategy to an efficient, noble metal-free-coordinated covalent organic framework (COF)-based, bifunctional electrocatalyst for water splitting.     

Data monitoring and sports injury prediction model based on embedded system and machine learning algorithm

Managing sports performance is very important in the sports industry. Performance, the executives, centers on boosting competitor execution and decreasing the danger of injury. Several factors contribute to these goals, including player health, emotional status, exercise load and physical intensity requirements. Generally speaking, injury prediction is an essential component of injury prevention, and successful identification of injury prediction is a primary indicator for effective prevention. The proposed Artificial Neural Network (ANN) objective is to develop and use early-doing ability and exercise load data to validate a hierarchical machine learning prediction system with accurate detection of player injuries. The physical and workload that requires detection of this early personalized damage can be avoided with specific help. The framework is used to test 21 soccer players’ sports information from various sources, including gathered and inside burden information, outside burden information, and review information. The entirety of this information is fused into the proposed framework to improve the exactness of harm expectation. This calculation distinguishes competitors in danger of injury, with their early intervention available.     

Phase transition of lithiated-spinel Li2Mn2O4 at high temperature

1 Introduction Lithium manganese oxides are the most attractive cathode materials for rechargeable lithium-ion batteries because of their low-cost and less toxicity when compared with either cobaltates or nickelates[1?3]. Among these oxides, the spinel-fr…     

基于问题框架的计算机辅助需求工程工具的研发

问题框架(Problem Frames,PF)已经得到需求工程界的广泛重视和研究。目前,问题框架在理论基础和开发方法等方面已经有很多研究成果,但如何把它们应用到实际的软件开发项目中仍是一个有待解决的问题。本工具可帮助系统分析员实现从用户需求到软件规约的平滑和可推理的变换,从而为软件开发项目中需求的沟通、建模及分析等提供技术支持。此外,该工具产生的结果也为下一步的软件设计提供帮助。它对促进问题框架方法的进一步发展和成熟,如从研究走向实用,具有重要的推动作用。     

OCDMA系统中变重光正交码的构造及误码率分析

变重光正交码是基于不同用户带有不同的QoS(Quality of Service)需求而提出的,由于它的码重不是固定值,使得其码字的容量较之常重光正交码有所增加.给出了变重光正交码的定义及其码字容量界,介绍了构造变重光正交码的一种方法,给出一些码字的构造结果,并对码重数不同的码字进行多址干扰误码率的仿真比较和理论分析.结果表明:在相同的码重数下,码重越大的误码率越小;而当码重数不同时,在相同的码重下,码重数大的误码率小.