Effect of structure on the properties of polyurethanes based on aromatic cardanol-based polyols prepared by thiol-ene coupling

Industrial-grade cardanol and 2-mercaptoethanol were reacted to generate hydroxyl-functionalized cardanol by UV, free-radical-initiated thiol-ene coupling between the double bond moieties of the cardanol long carbon side chain and thiol functional groups. The average hydroxyl number of the hydroxyl-functionalized cardanol was controlled by reaction time, with the hydroxyl values of this ranging within 168–201 mg KOH g⁻¹. This cardanol was then used as a polyol to prepare cardanol-based polyurethane with hexamethylene diisocyanate and a NCO/OH ratio of 1. To compare the effect of cardanol-based polyols with the properties of cardanol-based polyurethane, cardanol modified with 10-undecylenate was used as a raw material to prepare cardanol-based polyols, including the long carbon chain of 10-undecylenate. All properties were examined, and data revealed that cardanol-based polyols including this long carbon chain can improve the hydrophobic and mechanic properties of the cardanol-based polyurethane.     

生物质源多孔碳制备及其对废水中药物吸附研究进展

城市现代化与工业化的快速发展给环境造成的污染日趋严重，尤其以水体污染最为明显。近年来，工业废水中药物的含量逐年上升，污染程度已经不容忽视。因此，开发新型多孔材料用于废水中药物分子的吸附分离，已经成为了当前的研究热点。综述了近年来生物质源多孔碳（生物炭）在废水中污染物吸附分离方面的研究，首先简单介绍了废水中污染物的治理方法，在此基础上重点探讨了生物炭的制备与修饰，并结合碳材料表面化学性质与孔道结构，总结并展望了生物炭对药物的吸附性能。     

氧化石墨烯改性碳纤维复合材料抗冲击行为研究

使用单层纳米氧化石墨烯（NGO）粒子对环氧树脂进行改性处理，采用真空辅助树脂传递模塑成型工艺制备了[±45/0/90]_2S铺层角度下的纯树脂及单层NGO改性碳纤维复合材料（CFRP）层合板。通过落锤冲击试验、超声C扫描检测、冲击后压缩试验等对纯树脂及单层NGO改性CFRP进行实验研究。结果表明，纯树脂及单层NGO改性CFRP在损伤阻抗及损伤容限实验中均存在拐点现象，且拐点出现在相同深度位置，其中纯树脂CFRP拐点位置为0.51 mm，单层NGO改性CFRP拐点位置为0.43 mm；相对于纯树脂CFRP，单层NGO改性CFRP可以显著提高复合材料的抗冲击性能及冲击后的压缩性能；通过对冲击后凹坑深度及凹坑面积进行数据模拟，可以用拟合公式实现对复合材料的损伤预测。     

某轻型载货车储气罐支架振动断裂分析与优化

为了有效解决某轻型载货车储气罐支架的断裂故障,首先基于建立的储气罐支架有限元模型进行振动特性分析,分析结果表明其前三阶固有频率接均处于发动机激励频率范围之外,不会产生共振。其次测试各种道路的时域载荷,测试结果表明其中角度搓板路的激励频率与储气罐支架第一阶固有频率相接近,从而引起共振,不满足振动特性要求。然后对其进行振动强度分析,分析结果表明其应力水平不达标,其最大应力点与开裂处一致。再对其进行振动疲劳寿命预测分析,分析结果表明其疲劳寿命也不达标,其危险点也与失效位置相同。再采用集成平台对储气罐支架的结构进行优化设计,优化之后其模态频率、振动强度和振动疲劳均符合性能要求,并且其重量也有所减轻,总体优化效果较佳。最后整车试验结果表明优化之后储气罐支架的振动大幅度降低,并且没有发生失效。     

Application of finite-part integrals to three-dimensional fracture problems for piezoelectric media Part I: Hypersingular integral equation and theoretical analysis

This paper deals with some basic linear elastic fracture problems for an arbitrary-shaped planar crack in a three-dimensional infinite transversely isotropic piezoelectric media. The finite-part integral concept is used to derive hypersingular integral equations for the crack from the point force and charge solutions with distinct eigenvalues s _i(i=1,2,3) of an infinite transversely isotropic piezoelectric media. Investigations on the singularities and the singular stress fields and electric displacement fields in the vicinity of the crack are made by the dominant-part analysis of the two-dimensional integrals. Thereafter the stress and electric displacement intensity factor K-fields and the energy release rate G are exactly obtained by using the definitions of stress and electric displacement intensity factors and the principle of virtual work, respectively. The hypersingular integral equations under axially symmetric mechanical and electric loadings are solved analytically for the case of a penny-shaped crack.     

一种发出红色荧光的六核配合物[Cu6（pymt）6]

合成了一价铜和2-巯基嘧啶盐的配合物[Cu6（pymt）6]并进行结构分析，该配合物能发出强的红色荧光。其中，一价铜离子的配位环境为变形平面三角形，陪体pymt采用μ3-S2N桥联方式参与配位。     

Moving beyond the fourth dimension with an IFC-based single project database

4D CAD has been an active research area for many years. The first generation 4D tools simulated construction schedules and demonstrated the potential benefits in several case studies. Researchers tried to improve the functionality of the first generation 4D tools by adding annotations and highlighting the building elements that have problems. The future generation 4D tools are expected to include more than these. It has been envisioned that 4D models would be part of project databases in order to take decisions related with different project dimensions.This paper presents the development and implementation of a new 4D planning tool which is a part of a product model-based project database. This tool brings the 4D simulation and cost estimation together and aims to contribute to what-if analysis in construction projects. The last part of the paper presents a case study in which the proposed prototype is evaluated.     

BCM7113基本交互型STB的硬件设计

介绍一种基于BCM7113的数字电视机顶盒的硬件设计方案，该方案是应杭州市场的需求而设计开发的，最大的特点就是有线电视网和以太网的结合，BCM7113是Broadcom公司出品的集系统控制、信道解码和标清MPEG-2解码于一体的数字电视机顶盒专用芯片，该平台具有强大的扩展接口，如USB、ITU—R656等，并扩展了10M／100M以太网接口，有很强的可升级性。     

基于VBA技术的Word自动判卷系统的实现

介绍一种用VBA技术实现对Word文档操作的自动判卷系统。学生答题完后计算机可自动批阅并显示分数和正确解,根据得分情况给出相应的学习建议。该系统具有较高的判卷准确性,可以成为学习者平时练习和模拟考试的辅助工具。