Investigation of corrosion properties with Ni–P/TiNO coating on aluminum alloy bipolar plates in proton exchange membrane fuel cell

Aluminum alloy bipolar plates have unique application potential in proton exchange membrane fuel cell (PEMFC) due to the characteristics of lightweight and low cost. However, extreme susceptibility to corrosion in PEMFC operation condition limits the application. To promote the corrosion resistance of aluminum alloy bipolar plates, a Ni–P/TiNO coating was prepared by electroless plating and closed field unbalanced magnetron sputter ion plating (CFUMSIP) technology on the 6061 Al substrate. The research results show that Ni–P interlayer improves the deposition effect of TiNO outer layer and increase the content of TiN and TiO_xN_y phases. Compared to Ni–P and TiNO single-layer coatings, the Ni–P/TiNO coating samples exhibited the lowest current density value of (1.10 ± 0.02) × 10^?6 A·cm^?2 in simulated PEMFC cathode environment. Additionally, potential cyclic polarization measurements were carried out aiming to evaluate the durability of the aluminum alloy bipolar plate during the PEMFC start-up/shut-up process. The results illustrate that the Ni–P/TiNO coating samples exhibit excellent stability and corrosion resistance.     

Electromagnetic shielding properties of iron oxide impregnated kenaf bast fiberboard

The electromagnetic shielding effectiveness of kenaf fiber based composites with different iron oxide impregnation levels was investigated. The kenaf fibers were retted for removing the lignin and extractives from the fibers and magnetized. Using the unsaturated polyester and the magnetized fibers, kenaf fiber based composites were manufactured by the compression molding process. The transmission energies of the composites were characterized when the composite samples were exposed under the irradiation of electromagnetic (EM) wave with a variable frequency from 9 GHz to 11 GHz. Using the Scanning Electron Microscope (SEM), the iron oxide nanoparticles were observed on the surfaces and inside the micropore structures of single fibers. As the Fe content increased from 0% to 6.8%, 15.9% and 18.0%, the total surface free energy of kenaf fibers with the magnetizing treatments increased from 44.8 mJ/m² to 46.1 mJ/m², 48.8 mJ/m² and 53.0 mJ/m², respectively, while the modulus of elasticity reduced from 2875 MPa to 2729 MPa, 2487 MPa and 2007 MPa, respectively. Meanwhile, the shielding effectiveness was increased from 30–50% to 60–70%, 65–75% and 70–80%, respectively.     

PIXE study on recovery of making-technology of Chinese Longquan celadon made in the Southern Song Dynasty (1127–1279 CE)

Proton induced X-ray emission (PIXE) technique and factor analysis were used to study the recovery of making-technology of Chinese Longquan celadon made in the late Southern Song Dynasty (1127–1279 CE). Based on factor analysis, for the raw material for body and the recipe for glaze, there is a close but slightly different relationship between these Longquan celadons unearthed from the core area of Dayao and the non-core area, despite all the Longquan celadons belong to the high-calcium-glaze system. The chemical compositions of most of the tentative body and glaze samples are very close to those of Longquan celadons unearthed from the core area of Dayao and the non-core area. This study can provide a guidance for recovery of making-technology of Longquan celandon.     

Searching and learning english translation long text information based on heterogeneous multiprocessors and data mining

Cooperation with the entire language information retrieval aims to develop intelligent models that use non-compliant and English. It has been constructed to construct the translation model extraction of similar Source Language Sentences Extraction (SLSE). The SLSE, by creating a new pipeline of SLSE through the establishment of the network described above, the first bilingual dictionary of the model of training data, including the Deep Neural Network (DNN) that has been proposed, because it is often in such, it is building because it plays a very important role in the model, SLSE is evaluated by people to ensure the richness of the content that has been used as training data. If the English applicable, not built from 60 gigabytes of text. Since the processing time for it when not highly structured data mining is large, it is troublesome to collect data on this scale. To shorten the processing time, data mining is implemented as a whole.     

Mechanism of methanol decomposition on the Pd/WC(0001) surface unveiled by first-principles calculations

In this study, the decomposition of methanol into the CO and H species on the Pd/tungsten carbide (WC)(0001) surface is systematically investigated using periodic density functional theory (DFT) calculations. The possible reaction pathways and intermediates are determined. The results reveal that saturated molecules, i.e., methanol and formaldehyde, adsorb weakly on the Pd/ WC(0001) surface. Both CO and H prefer three-fold sites, with adsorption energies of −1.51 and −2.67 eV, respectively. On the other hand, CH₃O stably binds at three-fold and bridge sites, with an adsorption energy of −2.58 eV. However, most of the other intermediates tend to adsorb to the surface with the carbon and oxygen atoms in their sp³ and hydroxyl-like configurations, respectively. Hence, the C atom of CH₂OH preferentially attaches to the top sites, CHOH and CH₂O adsorb at the bridge sites, while COH and CHO occupy the three-fold sites. The DFT calculations indicate that the rupture of the initial C–H bond promotes the decomposition of CH₃OH and CH₂OH, whereas in the case of CHOH, O–H bond scission is favored over the C–H bond rupture. Thus, the most probable methanol decomposition pathway on the Pd/WC(0001) surface is CH₃OH → CH₂OH → trans-CHOH → CHO → CO. The present study demonstrates that the synergistic effect of WC (as carrier) and Pd (as catalyst) alters the CH₃OH decomposition pathway and reduces the noble metal utilization.     

牛头山水电站混凝土双曲拱坝设计和水库提前蓄水研究

牛头山水电站大坝为抛物线形混凝土双曲拱坝,最大坝高108.0 m,采用坝顶5孔开敞式溢洪道泄洪,挑流消能。为提前发挥水电站效益,在拱坝尚未完全封拱的情况下,通过计算分析,得出了水库可以下闸蓄水的结论。     

高坝通航技术在水口工程的新发展

水口水电站坝高101m,航运过坝采用一线三级船闸和一线垂直升船机。水口升船机是当时国内已建和在建同类升船机中总体规模最大的升船机,也是我国第一座自行设计、制造、施工和安装的大型升船机。在塔楼结构动力分析和试验研究、塔楼滑框倒模施工、升船机整体模型试验研究、承船厢整体制造和浮运、船厢安全锁定装置和船厢对接密封装置试验研究、整机安装及联调试验等方面充分体现了水口升船机的建成是高坝通航技术的新发展。