Anchoring single Pt atoms on hollow Ag3VO4 spheres for improved activity towards photocatalytic H2 evolution reaction

The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag₃VO₄ have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag₃VO₄ (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H₂ production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H₂ evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H₂ evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions.     

塔巴庙区块气层录井参数分析研究

塔巴庙区块气藏属于低压、低渗气藏,储集层物性差异大、含气级别高,但含气非均质性强,录井解释评价困难。针对这一问题,开展了综合判断储集层物性和含气性方面的研究,分别探讨了钻时与全烃、钻井液性能与全烃、钻井液粘度与全烃、气测显示与测井参数和烃组分与气显示之间的关系,分析了其相关性及其在塔巴庙区块气层解释评价中的意义及作用。通过相关性研究,不但摸索出定性解释评价气层的方法,同时为今后深入研究录井相关参数关系,探索其内在规律,为实现准确解释评价储集层奠定了基础。     

鄂北地区气测现场解释评价研究

鄂尔多斯盆地鄂北地区现场气测录井由于受多种因素影响,解释符合率相对较低。针对这一问题,在探讨影响气测录井显示因素、识别气测异常的基础上,分析了消除影响因素的途径和校正公式,建立了随钻全烃与全脱全烃的关系式,论述了地面和地层含气量计算方法。在初步评价气显示性质条件下,经统计分析得出了应用4参数——峰面积、校正全烃值、全烃计算值和地层含气量加权分值的解释评价标准,为鄂北地区气测录井解释评价和产能的初步预测探索了一种新模式,不但解决了鄂北地区气测解释符合率低的问题,而且对于深入开展气测录井参数与油气解释评价研究具有一定的参考意义。     

石化行业自动化控制仪表常见故障分析及其处理

介绍化工生产过程中仪表故障及其处理措施。     

Discretized LKF method for stability of coupled differential‐difference equations with multiple discrete and distributed delays

Time‐delay systems described by coupled differential‐functional equations include as special cases many types of time‐delay systems and coupled differential‐difference systems with time delays. This article discusses the discretized Lyapunov–Krasovskii functional (LKF) method for the stability problem of coupled differential‐difference equations with multiple discrete and distributed delays. Through independently dividing every delay region that the plane regions consists in two delays to discretize LKF, the exponential stability conditions for coupled systems with multiple discrete and distributed delays are established based on a linear matrix inequality (LMI). The numerical examples show that the analysis limit of delay bound in which the systems are stable may be approached by our result. Copyright © 2011 John Wiley & Sons, Ltd.     

综合商务大厦智能信息网络系统设计

随着科技信息技术的飞速发展,人们对办公和商务所处的环境提出了更高的要求。传统的商务活动在与互联网结合后,网络信息技术为商务活动在空间与时间上提供了极大的便利。信息网络系统的综合布线是楼宇智能化系统集成的主要业务,是智能商务大厦的一个重要的组成部分。根据榆林市学X大厦设施要求,提出了学X大厦的办公自动化目标：摆脱时空限制。介绍了主要的工程概况、综合布线系统设计以及系统配置等。     

基于ATP-EMTP的330 kV半复合传输杆塔雷电反击过电压仿真研究

介绍复合材料传输杆塔的优势与研究进展以及三种传统杆塔模型.为了验证330 kV半复合传输塔单根接地引下线设计的合理性,运用电磁暂态分析软件ATP-EMTP,建立输电线路、雷电流波形以及杆塔多波阻抗仿真模型.通过分析杆塔雷电过电压分布,判断接地引下线与传输线之间是否会发生闪络.     

工艺参数对选择性激光烧结PS/SBS/纳米CaCO3制件弯曲强度影响

针对聚苯乙烯(PS)粉末选择性激光烧结(SLS)成型件强度较低的问题,采用机械混合法制备了PS/苯乙烯–丁二烯–苯乙烯嵌段共聚物(SBS)/纳米CaCO₃复合粉末,通过单因素实验分析了SLS工艺参数对成型件弯曲强度的影响,并通过正交试验和极差分析获得了最优工艺参数组合。实验结果表明,烧结件的弯曲强度随着激光功率的增大而升高,随着扫描速度、扫描间距和分层厚度的增大而降低;激光功率对PS/SBS/纳米CaCO₃复合粉末烧结件弯曲强度的影响最大,分层厚度对弯曲强度的影响最小,扫描速度和扫描间距的影响介于两者之间;最佳工艺参数组合为:激光功率27 W,扫描速度1300 mm/s,扫描间距0.24 mm,单层厚度0.22 mm。在此工艺参数组合下PS/SBS/纳米CaCO₃复合粉末烧结件的弯曲强度为13.38 MPa;改性纳米CaCO₃与PS和SBS的相容性较好,能有效起到增强的作用。     

基于BLP模型的摆渡木马防御技术的研究

分析了摆渡木马的工作原理和特点,提出了控制数据从计算机流向移动存储介质的解决方法。根据BLP模型的基本思想,提出了基于BLP模型的摆渡木马防御方案。在该方案中,根据内网或计算机中文件的重要程度,将文件分成不同等级;将用户对文件的访问权限也分成相应的不同等级;当用户对文件进行访问时,通过比较权限等级和文件等级来决定是否能读或写,读或写采用＂下读上写＂的策略。由于把移动存储介质的级别设为最低,所以该方案能有效的防止摆渡木马。     

随机变量负相关性的性质和关系

文中对随机变量负相关性的性质和强弱关系进行了研究．运用概率分析的方法,首先证明了负象限相关的对称性、负相协的对称性、右尾递减和左尾递增的内在联系;其次,通过反例说明了随机递减不具备对称性;最后,如果二维随机变量的联合密度函数是RR2的,则其条件分布是随机递减的,进一步可得到随机变量是右尾递减和左尾递增的;如果二维随机变量是负相协的,则也是负象限相关的,进而得到随机变量是负线性相关．