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1.
《Carbon》2015
We perform classical molecular dynamics simulations to investigate the mechanical compression effect on the thermal conductivity of the single-walled carbon nanotube (SWCNT) forest, in which SWCNTs are closely aligned and parallel with each other. We find that the thermal conductivity can be linearly enhanced by increasing compression before the buckling of SWCNT forests, but the thermal conductivity decreases quickly with further increasing compression after the forest is buckled. Our phonon mode analysis reveals that, before buckling, the smoothness of the inter-tube interface is maintained during compression, and the inter-tube van der Waals interaction is strengthened by the compression. Consequently, the twisting-like mode (good heat carrier) is well preserved and its group velocity is increased by increasing compression, resulting in the enhancement of the thermal conductivity. The buckling phenomenon changes the circular cross section of the SWCNT into ellipse, which causes effective roughness at the inter-tube interface for the twisting motion. As a result, in ellipse SWCNTs, the radial breathing mode (poor heat carrier) becomes the most favorable motion instead of the twisting-like mode and the group velocity of the twisting-like mode drops considerably, both of which lead to the quick decrease of the thermal conductivity with further increasing compression after buckling. 相似文献
2.
《Carbon》2015
Absorbents with “tree-like” structures, which were composed of hollow porous carbon fibers (HPCFs) acting as “trunk” structures, carbon nanotubes (CNTs) as “branch” structures and magnetite (Fe3O4) nanoparticles playing the role of “fruit” structures were prepared by chemical vapor deposition technique and chemical reaction. Microwave reflection loss, permittivity and permeability of Fe3O4–CNTs–HPCFs composites were investigated in the frequency range of 2–18 GHz. It was proven that prepared absorbents possessed the excellent electromagnetic wave absorbing performances. The bandwidth with a reflection loss less than −15 dB covers a wide frequency range from 10.2 to 18 GHz with the thickness of 1.5–3.0 mm, and the minimum reflection loss is −50.9 dB at 14.03 GHz with a 2.5 mm thick sample layer. Microwave absorbing mechanism of the Fe3O4–CNTs–HPCFs composites is concluded as dielectric polarization and the synergetic interactions exist between Fe3O4 and CNTs–HPCFs. 相似文献
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Most researches on graphene/polymer composites are focusing on improving the mechanical and electrical properties of polymers at low graphene content instead of paying attention to constructing graphene’s macroscopic structures. In current study the homo-telechelic functionalized polyethylene glycols (FPEGs) were tailored with π-orbital-rich groups (namely phenyl, pyrene and di-pyrene) via esterification reactions, which enhanced the interaction between polyethylene glycol (PEG) molecules and chemical reduced graphene oxide (RGO) sheets. The π–π stacking interactions between graphene sheets and π-orbital-rich groups endowed the composite films with enhanced tensile strength and tunable electrical conductivity. The formation of graphene network structure mediated by the FPEGs fillers via π–π stacking non-covalent interactions should account for the experimental results. The experimental investigations were also complemented with theoretical calculation using a density functional theory. Atomic force microscope (AFM), scanning electron microscope (SEM), X-ray diffraction (XRD), nuclear magnetic resonance (NMR), thermal gravimetric analysis (TGA), UV–vis and fluorescence spectroscopy were used to monitor the step-wise preparation of graphene composite films. 相似文献
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《Journal of the European Ceramic Society》2020,40(8):3348-3353
Large transduction coefficient () is difficult to obtain in piezoelectric ceramics because these two parameters show opposite trends with compositional modifications. Herein, the Pb(Zr0.53Ti0.47)O3 ceramic powders were calcinated under different temperatures (A:830 °C, B:860 °C, and C:890 °C), and then mixed together according to different weight ratios (1A:1B:1C, 1A:2B:1C, 1A:2B:3C and 3A:2B:1C) for ceramics preparation. Both d33 and g33 are improved successfully, and the transduction coefficient with the weight ratio of 1A:2B:3C reaches up to 17,500 × 10−15 m2/N, which is 60 % higher than that with the powders calcinated under 830 °C, and at least twice those of commercial PZT-4, PZT-5A and PZT-8 ceramics. The improved transduction coefficient is owing to the enhanced piezoelectric constant and spontaneous polarization resulted from the increased grain size, relative density and the fraction of tetragonal phase. These results indicate that this is a simple but effective way to tailor the transduction coefficient in piezoelectric ceramics. 相似文献
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Z. Yu Y. F. Hsia X. Z. You H. Spiering P. Gutlich 《Journal of Materials Science》1997,32(24):6579-6581
A light-induced excited spin state trapping (LIESST) experiment for a thermal gradual spin crossover complex, Fetris (2-pyridylmethyl)
amine(NCS)2 or Fe(tpa) (NCS)2, was attempted for the first time. The high spin (HS) state after light inducement stayed metastable
over a period of days without relaxation at 10 K. Intersystem relaxation from a high to a low spin (LS) complex occurred at
50 K after bleaching at 10 K. Investigation of the Mossbauer spectra of the LIESST and relaxation experiment indicated that
the Debye–Waller factor was a correlation parameter of the HS fraction and that the co-operative effect played a role in the
relaxation process for such a solid compound.
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献
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