Anchoring single Pt atoms on hollow Ag3VO4 spheres for improved activity towards photocatalytic H2 evolution reaction

The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag₃VO₄ have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag₃VO₄ (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H₂ production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H₂ evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H₂ evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions.     

论我国大学不良竞争的形成及控制

大学在办学资源、办学过程、办学质量、办学形象的竞争中出现大量的不良倾向。大学的不良竞争是由于政府主导资源配置、资源和制度供给不足、大学系统重构等因素导致。必须通过控制主体、控制手段的转变和控制对象的发展形成新的控制机制，以保证大学竞争的秩序化和规范化。     

多传感器检测中的数据溶合技术

多传感器检测是使用多种(或多个)传感器对同一被测对象进行广泛的测量。应用多传感器检测技术和多传感器数据溶合技术对车削加工中的零件外圆尺寸检测进行了实验研究,结果表明,多传感器检测技术能够满足现代检测技术对信息的精确要求,使得检测监控系统更加准确、可靠。     

塔巴庙区块气层录井参数分析研究

塔巴庙区块气藏属于低压、低渗气藏,储集层物性差异大、含气级别高,但含气非均质性强,录井解释评价困难。针对这一问题,开展了综合判断储集层物性和含气性方面的研究,分别探讨了钻时与全烃、钻井液性能与全烃、钻井液粘度与全烃、气测显示与测井参数和烃组分与气显示之间的关系,分析了其相关性及其在塔巴庙区块气层解释评价中的意义及作用。通过相关性研究,不但摸索出定性解释评价气层的方法,同时为今后深入研究录井相关参数关系,探索其内在规律,为实现准确解释评价储集层奠定了基础。     

建筑意--中国雕版印刷博物馆及扬州博物馆设计

本文以中国雕版印刷博物馆及扬州博物馆设计为例，从空间意象、理水设计、造形元素等方面对特定历史条件、自然条件下的建筑创作进行了探讨。     

鄂北地区气测现场解释评价研究

鄂尔多斯盆地鄂北地区现场气测录井由于受多种因素影响,解释符合率相对较低。针对这一问题,在探讨影响气测录井显示因素、识别气测异常的基础上,分析了消除影响因素的途径和校正公式,建立了随钻全烃与全脱全烃的关系式,论述了地面和地层含气量计算方法。在初步评价气显示性质条件下,经统计分析得出了应用4参数——峰面积、校正全烃值、全烃计算值和地层含气量加权分值的解释评价标准,为鄂北地区气测录井解释评价和产能的初步预测探索了一种新模式,不但解决了鄂北地区气测解释符合率低的问题,而且对于深入开展气测录井参数与油气解释评价研究具有一定的参考意义。     

光纤通信在军事上的应用

简述了光纤通信在军事通信中的地位与作用，较全面介绍了陆、海、空军各领域的应用情况，阐明了军事通信对光纤通信元器件的要求和核爆炸对光纤通信的影响。     

石化行业自动化控制仪表常见故障分析及其处理

介绍化工生产过程中仪表故障及其处理措施。     

神东网络现状及解决思路

神东煤炭公司信息网络发展至今已经形成规模,在整个神华集团广域网中神东也是重要节点之一,肩负着周边各兄弟公司的广域网接入以及旗下众多煤矿和分公司业务数据的传输。由于神东网络属于自然发展型网络,在网络规模建设初期,问题容易规避,在形成规模以后,各种潜在的问题都可能导致网络故障从而影响整体网络的正常运行。分别从神东煤炭集团公司局域网、宽带网、井下工业以太网3个方面分别进行详细阐述。     

Discretized LKF method for stability of coupled differential‐difference equations with multiple discrete and distributed delays

Time‐delay systems described by coupled differential‐functional equations include as special cases many types of time‐delay systems and coupled differential‐difference systems with time delays. This article discusses the discretized Lyapunov–Krasovskii functional (LKF) method for the stability problem of coupled differential‐difference equations with multiple discrete and distributed delays. Through independently dividing every delay region that the plane regions consists in two delays to discretize LKF, the exponential stability conditions for coupled systems with multiple discrete and distributed delays are established based on a linear matrix inequality (LMI). The numerical examples show that the analysis limit of delay bound in which the systems are stable may be approached by our result. Copyright © 2011 John Wiley & Sons, Ltd.