A size-dependent thermodynamic model for coke crystallites: The carbon–hydrogen system up to 2500 K

The development is presented of a model of the thermodynamic functions of enthalpy, entropy and Gibbs energy for the elements carbon and hydrogen in coke crystallites. It is applicable to varying degrees of graphitization, described by the crystallite length L_a and the crystallite height L_c. The model parameters are derived from known properties such as bond enthalpies and entropies of formation. Good agreement has been obtained between the predicted thermal dehydrogenation of petroleum cokes and experimental data. The removal of hydrogen from idealized coke crystallites is predicted to occur mostly between 1100 and 1300 K. Agreement has also been found in the comparison of the predicted thermodynamic stability of coke relative to graphite, in a previous experimental study. This stability has been determined as at ≈900 J g⁻¹ at temperatures between 950 and 1250 K and for L_a = 10 nm. The current predictive capacity of the present model is valid for temperatures up to 2500 K.     

An investigation into physicochemical characteristics of ash produced from combustion of oil palm biomass wastein a boiler

Ash derived from combustion of Malaysian oil palm biomass (empty fruit bunches consisting of fibers) was physically and chemically characterized in order to provide a comprehensive understanding of its specific properties in terms of toxicity, compositions and reusability. Principal analyses conducted include particle size distribution, scanning electron microscopy, elemental dispersive X-ray, elemental analysis, toxicity characteristic leaching procedure (TCLP) as well as thermogravimetric, X-ray diffractometry and Fourier-transform infrared analyses. TCLP result indicated that the oil palm ash (OPA) should not be classified as toxic wastes in terms of heavy metal leachability since leachable copper, cadmium, lead and nickel concentrations were detected below the stipulated leachability limits. It was determined that the OPA contained high amount of potassium as well as presence of silica which implied its suitability to be reused as crude fertilizer or cement replacement material.     

The interleaved video frame distribution for P2P-based VoD system with VCR functionality

The peer-to-peer (P2P) network structure is widely employed for video streaming applications because of its high stability, flexible extensibility, and ability to distribute data stream loading among different peer nodes. Numerous P2P schemes have been proposed for video on demand (VoD) applications. High video source searching cost and long response latency are always issues in dealing with VCR functionality, such as jump and fast-forward/rewind, because of asynchronous interactive and random join/leave behaviors of end users. To overcome this bottleneck, an interleaved video frame distribution (IVFD) scheme is proposed to support full VCR functionality in a P2P environment without searching for new sources. Instead of acquiring video stream data from a single parent peer in the published schemes, each child peer in the IVFD scheme can simultaneously acquire interleaved video data from multiple parent peers. When a client peer carries out arbitrary VCR operations, such as jump or fast-forward/rewind, its parent peers are still able to provide intermittent video stream data for the client peer; thus, no video source search is necessary. Simulation results reveal excellent load distribution performance and response latency for VCR operations in the proposed IVFD scheme.     

Fabrication of ultraviolet photoconductive sensor using a novel aluminium-doped zinc oxide nanorod-nanoflake network thin film prepared via ultrasonic-assisted sol-gel and immersion methods

Unique and novel thin films with aluminium (Al)-doped zinc oxide (ZnO) nanostructures consisting of nanorod-nanoflake networks were prepared for metal-semiconductor-metal (MSM)-type ultraviolet (UV) photoconductive sensor applications. These nanostructures were grown on a glass substrate coated with a seed layer using a combination of ultrasonic-assisted sol-gel and immersion methods. The synthesised ZnO nanorods had diameters varying from 10 to 40 nm. Very thin nanoflake structures were grown vertically and horizontally on top of the nanorod array. The thin film had good ZnO crystallinity with a root mean square roughness of approximately 13.59 nm. The photocurrent properties for the Al-doped ZnO nanorod-nanoflake thin films were more than 1.5 times greater than those of the seed layer when the sensor was illuminated with 365 nm UV light at a density of 5 mA/cm². The responsivity of the device was found to be dependent on the bias voltage. We found that similar photocurrent curves were produced over eight cycles, which indicated that the UV sensing capability of the fabricated sensor was highly reproducible. Our results provide a new approach for utilising the novel structure of Al-doped ZnO thin films with a nanorod-nanoflake network for UV sensor applications. To the best of our knowledge, UV photoconductive sensors using Al-doped ZnO thin films with a nanorod-nanoflake network have not yet been reported.     

Electronic properties and gas adsorption behaviour of pristine,silicon-, and boron-doped (8, 0) single-walled carbon nanotube: A first principles study

Carbon nanotubes (CNTs) have received enormous attention due to their fascinating properties to be used in various applications including electronics, sensing, energy storage and conversion. The first principles calculations within density functional theory (DFT) have been carried out in order to investigate the structural, electronic and optical properties of un-doped and doped CNT nanostructures. O₂, CO₂, and CH₃OH have been chosen as gas molecules to study the adsorption properties based on zigzag (8,0) SWCNTs. The results demonstrate that the adsorption of O₂, CO_2, and CH₃OH gas molecules on pristine, Si-doped and B-doped SWCNTs are either physisorption or chemisorption. Moreover, the electronic properties indicating SWCNT shows significant improvement toward gas adsorption which provides the impact of selecting the best gas sensor materials towards detecting gas molecule. Therefore, these pristine, Si-, and B-doped SWCNTs can be considered to be very good potential candidates for sensing application.     

Location allocation modeling for healthcare facility planning in Malaysia

Malaysia has seen tremendous growth in the standard of living and household per capita income. The demand for a more systematic and efficient planning has become increasingly more important, one of the keys to achieving a high standard in healthcare. In this paper, a Maximal Covering Location Problem (MCLP) is used to study the healthcare facilities of one of the districts in Malaysia. We address the limited capacity of the facilities and the problem is formulated as Capacitated MCLP (CMCLP). We propose a new solution approach based on genetic algorithm to examine the percentage of coverage of the existing facilities within the allowable distance specified/targeted by Malaysian government. The algorithm was shown to generate good results when compared to results obtained using CPLEX version 12.2 on a medium size problem consisting of 179 nodes network. The algorithm was extended to solve larger network consisting of 809 nodes where CPLEX failed to produce non-trivial solutions. We show that the proposed solution approach produces significant results in determining good locations for the facility such that the population coverage is maximized.     

Work-related musculoskeletal disorders in home care nurses: Study of the main risk factors

BackgroundNurses are a risk group for work-related musculoskeletal disorders (WMSDs). Several studies reveal that nurses have high prevalence rates of injuries and symptoms related to WMSDs. However, many of these studies focus mostly on hospital nurses. Worldwide, few studies include home care nurses.ObjectiveThis work aimed to identify the body region most affected by musculoskeletal complaints in home care nursing, and subsequently develop a statistical model, that includes the main risk factors, to predict the risk of having musculoskeletal complaints in the identified region.MethodsThe research method was based on the Standardised Nordic Questionnaire applied to home care nurses working at Health Centres of northern Portugal. Univariate and multivariate models of logistic regression were used to meet the goals of this work.ResultsHome care nurses have a three times greater chance of having lumbar complaints than their counterparts working only at Health Centres (OR = 3.19 (p < 0.05), with a 95% confidence interval [1.256; 8.076]). A statistical model with seven variables (forearm posture; static postures; arm posture; arm supported; bed height; job satisfaction; assistive devices) was obtained to predict lumbar complaints.ConclusionsThe lumbar region was identified as the most affected by musculoskeletal complaints. These complaints were associated with seven factors.     

Effect of carbonitriding temperature process on the adhesion properties of diamond like-carbon coatings deposited by PECVD on austenitic stainless steel

The deposition of adherent coatings such as diamond-like carbon (DLC) on substrates of iron-based materials is difficult to obtain for two reasons: high residual compressive stress occurs in the inner film formation, and the mismatch of thermal expansion coefficient between steel and DLC film generates delamination effects. In order to determine the carbonitriding temperature prior to film deposition, the steel substrate and the DLC films were analyzed for their microstructure and mechanical properties of adhesion as a function of temperature. The technique used to deposit the coating was DC-pulsed plasma enhanced chemical vapor deposition. The delamination distances and the critical load of the film were obtained by scratch testing. The surface analysis by X-ray diffraction indicated the formation of nitride phases on the steel. Raman spectroscopy showed the fraction of sp³ carbon bonds in DLC films. Hardness profiling was used to verify the extent of the interface modified by carbonitriding along the cross section. For this, the steel sample with the appropriate surface modification to have high adhesion of the DLC film was used.     

Structure and magnetic behavior of Zn doped NdMnO3 manganite: Neutron diffraction study

Effect of Zn doping on the structural and magnetic properties of NdMnO₃ has been investigated by neutron diffraction and dc magnetic susceptibility measurements. The partial replacement of Mn³⁺ by Zn²⁺ results in the decrease in T_N. In the temperature dependent magnetization measurements, a broad hump and a sharp peak has been observed around ~ 50 K and 10 K respectively for both the samples. Thermal hysteresis in magnetization between cooling and heating runs indicate first-order phase transition. Magnetization measurements on NdMn_0.95Zn_0.05O₃ sample clearly show that, 5% Zn-doping in NdMnO₃ results in the suppression in magnetism which is evident from the weakening of Nd–Mn interaction below T_N, and resulting in antiferromagnetic coupling of Mn³⁺ ions along x-axis with Mn³⁺ moments oriented parallel or antiparallel to the x-component of Nd³⁺ moments.