Doping-free hybrid white organic light-emitting diodes with fluorescent blue,phosphorescent green and red emission layers

Industrialized white organic light-emitting diodes (OLEDs) currently require host-guest doping, a complicated process necessitating precise control of the guest concentration to get high efficiency and stability. Two doping-free, hybrid white OLEDs with fluorescent blue, and phosphorescent green and red emissive layers (EMLs) are reported in this work. An ultra-thin red phosphorescent EML was situated in a blue-emitting electron transport layer (ETL), while the ultra-thin green phosphorescent EML was placed either in the ETL (Device 1), or the hole transport layer (HTL) (Device 2). Device 2 exhibits higher efficiency and more stable spectrum due to the enhanced utilization of excitons by ultra-thin green EML at the exciton generation zone within the HTL. Values of current efficiency (CE), power efficiency (PE), and CRI obtained for the optimized hybrid white OLEDs fabricated through a doping-free process were of 23.2 cd/A, 20.5 lm/W and 82 at 1000 cd/m², respectively.     

Impact of class clustering in a multiclass FCFS queue with order-dependent service times

In multi-class queueing systems, customers of different classes can enter the system. When studying such systems, it is traditionally assumed that the different classes of customers occur randomly and independently in the arrival stream of customers in the system. This is often in contrast to the actual situation. Therefore, we study a multi-class system with so-called class clustering in the customer arrival stream, i.e., (Markovian) correlation occurs in the classes of consecutive customers. The system under investigation consists of one server that is able to serve two classes of customers. In addition, the service-time distribution of a customer depends on the equality or non-equality of its class with the class of the previous customer. This latter feature occurs frequently in practice. For instance, execution of the same task again can lead to both faster or slower processing times. The first case can occur when the execution of a different task entails resetting a machine, or loading new data, et cetera. The opposite situation appears, for instance, when execution of the same task requires postprocessing (such as cooling down or reinitialization of a machine). We deduce the probability generating function (pgf) of the system content, from which we can extract various performance measures, among which the mean values of the system content and the customer delay. We demonstrate that class clustering has a tremendous impact on the system performance, which highlights the necessity to include it in the performance assessment of any system in which it occurs.     

Multipath optical thermometry realized in CaSc2O4: Yb3+/Er3+ with high sensitivity and superior resolution

Design and fabrication of contactless optical thermometer with rapid and accurate performance has become a research hotspot in recent years. Herein, CaSc₂O₄: Yb³⁺/Er³⁺ is employed as the intermediary for temperature sensing under the excitation of 980 nm, which is proven to afford an ultra-sensitive and high-resolution optical thermometry in multiple ways based on the fluorescence intensity ratio (FIR) technology. The optimal thermal sensing behaviors are realized by the FIR of Er³⁺:²H_11/2 → ⁴I_15/2 to ⁴S_3/2 → ⁴I_15/2 transition, which has a relative sensitivity of 1184/T² and a minimal resolution of 0.03 K along with a maximal absolute error of 0.96 K. Besides that, the FIR between the thermally coupled Stark sublevels of Er³⁺:⁴F_9/2 manifold (FIR_R) as well as that of Er³⁺: ⁴I_13/2 manifold (FIR_N) can also provide excellent optical thermometry. The relative sensitivity of FIR_R-based and FIR_N-based optical thermometers are calculated to be 402/T² and 366/T², respectively, with a same minimal resolution of 0.09 K, which possess the potential to be used for biomedicine due to the inherent advantage of their operating wavelengths located in the biological window. The results demonstrate that CaSc₂O₄: Yb³⁺/Er³⁺ is a promising candidate for temperature sensing with multipath, high sensitivity, and superior resolution.     

水下无线光通信系统研究进展

水下无线光通信作为一种新兴的高速水下无线通信技术,在海洋生态环境监测、资源勘测以及军事作战等方面的作用不可小觑,并已成为全世界竞相争夺的关键性技术。对目前常用的3种水下无线通信方式进行比较,介绍了水下无线光通信的信道特性,并阐述水下无线光通信系统中光源、调制、信道编码以及探测等关键技术的研究进展。总结了水下无线光通信技术的发展趋势,为未来水下无线光通信系统的深入研究和实用化提供了参考。     

Modulating the Surface State of SiC to Control Carrier Transport in Graphene/SiC

Silicon carbide (SiC) with epitaxial graphene (EG/SiC) shows a great potential in the applications of electronic and photoelectric devices. The performance of devices is primarily dependent on the interfacial heterojunction between graphene and SiC. Here, the band structure of the EG/SiC heterojunction is experimentally investigated by Kelvin probe force microscopy. The dependence of the barrier height at the EG/SiC heterojunction to the initial surface state of SiC is revealed. Both the barrier height and band bending tendency of the heterojunction can be modulated by controlling the surface state of SiC, leading to the tuned carrier transport behavior at the EG/SiC interface. The barrier height at the EG/SiC(000‐1) interface is almost ten times that of the EG/SiC(0001) interface. As a result, the amount of carrier transport at the EG/SiC(000‐1) interface is about ten times that of the EG/SiC(0001) interface. These results offer insights into the carrier transport behavior at the EG/SiC heterojunction by controlling the initial surface state of SiC, and this strategy can be extended in all devices with graphene as the top layer.     

Preparation and employment of carbon nanodots to improve electron extraction capacity of polyethylenimine interfacial layer for polymer solar cells

The performance of polymer solar cells is substantially enhanced by introducing carbon nanodots as additives in polyethylenimine buffer layer. The most pronounced effect is observed in one type of device with the average power conversion efficiencies increased from 5.78% to 7.56% after the addition of carbon nanodots at an optimal concentration in the interfacial layer, which is mainly attributed to the enhanced light trapping and electron transfer in the devices. Besides the light-harvesting and electron transport capacity improvement, the addition of carbon nanodots can also increase exciton generation and dissociation, leading to a high electron mobility. This study demonstrates a facile approach for enhancing the efficiencies of polymer solar cells.     

Low threshold melt-processed two-photon organic surface emitting upconversion lasers

Herein, a low threshold, wavelength-tunable, compact, two-photon pumped upconversion laser is presented. The surface emitting lasers are composed of melt-processed 1,4-bis[2-[4-[N,N-di(p-totyl)amino]phenyl]vinyl]benzene (DADSB) as active media and two designed distributed bragg reflectors. The melting fabrication process is very simple, and the lasing threshold is as low as 150 μJ cm^?2 pulse^?1, when pumped by a Ti:sapphire amplifier operating at 800 nm with a 150 fs pulse width. To the best of our knowledge, it is one of the lowest values for two-photon lasers. Lasing from multimode to single-mode oscillation is demonstrated. Tunable single mode oscillation was obtained at wavelength from 514 nm to 523 nm with a spectral width of less than 0.2 nm.     

Realization of triplet–triplet annihilation in planar heterojunction exciplex-based organic light-emitting diodes

Triplet–triplet annihilation (TTA) for enhancement of luminous efficiency occurs with difficulty in exciplex-based organic light-emitting devices (OLEDs) because it is an interaction among several neighboring donor and acceptor molecules. However, TTA has been realized in our planar-heterojunction (PHJ) exciplex-based OLEDs by using a thin recombination zone to enhance the interfacial density of the triplet states. The TTA process, which is characterized by a high-field decrease (HFD) in the magneto-electroluminescence from the PHJ OLEDs, appears at approximately 150 K and becomes stronger with decreasing temperature. At a given temperature, the higher the injected current is, the stronger HFD is observed. Additionally, we find that TTA could even happens at room temperature with appropriate selection of the donor molecule, which may be attributed to the favorable electron-donating ability of the methoxy group (–OCH₃) in the donor molecule and the matched overlaps of the intermolecular conformation of the donor and the acceptor.     

All thermal-evaporated surface plasmon enhanced organic solar cells by Au nanoparticles

Au nanoparticles (NPs) are fabricated on indium-tin-oxide substrates by a thermal evaporation method and incorporated to an efficient small molecule organic solar cell (OSC). This renders an all thermal evaporated surface plasmon enhanced OSC. The optimized device shows a power conversion efficiency of 3.40%, which is 14% higher than that of the reference device without Au NPs. The improvement is mainly contributed to the increased short-circuit current which resulted from the enhanced light harvesting due to localized surface plasmon resonance of Au NPs and the increased conductivity of the device.