Synthesis and characterization of Ce/SiOC nanocomposites through the polymer derived ceramic method and evaluation of their catalytic activity

Cerium oxide and silicon oxycarbide (Ce/SiOC) porous nanocomposites have been synthesized through the polymer derived ceramic route. In the synthesis of the preceramic precursors, the addition of urea facilitates the deposition of Cerium atoms on the surface of SiO₂ nanoparticles since it prevents the SiO₂ from agglomeration. Both Ce and urea affects the structural and textural parameters of the obtained ceramics. Less crosslinked structures are formed when the urea concentration increases and it also provokes a reduction of the carbon crystallite size. Cerium, on the other hand, induces an increase of the carbon size as well as the number of SiOC units. Pore anisotropy and smoothness of the surface are also dependent on the composition of the material. As expected, the better thermocatalytic behavior against CO₂ decomposition is found at the largest Ce amounts but also, smooth surfaces and low pore anisotropies favor the accessibility of the gases to the thermocatalytic centers.     

Relationships between the accumulative damage and dielectric properties of woven BN-coated Hi-Nicalon™ SiC fibre-reinforced SiC matrix composites

The accumulative damage behaviour of BN-coated Hi-Nicalon™ SiC fibre-reinforced SiC matrix composite was examined under tensile cyclic loading at room and elevated temperatures. The accumulative damage occurring during the cyclic loading was quantitatively characterised using the damage parameter obtained by the hysteresis loop curves. The damage parameter increased with increasing applied stress beyond the matrix cracking stress, and it subsequently retained a nearly constant value until just before fracture. Moreover, the dielectric constant, dielectric loss and loss tangent of the composite were measured before and after the fracture in the frequency range 1–1000 MHz. The dielectric properties had similar frequency dependency before and after the fracture. However, the dielectric constant, dielectric loss and loss tangent were lower in the post-fractured specimens than in the pristine ones. The reduction of the dielectric properties was associated with the accumulative damage stored in the specimens. In addition, the relationships between the dielectric properties and the damage parameter were described in detail.     

In2O3:Ga and In2O3:P-based one-electrode gas sensors: Comparative study

Gas sensing characteristics of one-electrode sensors based on the In₂O₃ ceramics doped by gallium and phosphorus have been discussed. In₂O₃-based ceramic was prepared by sol–gel technology. Ozone, CO, CH₄ and H₂ were used as tested gases. The doping concentration effect on the sensor parameters such as magnitude of response, operating temperature, response and recovery times, sensitivity to the air humidity, and selectivity have been analyzed. It was shown that In₂O₃ doping by Ga and P could be used for the sensor performance optimization. It was assumed that the appearance of the second phase (InPO₄ and Ga₂O₃) and the change of structural parameters, taking place during doping process, were the main factors controlling the change of operating characteristics in In₂O₃:P and In₂O₃:Ga-based sensors.     

Can child-pedestrians’ hazard perception skills be enhanced?

ObjectiveTraffic collisions yield a substantial rate of morbidity and injury among child-pedestrians. We explored the formation of an innovative hazard perception training intervention – Child-pedestrians Anticipate and Act Hazard Perception Training (CA²HPT). Training was based upon enhancing participants’ ability to anticipate potential hazards by exposing them to an array of traffic scenes viewed from different angles.MethodTwenty-four 7–9-year-olds have participated. Trainees underwent a 40-min intervention of observing typical residential traffic scenarios in a simulated dome projection environment while engaging in a hazard detection task. Trainees were encouraged to note differences between the scenarios presented to them from separate angles (a pedestrian's point-of-view and a higher perspective angle). Next, trainees and control group members were required to perform crossing decision tasks.ResultsTrainees were found to be more aware of potential hazards related to restricted field of view relative to control.ConclusionsChild pedestrians are responsive to training and actively detecting materialized hazards may enrich child-pedestrians’ ability to cross roads.     

基于DEM的振动筛筛孔形状对潮湿原煤筛分效果影响的研究

随着原煤含水量的增加,引起原煤颗粒间相互粘聚,影响振动筛筛分效率。基于离散元法,运用EDEM软件模拟了潮湿原煤颗粒在圆形筛孔、方形筛孔和矩形筛孔的筛分过程,并且以筛分效率和阻碍粒排出率为衡量指标,对振动筛筛孔形状影响潮湿煤筛分效果进行了研究。结果表明:在筛孔名义尺寸相同的情况下,潮湿煤在矩形筛孔筛面上的筛分效果最好,方形筛孔次之,圆形筛孔最差。     

Machine learning techniques for scheduling jobs with incompatible families and unequal ready times on parallel batch machines

This research is motivated by a scheduling problem found in the diffusion and oxidation areas of semiconductor wafer fabrication facilities, where the machines can be modeled as parallel batch processors. Total weighted tardiness on parallel batch machines with incompatible job families and unequal ready times of the jobs is attempt to minimize. Given that the problem is NP hard, a simple heuristic based on the Apparent Tardiness Cost (ATC) Dispatching Rule is suggested. Using this rule, a look-ahead parameter has to be chosen. Because of the appearance of unequal ready times and batch machines it is hard to develop a closed formula to estimate this parameter. The use of inductive decision trees and neural networks from machine learning is suggested to tackle the problem of parameter estimation. The results of computational experiments based on stochastically generated test data are presented. The results indicate that a successful choice of the look-ahead parameter is possible by using the machine learning techniques.     

3D polymeric microfluidic device fabrication via contact liquid photolithographic polymerization (CLiPP)

In this contribution, a new method for the fabrication of complex polymeric microfluidic devices is presented. The technology, contact liquid photolithographic polymerization (CLiPP), overcomes many of the drawbacks associated with other rapid prototyping schemes, such as limited materials choices and time-consuming microassembly protocols. CLiPP shares many traits with other photolithographic methods, but three distinct features: (i) liquid photoresists in contact with the photomask, (ii) readily removed sacrificial materials, and (iii) living radical processes, enable multiple polymeric chemistries and mechanical properties while simultaneously enabling facile fabrication of 3D geometries and surface chemistry control. This contribution details fabrication techniques and methods for the fabrication of high aspect ratio posts covalently bonded to a polymeric substrate, an array of independently stacked bars on top of perpendicular bars, multiple undercut structures fabricated simultaneously, and a complex 3D geometry with intertwined channels.     

基于OpenCv运动目标识别技术的研究

在智能视频监控系统中,快速、准确、有效地检测出运动目标成为人们研究的主要课题之一。本文根据背景差分与帧间差分各自的特点,提出一种基于高斯模型的背景差分与帧间差分相结合的运动目标检测算法。说明高斯背景建模原理以及算法的背景模型更新方法,最后介绍了算法的实现流程和实验结果。在VisualC++6.0环境下,利用计算机视觉类库OpenCV对算法进行了验证。实验结果表明:该算法能快速、有效地提取目标。     

基于视差与分层渲染的立体显示效果评价研究

本文在充分分析国内外立体显示技术评价方法的基础上,提出了利用视差和分层渲染的方法进行立体显示效果的评价,结果表明其对于自由立体显示评价可以得到较明确的分析结果,最后对研究前景进行了必要的探讨。     

高弹性MXene/TPU纳米纤维纱线的制备及其应变传感性能

采用静电纺丝技术制备了热塑性聚氨酯弹性体(TPU)纳米纤维膜,并通过“Biscrolling”的方法制备高弹性过渡金属碳化物/氮化物（Ti3C2Tx MXene）改性TPU纳米纤维纱线。通过SEM、电阻测试、传感性能测试等对复合纳米纤维纱线进行结构和性能表征。结果显示,随着MXene负载量增加,复合纱线的强度先增加后降低,断裂伸长率可高达459%以上,展现出优异的弹性和弹性回复性;MXene片可在纳米纤维纱线表面及内部形成连续导电薄膜,赋予复合纱线较好的导电性（电阻76 Ω/cm）。纱线的应变传感性能测定实验表明,MXene/TPU纳米纤维纱线的传感系数可高达477.86,线性度高达0.995,高于绝大多数文献报道的纱线传感器,并且可以监测人体的各种运动状态,展现出较好的应变传感性能,在智能可穿戴领域展现出广泛的应用前景。