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排序方式: 共有137条查询结果,搜索用时 0 毫秒
1.
《晶体工程》1999,2(2-3):137-144
Three adduct structures of 4,4-dipyridyl (4,4-DP) have been prepared and studied using single-crystal X-ray techniques. These are indole-2-carboxylic acid [(4,4-DP)(ICA)2] 1, 3-aminobenzoic acid [(4,4-DP)(3-ABA)] 2, and 4-aminobenzoic acid [(4,4-DP)(4-ABA)] 3. The structures have an increasing degree of complexity in the overall hydrogen-bonding network. The structure of 1 comprises polymeric hydrogen-bonded chains of associated 4,4-DP and ICA molecules which propagate through a complementary site on the ICA molecules. The structure of 2 consists of two parallel polymeric hydrogen-bonded chains, each involving associated 4,4-DP and 3-ABA molecules, which cross-link through complementary 3-ABA sites. The structure of 3 is an extensive 3-dimensional hydrogen-bonded network involving all hydrogen-bond donor and acceptor sites on the constituent molecules. In each case the positions and directions of the N–H groups are important in determining the eventual lattice network. 相似文献
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现有的聚合签密方案主要是基于复杂的双线性对构造,计算效率较低,不能很好地适用于计算资源和通信带宽受限的应用环境。为了提高聚合签密的效率,提出一种不含双线性对映射的无证书聚合签密方案。基于计算Diffie-Hellman问题(CDHP)和离散对数问题(DLP)的困难性,在随机预言模型下证明了方案满足机密性和不可伪造性。该方案不含双线性对运算和指数运算,在单签密阶段仅需要2个点乘运算,与已有的典型聚合签密方案相比具有更高的计算效率且密文长度更短;而且方案的聚合签密验证阶段无需任何用户的秘密信息,方案具有可公开验证性;此外,方案在部分私钥生成阶段不需要安全信道,降低了通信复杂度。 相似文献
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Neural Processing Letters - In this paper, a new class of Riemann–Liouville fractional-order neutral-type delayed projective neural networks are introduced and studied. By utilizing the... 相似文献
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《International Journal of Hydrogen Energy》2020,45(11):6352-6359
The Ni/ZrO2 catalyst doped with Ca and Ni/ZrO2 were employed in the CO2 methanation, a reaction which will possibly be used for storing intermittent energy in the future. The catalysts were characterized by X-ray photoelectron spectroscopy (XPS, reduction in situ), X-ray diffraction (XRD, reduction in situ and Rietveld refinement), electron paramagnetic resonance (EPR), temperature-programmed surface reaction, cyclohexane dehydrogenation model reaction, temperature-programmed desorption of CO2 and chemical analysis. The catalytic behavior of these catalysts in the CO2 methanation was analyzed employing a conventional catalytic test. Adding Ca to Ni/ZrO2, the metallic surface area did not change whereas the CO2 consumption rate almost tripled. The XRD, XPS and EPR analyses showed that Ca+2 but also some Ni2+ are on the ZrO2 surface lattice of the Ni/CaZrO2 catalyst. These cations form pairs which are composed of oxygen vacancies and coordinatively unsaturated sites (cus). By increasing the number of these pairs, the CO2 methanation rate increases. Moreover, the number of active sites of the CO2 methanation rate limiting step (CO and/or formate species decomposition, rls) is enhanced as well, showing that the rls occurs on the vacancies-cus sites pairs. 相似文献
6.
《International Journal of Hydrogen Energy》2020,45(23):12949-12960
A phase stability map of metallic magnesium powder, exposed to environmental conditions for 12 months (Mg-12M) and subjected to different high-energy ball-milling speeds and milling times, was constructed. Mg-12M−160 [½MgO-⅓Mg(OH)2-⅙hydromagnesite] and Mg-12M−640 [¼MgO-⅝Mg(OH)2-⅛hydromagnesite] composites were obtained changing the milling conditions. The correlation among the accumulated energy (ΔEaccum), the impact energy (ΔEhit), and the phase stability under different high-energy ball-milling conditions were generated. The Mg-12M−160 composite had a hydrogen storage capacity of 0.63 wt% at −196 °C and 8.3 bar, although further hydrogen adsorption at higher pressures is expected. Structural defects play a significant role in the adsorption capacity. A representation of the possible absorption mechanism is proposed. 相似文献
7.
《International Journal of Hydrogen Energy》2020,45(46):24595-24603
Ce-promoted Ni/Al2O3 catalysts with Ce contents of 0, 5, 10, 15, and 20 wt% were investigated for CO2 methanation. Ni/15Ce/Al2O3 showed good selectivity and catalytic performance in CO2 methanation and remained stable at 350 °C for 80 h with minor fluctuations. Interactions between Ni and the Ce/Al2O3 support was characterized using X-ray diffraction, temperature-programmed reduction of H2, temperature-programmed desorption of CO2, X-ray photoelectron spectroscopy, Raman spectroscopy, and thermogravimetric analysis. Addition of Ce did not increase the catalytic surface area, which can significantly enhance the heterogeneous catalytic activity. However, XPS analysis showed that the Ce on the Ni/Al2O3 catalyst changed the surface electron states of Ni, Ce, and O. Additionally, CO2 adsorption/desorption was confirmed to be related to the amount of Ce present on Ni/Al2O3 by TGA and CO2-TPD. The Ce addition thus played an important role in determining the CO2 adsorption, desorption, and conversion. 相似文献
8.
《Journal of the European Ceramic Society》2021,41(14):6983-6990
Ternary 0.552Pb(Ni1/3Nb2/3)O3-xPbZrO3-(0.448-x)PbTiO3 (PNN-PZ-PT) ceramics near the triple point compositions were fabricated by an improved two-step sintering method. The triple point composition 0.552PNN-0.135PZ-0.313PT ceramic has outstanding piezoelectric performance with piezoelectric coefficient d33 = 1200 pC/N. Its easy fabrication and low cost make this piezoelectric material an excellent candidate for high sensitivity sensors and ultrasonic transducers. The evolution of domain structures for ceramics with composition near the triple point provides deeper insight into the mechanism of ultrahigh piezoelectric properties of PNN-PZ-PT ceramics. 相似文献
9.
GIS是一种现代信息地理系统,在课堂教学中展现了巨大的优势。文中开发了一种具有三维GIS功能的教学软件,实现了地理知识的直观展示和深入分析。该软件不仅丰富了地理教学内容,还提升了学生的实践能力和学习兴趣,为高校地理教学提供了有效的工具。研究表明,GIS辅助软件的应用显著提高了地理教学效果,有助于培养高素质的复合型人才。 相似文献
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