Effect of structure on the properties of polyurethanes based on aromatic cardanol-based polyols prepared by thiol-ene coupling

Industrial-grade cardanol and 2-mercaptoethanol were reacted to generate hydroxyl-functionalized cardanol by UV, free-radical-initiated thiol-ene coupling between the double bond moieties of the cardanol long carbon side chain and thiol functional groups. The average hydroxyl number of the hydroxyl-functionalized cardanol was controlled by reaction time, with the hydroxyl values of this ranging within 168–201 mg KOH g⁻¹. This cardanol was then used as a polyol to prepare cardanol-based polyurethane with hexamethylene diisocyanate and a NCO/OH ratio of 1. To compare the effect of cardanol-based polyols with the properties of cardanol-based polyurethane, cardanol modified with 10-undecylenate was used as a raw material to prepare cardanol-based polyols, including the long carbon chain of 10-undecylenate. All properties were examined, and data revealed that cardanol-based polyols including this long carbon chain can improve the hydrophobic and mechanic properties of the cardanol-based polyurethane.     

某轻型载货车储气罐支架振动断裂分析与优化

为了有效解决某轻型载货车储气罐支架的断裂故障,首先基于建立的储气罐支架有限元模型进行振动特性分析,分析结果表明其前三阶固有频率接均处于发动机激励频率范围之外,不会产生共振。其次测试各种道路的时域载荷,测试结果表明其中角度搓板路的激励频率与储气罐支架第一阶固有频率相接近,从而引起共振,不满足振动特性要求。然后对其进行振动强度分析,分析结果表明其应力水平不达标,其最大应力点与开裂处一致。再对其进行振动疲劳寿命预测分析,分析结果表明其疲劳寿命也不达标,其危险点也与失效位置相同。再采用集成平台对储气罐支架的结构进行优化设计,优化之后其模态频率、振动强度和振动疲劳均符合性能要求,并且其重量也有所减轻,总体优化效果较佳。最后整车试验结果表明优化之后储气罐支架的振动大幅度降低,并且没有发生失效。     

Application of finite-part integrals to three-dimensional fracture problems for piezoelectric media Part I: Hypersingular integral equation and theoretical analysis

This paper deals with some basic linear elastic fracture problems for an arbitrary-shaped planar crack in a three-dimensional infinite transversely isotropic piezoelectric media. The finite-part integral concept is used to derive hypersingular integral equations for the crack from the point force and charge solutions with distinct eigenvalues s _i(i=1,2,3) of an infinite transversely isotropic piezoelectric media. Investigations on the singularities and the singular stress fields and electric displacement fields in the vicinity of the crack are made by the dominant-part analysis of the two-dimensional integrals. Thereafter the stress and electric displacement intensity factor K-fields and the energy release rate G are exactly obtained by using the definitions of stress and electric displacement intensity factors and the principle of virtual work, respectively. The hypersingular integral equations under axially symmetric mechanical and electric loadings are solved analytically for the case of a penny-shaped crack.     

一种发出红色荧光的六核配合物[Cu6（pymt）6]

合成了一价铜和2-巯基嘧啶盐的配合物[Cu6（pymt）6]并进行结构分析，该配合物能发出强的红色荧光。其中，一价铜离子的配位环境为变形平面三角形，陪体pymt采用μ3-S2N桥联方式参与配位。     

Moving beyond the fourth dimension with an IFC-based single project database

4D CAD has been an active research area for many years. The first generation 4D tools simulated construction schedules and demonstrated the potential benefits in several case studies. Researchers tried to improve the functionality of the first generation 4D tools by adding annotations and highlighting the building elements that have problems. The future generation 4D tools are expected to include more than these. It has been envisioned that 4D models would be part of project databases in order to take decisions related with different project dimensions.This paper presents the development and implementation of a new 4D planning tool which is a part of a product model-based project database. This tool brings the 4D simulation and cost estimation together and aims to contribute to what-if analysis in construction projects. The last part of the paper presents a case study in which the proposed prototype is evaluated.     

BCM7113基本交互型STB的硬件设计

介绍一种基于BCM7113的数字电视机顶盒的硬件设计方案，该方案是应杭州市场的需求而设计开发的，最大的特点就是有线电视网和以太网的结合，BCM7113是Broadcom公司出品的集系统控制、信道解码和标清MPEG-2解码于一体的数字电视机顶盒专用芯片，该平台具有强大的扩展接口，如USB、ITU—R656等，并扩展了10M／100M以太网接口，有很强的可升级性。     

基于VBA技术的Word自动判卷系统的实现

介绍一种用VBA技术实现对Word文档操作的自动判卷系统。学生答题完后计算机可自动批阅并显示分数和正确解,根据得分情况给出相应的学习建议。该系统具有较高的判卷准确性,可以成为学习者平时练习和模拟考试的辅助工具。     

基于语义Web的搜索引擎研究

传统搜索引擎是基于关键字的检索,然而文档的关键字未必和文档有关,而相关的文档也未必显式地包含此关键字。基于语义Web的搜索引擎利用本体技术,可以很好地对关键字进行语义描述。当收到用户提交的搜索请求时,先在已经建立好的本体库的基础上对该请求进行概念推理,然后将推理结果提交给传统的搜索引擎,最终将搜索结果返回给用户。相对于传统的搜索引擎,基于语义Web的搜索引擎有效地提高了搜索的查全率和查准率。     

不同降雨工况下红黏土边坡持水响应规律与稳定性分析

以江西区域内典型红黏土边坡为研究对象,基于岩土非饱和渗流理论,建立红黏土边坡有限元计算模型,对4种典型降雨工况下红黏土边坡稳定性进行分析。结果表明,降雨强度、降雨持续时间均是影响红黏土边坡稳定性的重要因素;前期为常态时,边坡各参数指标均维持在初始稳定状态;降雨开始后,边坡安全系数呈减小态势,岩土体强度和稳定性降低,边坡中土体的孔隙水压力变大,体积含水量升高;越接近地表的土体降雨入渗响应越强烈,边坡不同位置处土体的降雨入渗影响程度依次为:坡肩>坡顶>坡面>坡脚>坡底;降雨入渗和互渗过程具有明显的滞后性,越靠近地表,孔隙水压力短期内变化越明显;土体干湿循环对边坡稳定性整体表现为负作用,且作用效果不可逆。