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1.
2.
The Er3+ doped oxyfluorogermanate glasses, with a composition containing Na element, were synthesized by the conventional melting–quenching technique. When Na element was introduced into the composition of oxyfluorogermanate glass, the crystals behavior was investigated in details. Depending on the annealing procedure supplied, thermal annealing of precursor glasses in the system GeO2/BaF2/AlF3/Na2O/NaF/ZnO/GdF3/ErF3 led to the precipitation of different crystal phase nanocrystals. It was confirmed the nanocrystals in GC600 is orthorhombic NaBaAlF6 which led to enhance obviously in the UC luminescence of Er3+. However, the nanocrystals in G585 led to decrease in the UC luminescence, which indicated few Er ions enter into the lattice of this nanocrystal phase. The reason of the decrease in UC emission intensity of GC585 was analyzed. 相似文献
3.
Xueliang Wang Huiqin Yin Wenguan Liu Guojun Yu Jian He Zhongfeng Tang Long Yan 《工业材料与腐蚀》2020,71(6):931-937
Understanding the corrosion of molten ZnCl2 on metal surfaces is significant for the corrosion protection of metals, sustainable use of molten salts, preparation of ZnO coatings, and so on. In this paper, surfaces of pure Ni, Cr, and Fe corroded by molten ZnCl2 were investigated. The results show that Ni suffered very slight corrosion, while Cr experienced more serious corrosion than Ni, but lighter corrosion than Fe. The morphology of the corrosion of Cr and Fe, respectively, presented pitting and intergranular corrosion characteristics. Furthermore, nanostructured ZnO coatings were obtained on the surfaces of Ni and Fe, but not on the surface of Cr. The ZnO coating on the Ni surface was doped with a small amount of Zn5(OH)8Cl2, and the ZnO coating on the Fe surface was doped with ZnFe2O4 and Zn2OCl2. The coatings on the Ni and Fe surfaces had an average thickness of 1.5 and 50 μm, respectively. 相似文献
4.
5.
用脉冲辐解和激光光解相结合,研究了异喹啉这种难降解杂环化合物在紫外光作用下的变化和与HO·的反应.结果表明,在波长为266nm的激光作用下,异喹啉不仅发生光激发,而且发生单光子电离,其量子产额为1.58×10-4.异喹啉光电离产生的阳离子自由基可以脱去质子,其pKa为5.50.异喹啉可以与HO·发生反应,其反应速率常数为3.4×109 mol-1·dm3·s-1.本工作的研究将为photo-Fenton法降解异喹啉提供理论上的依据. 相似文献
6.
The dielectric and piezoelectric properties of the (Pb0.985Bi0.01)(Ni1/4Zn1/12Nb2/3)x- (ZrσTi1-σ)1-xO3 piezoelectric ceramic system (0.2 ≤ x ≤ 0.7, 0.1 ≤ σ ≤ 0.9) were systematically investigated. The results showed that, after poling, the dielectric constant, ε
33
T
, increased for the tetragonal compositions but decreased for the rhombohedral compositions. Furthermore, high values of ε
33
T
and piezoelectric modulus, d
31 were found for the compositions along the extension of the morphotropic phase boundary. The highest values of the planar
electromechanical coupling factor, K
p, and the piezoelectric modulus, d
31, were found to be 0.70 and − 274 × 10-12 C N-1, respectively. The Curie temperature, remanent polarization, coercive field and the lattice constants of the a and c axes in relation to the Pb(Ni1/3Nb2/3)O3 content and the Zr/Zr + Ti ratio were also determined.
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献
7.
Two free and one silylated (silane-substituted) photochromic spirooxazines are doped into organically modified ceramics (Ormocer) coatings by sol-gel processing and the thermal decoloration kinetics of these coatings are investigated and compared with the corresponding ethanol solutions and PMMA coatings. The decoloration behaviour of the two free dyes (SO-1 and SO-2) in the Ormocer coatings is similar to that in ethanol solutions, obeying a first-order mechanism and possessing almost the same decoloration rates as in ethanol. This suggests that the dye molecules encapsulated within the pores of the solid matrix are as free as those in ethanol solutions. The silylated dye (SO-3) in the Ormocer coatings, however, exhibits a considerably lower decoloration rate than the corresponding free dye (SO-1) and evident deviation from the first-order mechanism. This indicates apparently that the degree of freedom of the dye molecules is reduced by the silylation. These results are discussed on the basis of solvent polarity, porous structure of the Ormocer coating, and the dye-to-matrix connectivity. 相似文献
8.
9.
《Optical Materials》2005,27(1):99-102
The spin Hamiltonian parameters g∥, g⊥, A∥ and A⊥ for Er3+ ion in LiYF4 are investigated by using the perturbation formulas of these parameters for a 4f11 ion in tetragonal symmetry. In these formulas, the contributions to the spin Hamiltonian parameters from the second-order perturbation terms and the admixtures of different states are considered. The relevant crystal field parameters are calculated from the superposition model and the local structural parameters of the Y3+ site occupied by impurity Er3+. The theoretical optical spectra within 4I15/2 and 4I13/2 states and the spin Hamiltonian parameters obtained in this work are consistent with the observed values. 相似文献
10.
《Optical Fiber Technology》2006,12(2):110-116
We report on a newly developed in-service measurement technique that can be used from a central office to find and identify any filter in front of an ONU on an optical fiber access network. Using this system, in-service tests can be performed because the test lights are modulated at a high frequency. Moreover, by using the equipment we developed, this confirmation operation can be performed continuously and automatically with existing automatic fiber testing systems. The developed technique is effective for constructing a fiber line testing system with an optical time domain reflectometer. 相似文献