Mechanical properties of graphene films enhanced by homo-telechelic functionalized polymer fillers via π–π stacking interactions

Most researches on graphene/polymer composites are focusing on improving the mechanical and electrical properties of polymers at low graphene content instead of paying attention to constructing graphene’s macroscopic structures. In current study the homo-telechelic functionalized polyethylene glycols (FPEGs) were tailored with π-orbital-rich groups (namely phenyl, pyrene and di-pyrene) via esterification reactions, which enhanced the interaction between polyethylene glycol (PEG) molecules and chemical reduced graphene oxide (RGO) sheets. The π–π stacking interactions between graphene sheets and π-orbital-rich groups endowed the composite films with enhanced tensile strength and tunable electrical conductivity. The formation of graphene network structure mediated by the FPEGs fillers via π–π stacking non-covalent interactions should account for the experimental results. The experimental investigations were also complemented with theoretical calculation using a density functional theory. Atomic force microscope (AFM), scanning electron microscope (SEM), X-ray diffraction (XRD), nuclear magnetic resonance (NMR), thermal gravimetric analysis (TGA), UV–vis and fluorescence spectroscopy were used to monitor the step-wise preparation of graphene composite films.     

基于移动平台的校园资讯系统设计与实现

为了让高校师生可以快捷方便地获取到校园各类资讯,摆脱时间和空间的限制,设计了一种基于移动平台的校园资讯系统。该系统在PC平台上采用Asp.Net和SQL Server 2005技术,基于B/S的三层网络结构设计,在移动平台上基于C/S模式设计并开发了一个具备相应功能的Android手机客户端应用[1]。该系统具有查询课程、查询教室、查询考试安排、学生交友、发布商品、查询商品等基本功能。该移动平台系统界面友好,操作方便,资讯丰富,极大地方便了高校师生的学习、工作和生活。     

存在高渗透区的黏土心墙土石坝渗流稳定性分析

黏土心墙土石坝是重要的挡水建筑物,心墙的低渗透性可以大幅降低坝体水力梯度,减少坝体发生渗透破坏的风险。然而心墙的质量问题（如局部高渗透区）会影响坝体的渗透稳定性,甚至酿成管涌溃坝等严重后果。以瀑布沟心墙土石坝为原型开展坝体渗流大型水槽模型试验,并结合有限元数值模拟方法研究高渗透区对坝体内部渗流场和渗流稳定性的影响。试验表明高渗透区域将改变心墙的渗流场,成为优势渗流通道,导致高渗透区域附近孔压值大幅上升,同时高渗透区域的存在将显著提升坝体渗漏速率。试验与模拟结果一致表明,随着高渗透区域逐步上移,高渗透区所在位置处的孔隙水压力增大,坝体渗漏量减小。高渗透区和心墙的渗透系数增加都会使心墙孔压值和渗漏量增加;随着高渗透区的渗透系数的增大,心墙坝渗流稳定性系数降低,导致坝体稳定性下降;随着心墙渗透系数的增大,高渗透区水力梯度略微减小,但心墙整体临界水力梯度下降,坝体稳定性降低。所得结论可为基于监测数据反演分析心墙的质量问题和评估坝体的安全性能提供依据。     

Enhanced healing of full-thickness diabetic wounds using bioactive glass and Yunnan baiyao ointments

In order to accelerate the chronic wounds healing, we investigated the healing effects of bioactive glass and Yuunan baiyao ointments in streptozotocin-induced diabetic rats. The ointments were prepared by mixing 45S5 bioactive glass powder （16% weight） with Vaseline and different weight percentages of Yurman baiyao. Full-thickness defect wounds were created on the back of 130 SD rats and were randomly divided into 8 groups. The wound healing rates were calculated at 4, 7, 10, 14 and 21 days after surgery. The samples were harvested for further observations. Considering the wound closure rate, group 6 （with 5% Yuunan baiyao） has better wound healing performance than other diabetic groups. The lower inflammatory response was observed by gross observation and confirmed by the results of H＆E staining and TEM observation. Besides, the proliferation of fibroblasts, the formation of granulation tissue, as well as the vascularization, were improved in group 6 compared to other diabetic groups. All results suggest that bioactive glass and Yunnan baiyao ointments can accelerate the recovery of diabetes-impaired skin wounds, and comparing to other diabetic groups, group 6 （with 5% Yunnan baiyao） has better healing effect.     

Na0.5Bi0.5TiO3 phase relations: Thermodynamics and phase equilibria in the systems Bi2O3 – TiO2, Na2O – TiO2, and Na2O – Bi2O3 – TiO2

The lead-free piezoelectric material sodium bismuth titanate (NBT, Na_0.5Bi_0.5TiO₃) has attracted considerable attention owing to its promising dielectric, piezoelectric, and electrical properties. However, the literature on the binary subsystems is contradictory and there are only limited data for the ternary system. The present work surveys all of the reports of the binary subsystems Bi₂O₃ – TiO₂ and Na₂O – TiO₂ and synthesizes these data into inclusive revised versions. The compatibilities for the ternary system Na₂O – Bi₂O₃ – TiO₂ were determined experimentally, thus enabling the construction of a complete isothermal section at 800 °C. The compatibilities associated with the problematic binary subsystem Na₂O – Bi₂O₃, which experiences extreme volatilisation, were determined through the generation of the absent standard-state thermodynamic functions for the relevant binary and ternary phases, thus providing a full suite of thermodynamic data for this system. The thermodynamic stability diagrams for Na₂O, Bi₂O₃, and TiO₂ thus were calculated. The isothermal section also addresses the contradictions in the literature concerning the formation of solid solutions of Bi₁₂TiO_20-x / Bi_12-xTi_1+xO_20+0.5x, pyrochlore (Bi₂Ti₂O₇ / Na_wBi_2-xTi_2-yO_7-z), BTO (Bi₄Ti₃O₁₂ / Na_xBi₄Ti₃O_12+0.5x), and NBT (Na_0.5Bi_0.5TiO₃ / Bi_1±xNa_xTiO_3.5±x). Further, it was observed that the congruent melting point of NBT, which was determined to be 1225 °C, was preceded by the onset of gradual structural destabilization at 940 °C. Also, the NBT rhombohedral → tetragonal phase transformation was observed at an onset temperature of ∼250 °C. The present work thus provides platform data for the fabrication and reactivities of materials in the ternary system Na₂O – Bi₂O₃· TiO₂ and its binary subsystems.     

基于Moodle的《面向对象程序设计》问题驱动混合教学模式建设

传统课堂教学是教师主导的教学活动,而在线学习是以学生为主体参与的教学活动,它通过研究和探索拟建立一种新的学习模式,即问题驱动混合教学模式。该模式以Moodle教学平台为基础,以《面向对象程序设计》这门课为例进行实践。教学实践表明,这种混合教学方式,能帮助教师实现个性化教学、丰富教学手段,增进教学过程中的互动交流,提高学生学习的自主性和协作性,并进一步提高教学效果。可以促进学生的主动参与性,增强学生对学习过程的控制力,提高学习效果,而且对原有的教学组织影响不大,很容易实现平稳过渡。     

卫生经济学应用于慢性病防控决策的战略研究

为提高当前慢性病防控体系的效率,更好地遏制慢性病的流行,保护公众健康,2015年中国工程院设立了"卫生经济学应用于慢性病防控决策的战略研究"重大咨询项目。课题组调研发现,作为一种重要的卫生决策工具,卫生经济学在慢性病防控决策过程中尚处于初级应用阶段。对卫生经济学的重要性认识不足,对卫生经济学的方法的掌握和应用能力有限,制约了其在慢性病防控决策中的应用,因此建议建立多元主体参与的卫生经济学研究力量,加强卫生经济学应用于慢性病防控决策的大数据积累及应用研究,提出将卫生经济学应用于我国慢性病防控决策的战略框架。