Core–shell NTC materials with low thermal constant and high resistivity for wide-temperature thermistor ceramics

Core–shell structures have been proposed to improve the electrical properties of negative-temperature coefficient (NTC) thermistor ceramics. In this work, Al₂O₃-modified Co_1.5Mn_1.2Ni_0.3O₄ NTC thermistor ceramics with adjustable electrical properties were prepared through citrate-chelation followed by conventional sintering. Co_1.5Mn_1.2Ni_0.3O₄ powder was coated with a thin Al₂O₃ shell layer to form a core–shell structure. Resistivity (ρ) increased rapidly with increasing thickness of the Al₂O₃ layer, and the thermal constant (B) varied moderately between 3706 and 3846 K. In particular, Co_1.5Mn_1.2Ni_0.3O₄@Al₂O₃ ceramic with 0.08 wt% Al₂O₃ showed the increase of ρ double, and the change in its B was less than 140 K. The Co_1.5Mn_1.2Ni_0.3O₄@Al₂O₃ NTC ceramics showed high stability, and their grain size was relatively uniform due to the protection offered by the shell. The aging coefficient of the ceramic was less than 0.2% after aging for 500 hours at 125°C. Taken together, the results indicate that as-prepared Co_1.5Mn_1.2Ni_0.3O₄@Al₂O₃ NTC ceramics with a core–shell structure may be promising candidates for application as wide-temperature NTC thermistor ceramics.     

Microstructural and electrical changes in Ca0.9R0.1CeNbMoO8 (R = Y,Sm, Nd,La) ceramics induced by rare-earth ion doping

Rare-earth ions doped Ca_0.9R_0.1CeNbMoO₈ (R = Y, Sm, Nd, La) ceramics have been successfully prepared by solid-state method, and their modifications to the microstructure and electrical properties are also investigated. The rare-earth ions doped ceramics exhibit the scheelite structure. With the increase in the radius of rare-earth ions, the lattice distortion and bond interaction will be enhanced, and the consistency of grain size will be reduced. The ceramics exhibit negative temperature coefficient (NTC) thermistor characteristics in the temperature range of 473 K-1273 K, and the activation energy decreases with the increase of the radius of rare-earth ions. Rare-earth ions doping can increase the content of Ce³⁺ ions and promote the conductivity of ceramics. Except for Sm³⁺-doped ceramics, the high-temperature aging rate of other ceramics is less than 2%. The existence of some metastable Sm²⁺ ions in Sm³⁺-doped ceramics not only increases the activation energy, but also reduces the high-temperature stability of the ceramics.     

Novel thermal-sensitive properties of NBT-BZT composite ceramics for high-temperature NTC thermistors

We found for the first time that (1 − x) Na_0.5Bi_0.5TiO₃-xBiZn_0.5Ti_0.5O₃ (NBT–BZT) composite ceramics showed negative temperature coefficient (NTC) at a high temperature. The NBT–BZT nanopowders were successfully prepared by Pechini method. Their ceramics were sintered at 1100°C. The NBT–BZT ceramic exhibited a good linear relationship between logarithm of electrical resistivity (Inρ) and reciprocal of absolute temperature (1000/T) at 250°C–1050°C. The obtained ρ₆₀₀, ρ₉₀₀, and B_600/900 constants of the NBT–ZBT NTC thermistors are approximately 5.92 × 10⁶ to 3.01 × 10⁴ Ω cm, 7.03 × 10³ to 7.60 × 10² Ω cm and 2.3 × 10⁴-1.3 × 10⁴ K, respectively. The electrical characteristics can be tuned to the desired value by changing the Na_0.5Bi_0.5TiO₃ content in the compound. The electrical conductivity in these compounds is due to the electron jumps between Ti³⁺ and Ti⁴⁺ and oxygen-ion conductivity. Results demonstrate a tremendous potential of the studied system for perovskite materials with NTC performance.     

磺酸型离子液体的合成及其在酯化反应中的催化性能研究

以N-甲基咪唑、2-氯乙醇、对甲苯磺酰氯和苯为原料合成了氯化1-甲基-3-[α-甲基-(4-磺酸苄基)]咪唑盐、1-甲基-3-[α-甲基-(4-磺酸苄基)]咪唑硫酸氢根盐、1-甲基-3-[α-甲基-(4-磺酸苄基)]咪唑对甲苯磺酸盐三种离子液体,并用红外光谱和核磁共振对产物的结构做了表征.以乙腈为探针分子,采用红外光谱对合成的离子液体做了酸性类型的表征.考察了以上三种离子液体在壬二酸和甲醇的酯化反应中的催化性能,室温下n(壬二酸)∶n(甲醇)=1∶2时,反应4 h,壬二酸甲酯的产率可达到90.0%、选择性超过98.0%,且反应结束后产物易于分离.离子液体循环使用5次以上,催化活性没有明显降低.     

脂肪酶催化合成棕榈酸维生素C酯的研究

在溶剂相中,用固定化脂肪酶催化合成棕榈酸维生素C酯。研究了反应体系含水量、溶剂、反应温度、加酶量、加入分子筛等因素对反应的影响。结果表明,最佳反应条件为:Novo 435脂肪酶用量为反应物质量的4%,叔丁醇作溶剂,反应温度55℃,摇床转速200 r/min,反应时间36 h,转化率52%,产品纯度95%。     

甘草酸及其衍生物的活性研究进展

甘草酸是甘草中的重要成分之一,具有广泛的药理活性,尤其是其衍生物具有显著的抗炎、抗乙肝病毒、抗艾滋病毒等活性.综述了近年来国内外专家对甘草酸及其衍生物的药理活性研究新进展.     

基于时空注意力机制的加油站级客流量预测

加油站是重要的能源供给单位,对加油站站点的下一时段客流量进行精准预测,可为相关资源的调度与分配提供决策支撑。针对加油站级客流量预测问题,结合加油站客流数据的时空特征,提出一种基于注意力机制的时空网络模型。以路网结构建模的站级客流数据为输入,结合卷积神经网络、长短期记忆网络与注意力机制,解决站点间的空间依赖、短期与长期时序依赖以及长期时序依赖中的时间漂移问题,精准预测下一时段的站级客流量。在真实数据集上的实验结果表明,与历史平均模型、长短期记忆网络模型和双向长短期记忆网络模型等基线模型相比,该模型在均方误差（RMSE）、平均绝对误差与平均绝对百分比误差上均有所提升,其中RMSE提升22.89%。     

基于重建误差的任务型对话未知意图检测

现有未知意图检测模型通常将语句映射到向量空间,并使用局部异常因子算法定义密度较小的特征点为未知意图,但经交叉熵损失训练的已知意图特征簇更加狭长,簇内的整体间距、密度和分散情况不均匀,进而增加了检测难度。针对上述问题,提出一种基于自动编码器重建误差的未知意图检测模型。在训练阶段,使用融入标签知识的联合损失函数训练已知意图分类器,使已知意图特征类间距离大且类内距离小,并利用这些特征训练一个仅能获取已知意图信息的自动编码器。在测试阶段,利用自动编码器将重建误差较大的样本视为未知意图,其余样本视为已知意图正常分类。在SNIPS数据集上的实验结果表明,在已知意图占比为25%、50%、75%时,该模型的Macro F1得分相比于表现最优的增强语义的高斯混合损失基线模型分别提升了16.93%、1.14%和2.37%,能够检测到更多的未知意图样本,同时在类别分布极不平衡的ATIS数据集上也有较好的性能表现。     

改进的关联分类算法在信息化评估中的应用

在信息化评估过程中,传统关联分类算法无法优先发现短规则,且分类精度对规则次序的依赖较强。为此,提出基于子集支持度和多规则分类的关联分类算法,将训练集按待分类属性归类,利用子集支持度挖掘关联规则,通过计算类平均支持度对测试集进行分类。实验结果表明,该算法发现规则的能力和分类精度均优于传统方法。     

基于词缀库的非监督维吾尔语词切分方法

在维吾尔语中,词缀的数量有限且构词具有一定的规律性。为了提高维吾尔语词切分算法的性能,在一个词缀库的基础上,通过分析维吾尔语的基本构词规则,提出了一种改进的非监督维吾尔语词切分方法。该方法对词进行规则切分,采用MAP切分评价模型对规则切分打分,选取得分最高的规则切分作为该词的最终切分形式。在一个5000词的测试语料上进行了实验,实验结果表明,使用该方法进行维吾尔语词切分具有更高的准确率。