聚苯醚磺酸锂／共聚醚复合物的离子导电性研究

合成了３种不同磺化度的聚苯醚磺酸锂（ＳＰＰＯＬｉ）与Ｐ（ＭＥＯ１６－ＡＭ）／ＳＰＰＯＬｉ复合物。研究了复合物的离子导电性与磺化度，组成比及增塑剂含量的关系。含４０％（ｍａｓｓ）增塑剂的复合物具有单离子导电特征，锂离子迁移数高达０．９７，室温电导率达２×１０－５Ｓ／ｃｍ。     

Experimental data and approximate estimation for dissociation time of hydrate plugs

New experimental data coupled with a numerical model and an approximate solution are proposed to predict dissociation time of hydrate plugs in oil sub-sea pipelines. The experimental hydrate plugs are dissociated by the method of symmetric depressurisation, both in a specially designed apparatus and a classical batch reactor. The agreement between the estimation of the model and the experimental data and the simplicity of the approximate equation presents an advantage in estimating the time of hydrate plug dissociation in pipelines.     

不同形状垃圾焚烧过程中挥发份的释放仿真研究

假设垃圾加热到核心温度为760℃时认为其挥发份全部析出，把固体垃圾看成平板、球形、柱形三种基本形状。建立三种形状垃圾的非稳态导热计算的数学模型和仿真模型，并在模型上进行仿真实验。通过研究垃圾焚烧过程中挥发份生成和燃烧的基本规律，得到垃圾尺寸和烟气流速对挥发份析出的影响．提出改善垃圾焚烧的措施。     

The ponding problem on elastic membranes: an analog equation solution

 In this paper, the nonlinear response of elastic membranes with arbitrary shape under partial and full ponding loads has been analyzed. Large deflections are considered, which result from nonlinear kinematic relations. The problem is formulated in terms of the displacements components and the three coupled nonlinear governing equations are solved using the analog equation method (AEM). The membrane may be prestressed either by prescribed boundary displacements or tractions. Using the concept of the analog equation the three coupled nonlinear equations are replaced by three uncoupled Poisson's equations with fictitious sources under the same boundary conditions. Subsequently, the fictitious sources are established using a procedure based on the BEM and the displacement components as well as the stress resultants at any point of the membrane are evaluated from their integral representations. In addition to the geometrical nonlinearity, the ponding problem is itself nonlinear, because the ponding load depends on the deflection surface that it produces. Iterative schemes are developed which converge to the equilibrium state of the membrane under the ponding loads. Several membranes are analyzed which illustrate the method and demonstrate its efficiency and accuracy. The method has all the advantages of the pure BEM, since the discretization and integration is limited only to the boundary. Received 28 July 2001     

Studies on the structural and ionic transport properties at elevated temperatures of La1−xMnO3±δ synthesized by a wet chemical method

Structural transformation and ionic transport properties are investigated on wet-chemically synthesized La_1−xMnO₃ (x=0.0–0.18) compositions. Powders annealed in oxygen/air at 1000–1080 K exhibit cubic symmetry and transform to rhombohedral on annealing at 1173–1573 K in air/oxygen. Annealing above 1773 K in air or in argon/helium at 1473 K stabilized distorted rhombohedral or orthorhombic symmetry. Structural transformations are confirmed from XRD and TEM studies. The total conductivity of sintered disks, measured by four-probe technique, ranges from 5 S cm⁻¹ at 298 K to 105 S cm⁻¹ at 1273 K. The ionic conductivity measured by blocking electrode technique ranges from 1.0×10⁻⁶ S cm⁻¹ at 700 K to 2.0×10⁻³ S cm⁻¹ at 1273 K. The ionic transference number of these compositions ranges from 3.0×10⁻⁵ to 5.0×10⁻⁵ at 1273 K. The activation energy deduced from experimental data for ionic conduction and ionic migration is 1.03–1.10 and 0.80–1.00 eV, respectively. The activation energy of formation, association and migration of vacancies ranges from 1.07 to 1.44 eV.     

Electrical conductivity in iodine-doped ethyl cellulose

The electrical conductivity of solution-grown ethyl cellulose (EC) films, 5–30 μm thick, has been studied in the sandwich configuration (metal–EC–metal) as a function of iodine concentration from 0.5 to 5.0 wt% ratio. The studies were conducted in the temperature range 333–383 K, while the field was varied over the range (3.0–5.5) × 10⁴V/cm. Aluminium was used as the lower electrode, while the upper electrode was of Al, Ag, Cu, Au or Sn. Certain transient effects such as a large burst of current immediately after the application of field were observed. An attempt was made to identify the nature of the current by comparing the observed dependence on electric field, electrode material and temperature with the respective characteristic features of the existing theories of electrical conduction. The results show that the electrical conduction follows Ohm's law at lower fields, while at higher fields, space-charge limited current (SCLC) was observed. It was also found that Richardson–Schottky emission was responsible, to some extent, for the transport of charge carriers in the polymer. The conductivity of the films increased on doping with iodine. The dopant molecules are considered to act as additional trapping centes and provide links between the polymer molecules in the amorphous region, thus resulting in the formation of charge transfer complexes.     

A double-layer current conduction model for high-κ gate dielectric materials with interfacial oxide or silicate layer

The current-voltage (I-V) characteristics of metal-oxide-semiconductor (MOS) structures with hafnium oxide as the gate dielectric film were studied. Sharp shifts from a low-voltage ohmic regime to a tunneling conduction were observed in the high-voltage range. The paper demonstrates that this behavior can be described very well with a double-layer dielectric model. Excellent fittings of the experimental curves were obtained and the related key structural and physical parameters were obtained. The model fitting further suggests the optimal annealing conditions for preparing the hafnium oxide films.     

Application of boundary element method to 3-D problems of coupled thermoelasticity

This paper deals with a new boundary element method for analysis of the quasistatic problems in coupled thermoelasticity. Through some mathematical manipulation of the Navier equation in elasticity, the heat conduction equation is transformed into a simpler form, similar to the uncoupled-type equation with the modified thermal conductivity which shows the coupling effects. This procedure enables us to treat the coupled thermoelastic problems as an uncoupled one, A few examples are computed by the proposed BEM, and the results obtained are compared with the analytical ones available in the literature, whereby the accuracy and versatility of the proposed method are demonstrated.     

Time‐dependent heat transfer coefficient of a wall

A time‐dependent coefficient of heat transfer is proposed for the computation of thermal power required, so that a room temperature reaches a desired value within a given time. A mathematical formulation of the room heating transient phenomenon is constructed in a dimensionless form. Using an integral approximate solution an analytical expression for this coefficient is provided and it is verified by diagrams adopted by DIN 4701. Copyright © 2003 John Wiley & Sons, Ltd.     

PLC在原料系统的应用

阐述了硅铁生产中焦碳生产输送系统的工作原理和工艺要求，介绍了PLC在原料输送系统中的应用，给出了PLC的I／O接线图及程序框图，提出了工业原料生产输送控制系统的设计特点。