М.Ю.巴利新的粉末冶金理论

巴利新(原苏联)是世界知名的粉末冶金学家。1938年他提出的压制方程ln p=—AV+B仍为美国1984年出版的《金属手册》第九版第七卷‘粉末冶金’所引用。早在70年代,巴利新就根据他提出的一系列新理论,提出一个新的压制或固结方程式组α=~2z,f=F(,α),p=pαf,但除原苏联外,该方程鲜为人知。鉴于此,本文作者对巴利新60年代以来发表的一系列关于粉末冶金理论的论著进行了整理,现扼要地予以阐述,这对我国粉末冶金理论的研究或许是有益的。     

Mössbauer effect studies and X-ray diffraction analysis of cobalt ferrite prepared in powder form by thermal decomposition method

Cobalt ferrite (Co_xFe_3?xO₄) is prepared in powder form by thermal decomposition of iron and cobalt salts and is analysed by X-ray diffraction and Mössbauer spectroscopic techniques. The variation of Mössbauer parameters, lattice parameters and crystallite size of the products formed with variation in the composition of Fe and Co ratios are studied. The studies confirm the formation of nano-size cobalt ferrite particles with defect structure and it is found to be maximum for the Fe : Co = 60 : 40 ratio of the initial precursor oxides.     

粉末冶金温压工艺的研究进展及其展望

综述了粉末冶金温压工艺的研究进展,概述了温压工艺的粉末原料、聚合物、温度、压力、烧结环节对温压工艺的影响和温压工艺的致密化机理。详细介绍了温压工艺的新进展—流动温压、高压温压等,并对其应用前景进行了展望。     

Optimal estimation of parameters of dynamical systems by neural network collocation method

In this paper we propose a new method to estimate parameters of a dynamical system from observation data on the basis of a neural network collocation method. We construct an object function consisting of squared residuals of dynamical model equations at collocation points and squared deviations of the observations from their corresponding computed values. The neural network is then trained by optimizing the object function.The proposed method is demonstrated by performing several numerical experiments for the optimal estimates of parameters for two different nonlinear systems. Firstly, we consider the weakly and highly nonlinear cases of the Lorenz model and apply the method to estimate the optimum values of parameters for the two cases under various conditions. Then we apply it to estimate the parameters of one-dimensional oscillator with nonlinear damping and restoring terms representing the nonlinear ship roll motion under various conditions. Satisfactory results have been obtained for both the problems.     

粉末冶金低合金钢的制备和性能研究进展

从粉末制备、成形工艺、烧结工艺和组织控制等方面,系统的介绍了国内外粉末冶金低合金钢的制备技术,并对其研究方向和应用前景进行了展望。     

An efficient algorithm for characteristic tracking on two-dimensional triangular meshes

Tracking characteristics on unstructured meshes is an important part of many numerical methods in computational fluid mechanics. In this paper, we propose an efficient algorithm for characteristic tracking on two-dimensional unstructured triangular meshes. Numerical experiments, including an example for applying this algorithm with the Eulerian-Lagrangian localized adjoint method (ELLAM) to solve a convection-dominated convection-diffusion problem, are presented to demonstrate the efficiency of this algorithm.     

Solid-state NMR as a probe of porous catalysts and catalytic processes

The power of solid-state NMR for the interrogation of porous catalytic materials is illustrated using three examples. First, for the investigation of catalytic processes occurring within the confines of a microporous catalyst NMR is shown to reveal both the details of shape-selectivity and the nature of internal surface species. Second, NMR is shown to be a powerful short-range tool to reveal precise structural information on highly disordered microporous titanosilicates. Despite long-range disorder the short-range order is maintained and can be easily studied. Finally, the same utility of probing short-range chemical phenomena is shown to be crucial for the investigation of novel-ordered-amorphous-mesoporous materials known generically as M41S. This class of material is currently one of the most important with potential catalytic application.     

激光光束质量因子的研究进展

本文详细分析了各种光场下光束质量M2因子。在不同的场中,A.E.Siegman当初所定义的M2因子,已经有了很大的变化,因而M2因子的特性也与当初不同,不仅M2因子可以大于等于1,而且可以小于1,甚至小于0。其反映的物理意义,也从经典场中的衍射极限倍数,变化为非经典场中的准直性量度以及对空间相干性的某些反映。此外还列举并分析了几种特殊的光束质量因子,最后讨论了M2因子应用的问题并指出了其局限性。     

Thermally and plastically induced residual strains in textured Zircaloy-2 plate

The residual intergranular strains in textured Zircaloy-2 plate samples induced by cooling from 823 K to ambient temperatures, by cold-rolling by 1.5% and 25% and by deforming in tension by 1.5% were measured by neutron diffraction. The strong rolling texture, which gives rise to two ideal orientations, permitted the interpretation of much of the data in terms of strain tensors for the two orientations. The experimental results were compared with calculations based on the elasto-plastic self-consistent model with no adjustable parameters. Close agreement was obtained for samples in the as-cooled state and deformation in tension by 1.5% but the agreement is less satisfactory for cold-rolling.     

EBSD investigation of SiC for HTR fuel particles

Electron back-scattering diffraction (EBSD) can be successfully performed on SiC coatings for HTR fuel particles. EBSD grain maps obtained from thick and thin unirradiated samples are presented, along with pole figures showing textures and a chart showing the distribution of grain aspect ratios. This information is of great interest, and contributes to improving the process parameters and ensuring the reproducibility of coatings.