电沉积法制备铜分散电极

研究了电沉积制备铜分散电极的方法,通过对阴极极化曲线的测试,考察了电流密度及不同冲击电流方式对铜粉粒度的影响。结果表明:适当的电流密度、合适的分散剂、间歇式的电流是得到较细铜粉的条件。同时对铜分散电极的电化学性质进行初步测试,结果表明铜粉细化以后,铜分散差电池的电动势值有所上升。     

硼酸铝晶须增强环氧树脂和双马来酰亚胺树脂体系的研究

本文以硼酸铝晶须为增强剂，以4，5-环氧环己烷-1，2-二甲酸二缩水甘油酯(TDE-85)，甲基纳狄克酸酐(MNA)、N，N’-二胺基二苯甲烷型双马来酰亚胺(BMI)/O，O′-二烯丙基双酚A(BA)体系分别作为基体制备晶须增强复合材料。研究了晶须对树脂的尺寸、表面处理方法、含量对树脂体系力学性能和热性能的影响；通过扫描电子显微镜(SEM)分析了浇注体的弯曲、冲击断口，研究晶须的增强机理。     

Effect of Synergistic Anticorrosion Treatments on Cycling Stability of Mg-Based Hydrogen Storage Electrode

In this paper, any two of the three anticorrosion agents, that is emulsifier (OP-10), soluble glass (Na2O·nSiO2) and glycerin (C3H8O3), were treated simultaneously on the surface of amorphous (a-) MgNi+5% Ml2Mg17 (Ml denotes the lanthanum-rich mish metal) electrode and the electrolyte. Effect of the synergistic anticorrosion treatment on charging/discharging cycle stability of the electrode was investigated. Contrasted with single treatment method, the cycling stability of the electrodes was further improved. The desirable synergistic anticorrosion method was that the electrode was treated by the soluble glass, and that OP-10 was added into the electrolyte. The cyclic voltammogram (CV) results of the electrode show clearly that the anticorrosion agent can change the electrochemical activity and mechanism of the electrode. The concentration of the anticorrosion agent in the electrolyte treated by the synergistic anticorrosion method was also investigated. The appropriate concentration of the anticorrosion agents in the electrolyte is 0.143%.     

石油工程项目管理机制

为了妥善处理石油工程项目中的委托-代理关系,研究了委托-代理模型和石油工程项目管理中的激励约束机制,分析了激励机制、监督机制和选择机制在石油工程项目运行管理中的重要性.只有用有效的契约去激励技术服务公司,才能使服务公司在追求自身效益最大化的同时也为实现石油公司的最大效益而尽最大努力;只有对技术服务公司的作业实施监督,才能形成对技术服务公司的有效约束;采用激励性承包方式、实施综合性评标和组建工程项目动态联盟能够防止逆向选择.分析表明,在最优激励安排下,激励强度与项目面临的不确定性、承包商的边际成本及其风险规避系数负相关,与承包商的边际生产率正相关,还与其他可观测变量相关.在最优监督水平下,作业公司的边际生产率越高,边际成本越低,越容易监督,监督带来的边际收益越高.对于那些监督比较困难的项目,可以通过加强惩罚力度的方式弥补难以有效监督的不足.激励性承包方式可以减小逆向选择造成的危害,组建动态联盟可以进一步加强激励作用,降低道德风险,解决逆向选择问题.参8     

Corrosion Inhibition Mechanism with Spilt Cell Technique of Rare Earth Metal on LC4 Al Alloy

A new method of studying the corrosion inhibition mechanism of rare earth metal(REM) on LC4 Al alloy with the spilt cell technique was studied. The principle and experimental method of the spilt cell technique were analyzed. By measuring the change of net-electric current between the two electrodes caused by the change of the amount of oxygen in the solution and the addition of CeCl₃, the influence of corrosive performance of CeCl₃ on LC4 super-power aluminum alloy in the 0.1 mol·L⁻¹ NaCl solution was investigated. Meanwhile, the conditional changes of pH values, CeCl₃ solution, additire and time of performance were also studied. Finally, the features of electrode surface were revealed by using SEM and X-ray energy-dispersive spectrometry (EDS). By combining these with other electric chemical techniques, such as potential-time curve, polarization curve et al.     

真空制盐蒸发结晶器的设计与实践

真空蒸发制盐外热式强制逆循环轴向出料蒸发结晶器，经多个厂家生产应用实践证明是成功的，具有生命力的。这种新型结构，作为一项新技术新设备应加强研究，总结提高，推广应用。不断完善。文章从流体力学、结晶机理角度要求，到具体工程设计参数和材质选用。论述了该罐的特点。     

黄河下游河道萎缩致灾机理探讨

本文基于水力学原理，结合实体模型试验及原型实测资料分析，探讨了黄河下游河道萎缩的概念、致灾效应和致灾机理。分析表明，河道萎缩是造床过程中河道排洪输沙功能衰退的一种演变现象，其致灾效应是使洪水涨率增大，同流量下洪水水位不断抬升。致灾的现象主要表现在畸型河势增加、工程险情增多、直接造成工程损失及滩区经济损失等。试验研究揭示，主河槽宽度缩窄造成洪水水位涨幅增大，河底平均高程抬升和过水断面面积减小造成洪水水位起涨的基准面抬升是河道萎缩致灾的主要原因。河道萎缩致灾效应的大小与萎缩模式有关，其中以“集中淤槽”模式所形成的致灾效应尤为明显。     

Reaction scheme and kinetic modelling for the MTO process over a SAPO-18 catalyst

A kinetic model for simulation of the MTO process over SAPO-18 catalyst in a wide range of operating conditions has been proposed. The kinetic model predicts the experimental evolution of reaction products with time on stream, which follows three consecutive periods: initiation (where olefin production increases), a period of maximum olefin production and a period in which this production decreases. The kinetic scheme takes into account these three steps that evolve with time on stream: formation of active intermediate compounds, an step where olefins are formed by reaction of oxygenates (methanol/DME) with these intermediates and deactivation of intermediates by degradation to coke. The presence of water in the reaction medium attenuates the reaction rate of these steps. Discrimination of kinetic equations and calculation of the parameters of best fit have been carried out by solving the mass conservation equations of the individual components of the kinetic scheme together with the kinetic equation for deactivation and taking into account the effect of water on the kinetics of each step.     

交联聚合物驱油技术研究及应用

交联聚合物驱油技术是聚合物驱油技术的发展和改善，与单纯聚合物相比，该体系具有抗剪切、耐温耐盐、在多孔介质中阻力系数大等特点，能较大程度改善油藏非均质程度，提高原油采收率。以其作为驱油体系具有创新性，可更好地适应高含水期油藏特性，是一种集调剖和驱替于一体的新型驱油技术。文中对交联聚合物的交联机理进行了探讨，给出了室内评价结果，分析了该技术在孤岛油田渤19块的应用效果，现场应用表明，该技术增油降水效果显著，是比较理想的提高EOR的新方法。     

论剪切质量的提高

通过对飞剪剪切长度，精度，剪刃间隙和压板机构等参数的优化，来提高钢板的剪切质量。