环氧氯丙烷中有机杂质组分的气相色谱法测定

介绍了在环氧氯丙烷国家标准制定过程中对环氧氯丙烷中有机杂质组分测定方法的改进。通过采用毛细管柱气相色谱法,对分离条件、毛细管柱选择等进行了试验和讨论。试验结果表明,采用毛细管柱气相色谱法,选用N2作为载气,分流比50∶1,并采用程序升温:柱初温40℃(保持5 min)→10℃/min→180℃(保持30 min)的条件下可获得更好的分离效果及准确度,该方法测得各杂质组分的相对标准偏差为0.0113%~0.0377%,回收率为93.3%~102.9%。能满足生产中质量控制和产品出厂分析的需要,保证了国家标准分析方法的先进性。     

高温变换催化剂制备条件的神经网络优化

将影响低汽气比条件下LB型节能高温变换催化剂活性的主要因素作为人工神经网络的特征输入向量,将全部实验数据分为训练集和预测集,运用Matlab神经网络工具箱,按改进的Bayes自动归一化算法建立反向传播神经网络模型,不仅可防止网络陷入局部最小,而且提高了网络训练精度和泛化能力。适当拓宽正交实验各因素的水平范围,经过不同因素、不同水平间的组合模拟,预测出LB型节能高温变换催化剂的最佳制备条件为氧化铈质量分数0.76%、氧化铜质量分数5.8%、氧化铬质量分数8.6%、氧化镧质量分数1.0%、铁液浓度92 g/L、中和过程最终pH值9.5。在最佳条件下试制催化剂在低汽气比下的平均活性达77.6%。     

苯乙烯适宜贮存工艺条件研究

测定了贮存时间、阻聚剂TBC(叔丁基邻苯二酚)含量和铁锈量对苯乙烯聚合物和过氧化物含量的影响,通过均匀设计实验考察了苯乙烯聚合物含量与贮存条件的关系.结果表明,当苯乙烯聚合物的质量分数不高于10 mg/kg(优等品指标)时,在贮存温度为20℃条件下,苯乙烯可贮存8~9 d;在30℃时,可贮存5 d;由拟合得到的苯乙烯聚合物含量与贮存条件的关系式解得:贮存温度为18℃,TBC质量分数为13.8 mg/kg,贮存时间为12 d.     

5G通信用化工新材料国内外市场现状及未来发展重点分析

简述了5G通信行业替代4G通信行业新材料的变化.重点分析了5G通信用化工新材料性能要求及国内外市场情况.指出5G通信行业及衍生市场的发展,将为我国化工新材料带来巨大的发展机遇.     

Robust consensus algorithm for multi-agent systems with exogenous disturbances under convergence conditions

In this paper, a robust consensus algorithm is developed and sufficient conditions for convergence to consensus are proposed for a multi-agent system (MAS) with exogenous disturbances subject to partial information. By utilizing H_∞ robust control, differential game theory and a design-based approach, the consensus problem of the MAS with exogenous bounded interference is resolved and the disturbances are restrained, simultaneously. Attention is focused on designing an H_∞ robust controller (the robust consensus algorithm) based on minimisation of our proposed rational and individual cost functions according to goals of the MAS. Furthermore, sufficient conditions for convergence of the robust consensus algorithm are given. An example is employed to demonstrate that our results are effective and more capable to restrain exogenous disturbances than the existing literature.     

Uncooperative gait recognition by learning to rank

Gait is a useful biometric because it can operate from a distance and without subject cooperation. However, it is affected by changes in covariate conditions (carrying, clothing, view angle, etc.). Existing methods suffer from lack of training samples, can only cope with changes in a subset of conditions with limited success, and implicitly assume subject cooperation. We propose a novel approach which casts gait recognition as a bipartite ranking problem and leverages training samples from different people and even from different datasets. By exploiting learning to rank, the problem of model over-fitting caused by under-sampled training data is effectively addressed. This makes our approach suitable under a genuine uncooperative setting and robust against changes in any covariate conditions. Extensive experiments demonstrate that our approach drastically outperforms existing methods, achieving up to 14-fold increase in recognition rate under the most difficult uncooperative settings.     

纳米SiO2粉体的制备与研究

纳米SiO2粉体的制备是以硅酸钠和盐酸为原料，添加适宜的稳定剂(非离子表面活性剂)和分散剂，在适宜的pH值和温度下，采用化学沉淀法合成。研究表明，要得到性能优良纳米的SiO2粉体，最佳工艺条件为：温度20～40℃，pH=6，反应液质量浓度P1=20g／L，P2=1．20g／L，反应时间15min。结果表明：制备的纳米SiO2粒径30～50nm，比表面积大，分散性好，质量优良，可达到产业化的生产。     

焦化污水处理工艺的优化与改造

通过对焦化污水处理过程影响因素的研究,优化了AAO污水处理工艺,对厌氧池进行了改造。使污泥的NO3-负荷减少,氨氮的反硝化率和COD的去除率显著提高。优选了混凝药剂,在混凝反应池增设了空气搅拌管,提高了悬浮物、色度等指标。实现了出水水质达标,使处理后污水可用于熄焦。     

民族元素在游戏美术视觉形式美中的运用探究

网络游戏是一种新兴的娱乐方式,人们在进行网络游戏时,会受到其文化思想内容的影响。作为新兴的文化娱乐活动,网络游戏具有传播文化的使命。在色彩缤纷的网络游戏里,传统视觉元素是重要的表现素材,探究民族元素在游戏美术视觉形式美中的运用,对于网络游戏的民族化发展有重要的现实意义。     

酸性铵盐沉钒条件实验研究

以温度、时间、搅拌强度为变量，以沉淀率、抽滤后滤饼含水量、烘干后多钒酸铵(APV)中杂质含量等作为评价指标，对酸性铵盐沉钒条件进行了研究. 结果表明：以含钒30 g/L左右的溶液为原料，加硫酸铵后用硫酸调节pH至2.2左右，沸水浴(95℃)中沉淀120 min左右，桨式搅拌转速300 r/min，可获得99%以上的沉淀率，抽滤滤饼含水量20%以下，烘干后APV含Na 0.70%~ 1.08%, S 0.78%~1.20%.