Effect of the addition of acrylonitrile/ethylene–propylene–diene monomer (EPDM)/styrene graft copolymer on the morphology–properties relationships in poly(styrene‐co‐acrylonitrile)/EPDM rubber blends

Blends of poly(styrene‐co‐acylonitrile) (SAN) with ethylene–propylene–diene monomer (EPDM) rubber were investigated. An improved toughness–stiffness balance of the SAN/EPDM blend was obtained when an appropriate amount of acrylonitrile–EPDM–styrene (AES) graft copolymer was added, prepared by grafting EPDM with styrene–acrylonitrile copolymer, and mixed thoroughly with both of the two components of the blend. Morphological observations indicated a finer dispersion of the EPDM particles in the SAN/EPDM/AES blends, and particle size distribution became narrower with increasing amounts of AES. Meanwhile, it was found that the SAN/EPDM blend having a ratio of 82.5/17.5 by weight was more effective in increasing the impact strength than that of the 90/10 blend. From dynamic mechanic analysis of the blends, the glass‐transition temperature of the EPDM‐rich phase increased from ?53.9 to ?46.2°C, even ?32.0°C, for the ratio of 82.5/17.5 blend of SAN/EPDM, whereas that of the SAN‐rich phase decreased from 109.2 to 108.6 and 107.5°C with the additions of 6 and 10% AES copolymer contents, respectively. It was confirmed that AES graft copolymer is an efficient compatibilizer for SAN/EPDM blend. The compatibilizer plays an important role in connecting two phases and improving the stress transfer in the blends. Certain morphological features such as thin filament connecting and even networking of the dispersed rubber phase may contribute to the overall ductility of the high impact strength of the studied blends. Moreover, its potential to induce a brittle–ductile transition of the glassy SAN matrix is considered to explain the toughening mechanism. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1685–1697, 2004     

纯钨MIM黏结剂的优化及其流变性能

为了获得适合纯钨注射成形的黏结剂,通过热力学计算和喂料的流变实验,系统地研究了黏结剂组元的相容性和不同配方的蜡基黏结剂的流变性能,分析了多种因素对喂料黏度的影响,综合评价了不同黏结剂构成的喂料的流变性能,并对喂料进行了SEM观察,结果表明：所选用的黏结剂体系中各组元之间有很好的相容性,当PW与其他组元的质量比大于4时,表现为热力学相容性;由60%PW-10%HDPE-12%PS-13%PP-5%SA组成的黏结剂的流变性能最好,其综合模塑性指数为7.07 m2/N.s.K,SEM结果显示其喂料相当均匀.     

New CFD Validation Method with Application to Verify Computations of Near Wall Flows

For high Re number flows, a new computational fluid dynamics (CFD) validation method, namely, wall-surface compatibility criteria method and also called Gaos criteria, is proposed to verify near wall flows. As examples, Gaos criteria method and other two CFD verification methods (analytic solutions method and grid convergence analysis) are used to verify FLUENTs near wall flows solutions for two-dimensional incompressible laminar stagnation-point flows. The exact solution of the Navier-Stokes equations for laminar stagnation-point flows satisfy accurately all Gaos criteria, numerical simulations of laminar stagnation-point flows show that when physical parameters (the pressure coefficient and the Stanton number at wall surface) achieve convergence with more and more fine-screen grid, a part of Gaos criteria are not satisfied.     

中印贸易互补性实证分析

以比较优势理论和产业内贸易理论为依据,利用近58来的贸易统计数据,计算显示比较优势、Brulhart指标、贸易特化系数（TSC）的测度指数值及其变动趋势．分析结果表明,中印两国具有很强的产业间贸易互补性,但产业内贸易互补性不强,推动中印贸易的主要是产业间贸易,产业内贸易所占比重较少,并预测出中印贸易互补性有增强趋势．     

多功能吉赫兹横电磁波小室设计

目前一般的GTEM(吉赫兹横电磁波)小室大都用于EMS(电磁抗扰度)测试,而针对于EMI(电磁干扰)测试的尚不多见.介绍了一种既可用于EMS测试又可用于EMI测试,且还可用于高频电路辐射机理诊断的多功能GTEM小室,给出了该GTEM小室的结构设计方法和测量原理,阐述了利用该GTEM进行高频电路辐射机理诊断的实现方法.GTEM小室设计方案采用的是多极矩模型实现,可将近场测量结果转换为标准远场测量结果(如电波暗室或开域场).此外,利用该GTEM小室以及近场电磁场探头和频谱分析仪对被测设备进行近场测量,即可得出被测设备的辐射机理测量结果.     

石油树脂对热熔胶、压敏胶粘接性能的影响

介绍了石油树脂的分类、增粘树脂的结构特点,国内外热熔胶、压敏胶用石油树脂发展,热熔胶对石油树脂的性能要求;论述了石油树脂与聚合物之间的相客性、石油树脂的软化点、熔融粘度等对热熔胶粘接性能的影响,展望了石油树脂的生产和发展方向.     

丙烯酸酯类无皂LIPN阻尼材料的合成和动态力学性能

采用无皂乳液分步聚合法合成了一系列LIPN阻尼材料，利用动态粘弹谱研究了其动态力学性能。结果表明：网络组分的相容性对阻尼性能的影响显，第三个网络的引入，显地改善了网络组分间的相容性，得到了阻尼性能优良的材料；交联剂用量在一定范围内变化有助于提高涂膜的阻尼性能；通过引入含羧基的共聚组分，提高了材料的高温阻尼性能。     

偶联剂与甘蔗渣／PVC复合材料性能的研究

分别用硅烷偶联剂KH560和钛酸酯偶联剂NDZ311对甘蔗渣/PVC复合体系进行处理。研究了两种处理方法对甘蔗渣/PVC复合材料力学性能、界面形态、耐水性能和加工性能的影响。结果表明,与未处理的相比,两种处理方法都改善了甘蔗渣和PVC之间的界面相容性,界面黏结得到增强,使复合材料的强度和韧性有了较大的提高,同时改善了甘蔗渣/PVC复合材料的加工性能。钛酸酯偶联剂处理对甘蔗渣/PVC复合材料性能的影响更为显著,当其用量为1%时,复合材料的拉伸强度和冲击韧性均得到提高,其中拉伸强度提高了55%。     

Preparation of a self‐compatibility alloy via a seed‐graft concentrated‐emulsion pathway

A novel polymerization procedure, the concentrated‐emulsion graft polymerization of styrene monomer with poly(butyl acrylate) seed, was proposed for the production of a self‐compatibility macromolecule alloy. The effects of the butyl acrylate content, sodium dodecyl sulfate concentration, and polymerization temperature on the graft ratio were investigated. Scanning electron microscopy, transmission electron microscopy, and impact strength were used to characterize the microstructure and mechanical performance of the self‐compatibility macromolecule alloy. The results showed that increasing the butyl acrylate content, reducing the sodium dodecyl sulfate concentration, and improving the polymerization temperature all favored an increased graft ratio, which resulted in increased impact strength of the self‐compatibility macromolecule alloy. Therefore, the concentrated‐emulsion polymerization method is particularly suitable for seed‐graft polymerization. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2915–2920, 2002; DOI 10.1002/app.10288     

SEBS/PP共混材料的研究及其进展

SEBS是一种用途广泛的新型弹性体材料,在常温下具有高弹性,高温下可直接加工成型。由于SEBS具有优异的耐臭氧、耐氧化、耐紫外线和耐候性能等,因此,应用范围广于普通SBS材料。但是,SEBS耐溶剂性和耐油性较差,常通过与其他材料共混改性来增强其加工性能。文章重点概述了苯乙烯-乙烯-丁烯-苯乙烯(SEBS)与聚丙烯(PP)共混材料的微观结构、相容性以及结构与性能的研究进展,介绍了近年国内外SEBS/PP共混改性的研究成果,包括填充油、无机材料、PPO、PC和PA6等改性体系,并比较了这些改性技术对SEBS/PP共混体系微观结构及性能的影响,近年内,SEBS/PP共混材料的理论研究和工程应用会有长足发展。