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71.
Mahendra Nath Roy Bhoj Bahadur Gurung Vikas Kumar Dakua 《International Journal of Thermophysics》2006,27(5):1539-1550
Electrolytic conductivities of potassium halides, KX (X = Cl−, Br−, I−) have been investigated in 10, 20, and 30 mass% glycerol + H2O mixtures at 298.0, 308.0, and 318.0 K. The conductance data have been analyzed by the Fuoss-conductance–concentration equation in terms of the limiting molar conductance (Λ0), the association constant (K
A
), and the distance of closest approach of ion (R). The association constant (K
A
) tends to increase in the order: 10 mass% < 20 mass% < 30 mass% glycerol + water mixtures, while it decreases with temperature. Thermodynamic parameters ΔH
0, ΔG
0, and ΔS
0 are obtained and discussed. Also, Walden products (Λ0η) are reported. The results have been interpreted in terms of ion–solvent interactions and structural changes in the mixed solvents. 相似文献
72.
In a fin-tube heat exchanger the contact between fin collar and tube surface is obtained through mechanical expansion of tubes. Since the interfaces between the tubes and fins consist partially of metal-to-metal contact and partially of air, the features of heat transfer through the contact interfaces have not been fully investigated. The present study aims at the development of a new tool including an experiment and a numerical calculation for the estimation of the thermal contact conductance between the fin collar and tube surface, and pursues the evaluation of the factors affecting the thermal contact conductance in a fin-tube heat exchanger. Heat exchangers fabricated for the current study have been put to the test for heat balance in a vacuum chamber with water as an internal fluid. And a finite difference numerical scheme has been used for the data reduction of the experimental data to evaluate the thermal contact conductance. Fin-tube heat exchangers employed in the current research are of tube diameter of 7 mm with different tube expansion ratios, fin spacings, and fin types. The results of the present study imply that these parameters as well as hydrophilic fin coating have a significant effect on the thermal contact conductance. It has been discovered that the portion of the thermal contact resistance is not negligible compared with the total thermal resistance in a fin-tube heat exchanger, and this means that in order to reduce the thermal contact resistance thoughtful care should be taken in fabricating heat exchangers. 相似文献
73.
针对目前光伏发电系统采用的固定电压法、增量电导法等最大功率点跟踪控制技术跟踪速度慢、精度不佳的问题,提出采用变步长电导增量法进行最大功率点跟踪控制;为了控制光伏系统中电网电流和直流母线电压,采用输入输出反馈线性化控制技术,使得系统的功率因数和直流母线电压可用相同的算法进行控制。在Matlab/Simulink环境下对基于变步长电导增量法算法与输入输出反馈线性化控制技术的光伏发电系统进行了建模仿真,结果表明,采用反馈线性化技术控制逆变器后,日照强度和温度变化不会对电网功率因数产生影响;变步长电导增量法提高了光伏发电系统的动态和稳态性能,且降低了电网电流的总谐波失真率。 相似文献
74.
75.
Abstract In double‐porosity and multiple continuum models the fractured rock domain can be simplified as two overlapping continua, one for the matrix block system and the other for the fracture network. In this case, it is necessary to define an exchange term accounting for the transfer of fluid and solute masses between the two continua. A newly derived geometric parameter appears in the fluid exchange term, and is valid for any point‐centered block. The geometric parameter is more general and has a clear physical meaning. It is a function of both the shape and the size of the matrix block and agrees well with the double porosity model. The geometric center and conductance of the element is different under the quasi‐steady state compared to the steady state. Quasi‐steady condition is more suitable than steady state condition for modeling fractured media. 相似文献
76.
The present work applies the regularized boundary integral equations that are newly developed to treat the thermoelastic field in thin anisotropic media. For the anisotropic thermal field, a direct domain mapping technique is applied with a unique interface condition that considers the heat conductance relation. By incorporating the heat conductance effect, the paper investigates how interfacial thermal stresses between generally anisotropic materials vary with the heat conductance coefficient. Accounting for the thermal conductance effect, the paper presents the complete algorithm for computing the thermal as well as the subsequent elastic fields on interfaces between dissimilarly adjoined anisotropic composites. 相似文献
77.
Hot-rolled steel coils are stored upon manufacturing to cool to about 50°C. High temperatures of coiling cause thermal stresses during the cooling stage that result in spot welding between strip layers of coil. Under these conditions, surface defects or strip ruptures may occur during uncoiling. This paper will initially introduce the heat transfer model in the coil based on stress-dependent thermal conductivity in the radial direction of the coil. The two approaches of “solid body” and “thin-walled, concentric cylinders” for thermal stress analysis will then be used to compute the thermal compressive stresses in the coil. Comparison of the results obtained from these two approaches in the mathematical model reveals that the solid body approach overestimates the thermal stresses when compared to the thin-walled concentric cylinders approach, the inequality rising with reduced strip thickness. This difference, however, is found to have no considerable impact on predicting coil temperature. 相似文献
78.
A compact Ids model with physical drain-conductance (gds) modeling for deep-submicron MOSFETs is formulated based on first-principle momentum-/energy-balance equations, which simultaneously includes the hot-electron and thermoelectric effects in a unified compact form with two fitting parameters and one-step extraction. The model has been verified with 0.18-μm experimental data with good gds prediction. 相似文献
79.
针对尿素水解系统处理后工艺冷凝液电导持续超标现象,分析问题的根本原因,制订有效措施加以解决。 相似文献
80.
Introduction of photochromic properties into semiconductors confers semiconductors with smart behaviors, color-related applications, and new modulation approaches. Photochromophores with electron-transfer (redox) behavior, such as viologen and naphthalene diimide, are ideal functional motifs to design photochromic semiconductors owing to good adaptability to the solid matrix, but their reverse reactions are exclusively realized by the thermal mode, which is slow (in dozens of seconds or longer) and thus significantly hinders real applications in the fields that require high-speed switching. This study reveals that photoexcitation in the electronic absorption band of the π-aggregate of viologen cation radicals can successfully trigger reverse electron transfer quickly (in 1 s with a continuous-wave 808 nm laser at a power density of 5 W cm−2; the photothermal effect is excluded), and the first single-component all-optically photochromic semiconductor is accordingly discovered. This discovery breaks through a traditional concept that reverse reactions of viologen compounds can not be triggered by the light, and provides a potential approach to realize all-optical switch of single-component photochromic smart semiconductors based on electron-transfer photochromic functional motifs. 相似文献