苯和甲苯差分吸收光谱方法的实验室测量研究

本文介绍了差分光学吸收光谱法(DOAS)测量大气污染气体浓度的基本原理。DOAS方法就是利用氙灯发出的紫外—可见光，经望远镜准直后再经过一段距离的传输，由望远镜来接收．在传输中，由于各种不同的分子在不同的波段对光有不同的吸收特征，使光谱具有了污染物的特征，再通过与光源发出的光进行比较，反演这些气体在大气中浓度．我们将DOAS方法应用在监测有机物上，在分析光谱的过程中，应用多项式拟合和最小二乘法，从而精确地从测量光谱中来反演出大气中污染气体的浓度．文中用DOAS方法测量了苯和甲苯的样品，并分析了结果，结果和理论吻合．可为环境中有机污染物监测提供可靠的方法。     

The Effect of Moisture Content on the Conversion of Ergosterol to Vitamin D in Shiitake Mushrooms

The distribution of ergosterol in different parts of shiitake mushrooms was studied in order to optimize the conversion of ergosterol to vitamin D₂ during drying. The effect of moisture on the conversion of ergosterol to vitamin D₂ was also investigated by adjusting the moisture content of fresh mushrooms to different levels in a large vacuum desiccator and subjecting them to UV irradiation at 290-320 nm wavelength, for 2 h. The moisture, ergosterol and vitamin D₂ contents were determined using standard procedures. It was found that the ergosterol content on a dry matter basis of fresh shiitake mushroom was highest in the gills (10.6 ± 0.99 mg/g DM), followed by the cap or pileus (5.34 ± 0.64 mg/g DM) and was least in the stalk or stipe (2.97 ± 0.56). The moisture content had a marked influence on the conversion of ergosterol to vitamin D₂, the best conversion taking place at a moisture content of about 70% on a wet basis.     

波长为515nm的氩离子激光器的频率稳定

用声光晶体对氩离子激光作频率调制,获得了碘分子的差拍饱和吸收信号。将得到的斜率极陡的—阶微商形式的饱和吸收信号作为鉴频曲线把氩离子频率激光稳定到~(127)I_2分子的p(13)43—0的a_3超精细分量上。通过与一稳定到相同精细分量的稳频氩离子激光拍频,给出激光频率稳定性优于±6.5×10~(-12),重复性优于±3.4×10~(-11)。     

Carnot comparison of multi-temperature level absorption heat cycles

Comparison of different absorption heat cycles is not always made on the correct manner. This also includes comparison of an ideal absorption cycle with a mechanical analogy. A new Carnot model operating with two heat engines and two mechanical heat pumps is defined to be the correct and logical way to describe the mechanical analogy for an absorption heat pump and an absorption heat transformer. General equations for the Carnot coefficient of performance, COP_r, are exemplified and simulated for an absorption heat pump and an absorption heat transformer, and an entropy flow fraction diagram is introduced. The important fact that the absorption heat cycles must operate under the same conditions when they are compared is discussed.     

降低过滤机滤饼水分和细粒煤脱水浅析

根据对选煤厂细粒煤样的实验室优化脱水试验、工业试验及分析结果 ,对真空系统、气水分离器和分配头实施了技术改造 ,细粒煤脱水系统的运行状况得到显著改善 :圆盘真空过滤机滤饼水分降到 2 0 %左右 ,脱饼率在 95 %以上 ,每年的直接经济效益可达 30 0多万元     

The thermodynamic performance of a new solution cycle in double absorption heat transformer using water/lithium bromide as the working fluids

In this paper, a new solution cycle in the double absorption heat transformer is presented and the thermodynamic performance of this new cycle is simulated based on the thermodynamic properties of aqueous solution of lithium bromide. The results show that this new cycle is superior to the cycle being studied by some researchers. This new solution cycle has a wider range of operation in which the system maintains the high value of COP and has larger temperature lifts and operation stability. The relationship between the absorber and the absorbing evaporator is more independent and this makes the operation and control of the system more easier.     

丙烯腈吸收塔放空管道噪声控制

某石油化工总厂丙烯腈车间的吸收塔在放空负荷增大以后产生了较严重的噪声,对生产环境造成极大污染。为对丙烯腈吸收塔的放空管道实施噪声控制,改善工厂以及周边厂家的生产环境,进行了噪声控制方案设计及消声器设计。项目实施后,噪声绝对值降低了20分贝,噪声幅度降低达24％。     

Water absorption properties of phosphate glass fiber‐reinforced poly‐ϵ‐caprolactone composites for craniofacial bone repair

The moisture uptake of polymers and composites has increasing significance where these materials are specified for invasive, long‐term medical applications. Here we analyze mass gain and the ensuing degradation mechanisms in phosphate glass fiber reinforced poly‐?‐caprolactone laminates. Specimens were manufactured using in situ polymerization of ?‐caprolactone around a bed of phosphate glass fibers. The latter were sized with 3‐aminopropyltriethoxysilane to control the rate of modulus degradation. Fiber content was the main variable in the study, and it was found that the moisture diffusion coefficient increased significantly with increasing fiber volume fraction. Diffusion, plasticization, and leaching of constituents appear to be the dominant aspects of the process over these short‐term tests. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Effect of olive residue benzylation on the thermal and mechanical properties of poly(vinyl chloride)/olive residue composites

The changes in mechanical properties, the thermal stability, and the water absorption capacity of poly (vinyl chloride)/olive residue flour composites were studied as a function of various residue olive flour ratios, i.e., 0, 5, 15, and 25% by weight taking into account the effect of benzylation chemical treatment of the filler. The study showed that composite samples prepared with the untreated filler exhibited higher tensile modulus and hardness compared with the neat resin, whereas elongation and tensile strength were observed to decline. On the other hand, the PVC hardness was found to increase with addition of the untreated olive residue flour (ORF), however the composite samples prepared with the benzylated flour exhibited lower hardness than those prepared with untreated olive residue. Moreover, the amount of absorbed water depends on the amount of filler in the composite. The comparison of the results obtained from the samples of F5, F20, and F30 formulations between the untreated and treated ORF indicated a reduction in absorbed water for the composite samples containing treated ORF with benzyl chloride. As a result, the mechanical properties of the treated composites were improved. Furthermore, the thermal characterization of the different samples carried out by color change test and thermogravimetric analysis revealed an increase in the onset temperatures of decomposition for the treated composites. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

使用地热能的吸收式制冷系统

吸收式制冷系统可以利用低品位的热源来制冷，相对于常见的蒸汽压缩式制冷系统而言在这方面具有优势。我国是一个地热资源很丰富的国家，为了充分利用这一资源，我们有必要对以地热为热源的吸收式制冷系统进行研究。本文着重分析了使用地热资源的溴化锂吸收式制冷系统。