Development of calibration models for quality control in the production of ethylene/propylene copolymers by FTIR spectroscopy,multivariate statistical tools,and artificial neural networks

Principal component regression (PCR), partial least squares (PLS), StepWise ordinary least squares regression (OLS), and back‐propagation artificial neural network (BP‐ANN) are applied here for the determination of the propylene concentration of a set of 83 production samples of ethylene–propylene copolymers from their infrared spectra. The set of available samples was split into (a) a training set, for models calculation; (b) a test set, for selecting the correct number of latent variables in PCR and PLS and the end point of the training phase of BP‐ANN; (c) a production set, for evaluating the predictive ability of the models. The predictive ability of the models is thus evaluated by genuine predictions. The model obtained by StepWise OLS turned out to be the best one, both in fitting and prediction. The study of the breakdown number of samples to be included in the training set showed that at least 52 experiments are necessary to build a reliable and predictive calibration model. It can be concluded that FTIR spectroscopy and OLS can be properly employed for monitoring the synthesis or the final product of ethylene–propylene copolymers, by predicting the concentration of propylene directly along the process line. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Optically tuned superconductive-dielectric resonators with whispering-gallery modes

An analytical method is presented for calculating the resonant frequency andQ-factor of a superconducting dielectric disk resonator operating in millimeter-wave regime with whispering-gallery mode. Resonant frequency shift due to the optical generation of quasi-particles in superconducting film is investigated as a function of photon flux. An optically tunable resonant frequency of about 500 MHz is estimated, and good agreement is found between numerical results and experimental ones.     

A new synthesis procedure for titanium-containing zeolites under strong alkaline conditions and the catalytic activity for partial oxidation and photocatalytic decomposition

A new synthesis procedure for titanium-containing aluminosilicate zeolites has been obtained using a clear colloidal dispersion (sol) which was prepared with titanium isopropoxide, water, hydrochloric acid and colloidal silica, Ludox. When NaY, KL, offretite, mordenite and ZSM-5 zeolites were crystallized from the sol following conventional hydrothermal crystallization procedures, all the aluminosilicate zeolites showed the same X-ray absorption fine structure at the Ti K edge indicating framework Ti. The zeolites showed remarkable catalytic activity for the partial oxidation of cyclohexene using H₂O₂ as an oxidant and the photocatalytic decomposition of trichloroethene using water.     

The method of testing of XLPE cable insulation resistance to partial discharges and electrical treeing

The paper gives a method of model XLPE medium voltage cable insulation testing for partial discharges and electrical treeing with a point to plane test geometry. Based on this method, a comparative estimate of insulation resistance to treeing and partial discharges have been made. XLPE crosslinked by different methods (steam medium and hot nitrogen medium) and with varying contents of inorganic filler kaolin were tested. The characteristics of partial discharges were measured by means of a pulse height analyser characterized with a microscope. The data have been analysed statistically.     

THE ANALYSIS OF THE SEPARATED LAYERS ALGORITHM BY DOMAIN DECOMPOSITION METHOD

From the principle of of the Domain Decomposition Method (DDM), we analyse the 2nd-order linear elliptic partial differential problems and link the Separated-Layers Algorithm (SLA) with DDM. The mathematical properties of SLA and numerical example are presented to obtain satisfactory computation results. For general linear differential ones, also are the structure of SLA and its characteristics discussed.     

用偏微分方程构造过渡面

用偏微分方程的构造曲面是一种新兴的方法，本文借若干算例说明如何用偏微分方程构造两已知曲面之间的过渡面。论文着重讨论用四阶方程构造一阶连续的过渡面。     

液压支架设计及制作过程中的优化

主要介绍液压支架设计和使用过程中局部结构上的缺陷,经过优化设计从而实现安装、拆卸方便,维护量减少,检修便利。制作过程中部分零部件改变工艺过程实现通用化、系列化。     

一种基于偏最小二乘法的室外光照估计算法

针对固定视点下的室外场景在线视频光照求解问题,提出一种基于偏最小二乘室外场景实时光照估计算法.在离线阶段提取场景中对光照变化较为敏感的区域,并将这些区域像素值的均值与方差的无偏估计作为场景图像的统计参数,再利用偏最小二乘回归分析建立场景的光照参数与图像统计参数之间的模型;在在线阶段使用所建立的模型实时估计视频每一帧的光照条件.实验结果表明,使用该算法所求解的光照参数对虚拟物体进行绘制并将其融入视频中后,合成场景真实感很强.     

基于Gumbel Copula函数的堆石坝沉降模型因子优选研究

为克服常规沉降模型因考虑众多影响因子造成欠拟合及预测精度不高的缺点,首先由因子优选准则得到沉降模型的预选因子集,运用了Copula熵和PMI(偏互信息)两种方法对预选因子集进行优选,再将优选因子集引入沉降模型并计算典型测点的沉降值,验证了该优选方法的可行性。实例表明,基于Gumbel函数的沉降模型拟合预测精度优于常规模型,具有较高的工程指导意义及较好的推广价值,可运用于堆石坝的变形预测。     

Stability of Impulsive Stochastic Neutral Partial Differential Equations With Infinite Delays

In this paper, we study the existence and asymptotic stability in the pth moment of the mild solutions to impulsive stochastic neutral partial differential equations with infinite delays. Sufficient conditions ensuring the stability of the impulsive stochastic system are established. The results are obtained via the Banach fixed point theorem.