聚丙烯增韧改性研究进展

综述了国内增韧改性聚丙烯的研究动向 ,介绍了近年来茂金属聚烯烃弹性体和有机/无机纳米粒子增韧聚丙烯的新技术     

塔里木盆地塔河油区原油生物标志化合物在运移方面的应用探讨

塔河油区奥陶系原油的成熟度较高,且受生物严重降解.不同的生物标志化合物成熟度参数仅对有机质生成原油的不同阶段起到标尺作用,需优选既能较好地抗生物降解且适用于较宽的成熟度范围的指标来分析塔河油气运移的可能途径.三环萜烷/17α(H)-藿烷、重排甾烷/规则甾烷及Ts/(Ts+Tm)的比值是比较适用于塔河油区这种特殊性质的原油的生物标志化合物.根据研究,奥陶系原油油气存在两个注入通道,早期主要是由南向北方向运移,油气成熟度相对较低,成藏较早;晚期由东向西运移,原油成熟度相对于早期的较高,原油成藏稍晚.     

叠前深度偏移中的旅行时并行计算技术

旅行时计算技术是基于波动方程叠前深度偏移方法的核心内容，射线跟踪的数值计算精度和效率直接影响着介质成像质量和实用化。基于三维射线跟踪的微变网络方法和波前重建思路，提出一种适用于三维复杂介质地震波走时的快速算法。但它所需计算量巨大。采用并行计算技术，设计出基于“任务缓冲池”的动态负载平衡策略，在现有的分布式计算机上，实现了三维射线追踪和叠前深度偏移的并行计算。     

常速度梯度射线追踪与二维层速度反演

速度问题是勘探地震学的核心 ,可以借助常速度梯度射线追踪方法 ,从反演的角度探讨速度建模问题。在射线追踪方面 ,从程函方程出发 ,将复杂的速度场剖分成小的矩形单元 ,并假设在每个矩形单元内速度具有常速度梯度 ,由此导出的一组常速度梯度射线追踪公式 ,可实现非均匀介质的射线追踪 ,具有适应性强、精度高和快速的优点。在层速度反演方面 ,采用相干速度反演的思想 ,根据各向同性介质中 ,零偏移距射线在界面处是法向入射的原理 ,建立了合成共中心点道集与射线深度偏移的正反演关系 ,由此利用合成共中心点道集与观测的共中心点道集逼近 ,采用层剥离方法进行层速度反演。通过理论推导与模型试算得到如下的认识与结论 :常速度梯度射线追踪具有较高的计算精度与效率 ,公式采用向量形式很容易推广到三维 ;确定层速度采用的是正反演相结合的方法 ,可得到稳定的速度场 ;该方法屏弃了基于双曲时矩关系确定层速度场的假设 ,使其能适应任意的速度分布。     

Physical Properties Important to Electrostatic and Non electrostatic Powder Transfer Efficiency in a Tumble Drum

ABSTRACT: Popcorn was oiled and coated in a tumble drum nonelectrostatically and electrostatically with sugar, cornstarch, salt, cellulose, maltodextrin, all-purpose flour, whole-wheat flour, or soy flour. Particle size, density, flowability, and chargeability were correlated to transfer efficiency using regression analysis. Of the various methods to measure chargeability, charge-to-mass and adhesion improvement were the most significant. For nonelectrostatic coating, small, dense, free-flowing powders were most efficient. Small, free-flowing highly charging powders were most efficient for electrostatic coating. Percent improvement was the highest for the least efficient powders. The greatest benefit with electrostatic coating was for low density, highly charging powders with no effect of size.     

The deposition morphology of Brownian/non-Brownian particles within a constricted tube

The deposition morphology of Brownian/non-Brownian particles within a constricted tube is investigated by applying the Brownian dynamics simulation method in the present paper. Two different geometric structures, the parabolic constricted tube (PCT) and the sinusoidal constricted tube (SCT), are adopted. The effect of various types of the total interaction energy curves of the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, and of the shadow area cast by those deposited particles, on the particles’ collection efficiencies are also examined. For the PCT structure, under the same interaction energy curve, it is found that the non-Brownian particles always own a higher collection efficiency than that of the Brownian particles. Since the deposition location moves closer to the constriction part of the tube, the collection efficiencies of the Brownian/non-Brownian particles increase with the decrease of flow velocity. The SCT behaves differently, it is found that the collection efficiencies of non-Brownian particles are only slightly higher than those of Brownian particles when SCT is adopted. The steep slope of the tube wall near the constriction part of SCT dominates the whole deposition process of Brownian/non-Brownian particles. In comparison with the available experimental data, it is found that the present method can give a good simulation result.     

Investigation into Displacement of Placer Gold Particles

The experimental research in displacement of gold particles in washed-out thickness of sand-gravel layer is conducted. The parameters of ability of gold particles to migrate in pulp flow are determined, and their immersion into loose soil is investigated.     

三维合成炮叠前深度偏移

对国际上标准的SEG/EAEG模型进行了三维合成炮叠前偏移研究。与三维单炮叠前深度偏移不同 ,三维合成炮叠前偏移有一个叠前数据的合成过程 ,由于合成后数据量大大减少 ,所以合成炮偏移的计算量要比单炮偏移小得多。阐述了三维合成炮叠前偏移的实现过程 ,给出了相应公式。对SEG/EAEG盐丘模型的一个数据集进行了MPI并行计算 ,取得了良好的成像效果。所作的较多计算表明了三维合成炮叠前偏移的正确性和有效性 ,这为野外实际数据的三维叠前深度偏移提供了另一条有效途径。     

流体势与油气运聚规律研究——以孤东地区为例

流体势是地下流体所有能的综合表现,不同的流体(如油、气、水)在各自的势场作用下,有各自的势场分布规律运动.通过研究地下流体势空间分布模式,可确定盆地流体系统构成,提高对油气运移规律的认识,明确预测有利油气聚集区,提高钻探成功率.研究表明,孤东地区地下流体势类型分为高势区、低势区,高势区分布与活跃生油洼陷分布一致,是孤东地区油气成藏的主要烃源区和动力源区.低势区与目前的油气田吻合较好.由此可依据流体低势区来预测新的油气聚集部位.      

GC–MS characterization of oligomers in polyadipates used as plasticizers for PVC in food contact

Fourteen commercial polyadipates and a polysebacate were analysed for their components of a molecular mass below 1000 Da, primarily with the aim of generating the background data for measuring the migration of this type of polymeric additives from plasticized PVC (e.g. cling films and gaskets of lids) into foods or food simulants. Since the composition of the material <1000 Da varies between the polyadipates, the main components must be identified to enable a correct quantification. Polyadipates differ in the diol used as linker, their termination (acid or alcohol) and in the end‐capping (free alcohols, acetylation, acylation with fatty acids, esterification with octanol/decanol). Gas chromatography (GC) provides good separation, but the material remaining in the column up to high temperatures decomposes and forms a hump in the rear part of the chromatogram. Examples of mass spectra are shown, the most indicative fragments pointed out and spectra of 159 components listed. The polyadipates and the sebacate are characterized by their structure, the main components <1000 Da and the fraction of material <1000 Da. Copyright © 2006 John Wiley & Sons, Ltd.