Measurement of intrinsic rates for homogeneous gas‐phase reactions at high temperatures

A coiled quartz tubular reactor has been designed to measure the intrinsic reaction kinetics for homogeneous reactions at high temperatures up to 1100°C. Actual gas residence times were less than 100 ms. A simple and well‐studied test reaction (i.e., the decomposition of nitrous oxide, N₂O), with published intrinsic kinetics, was used to verify the operation of the experimental reactor. For this system, Peclet numbers (Pe = uL/DL) computed from experimental conversion data were greater than 1000, indicating that the plug flow assumption could be used with this reactor system to determine intrinsic rate expressions with errors of less than 5% for the conditions studied.     

石化企业发展第三方物流的探讨

在基于第三方物流的初步认识上，对石化企业物流活动现状、发展第三方物流的意义及方式进行分析探讨，以期为管理者决策提供参考，对加强石化企业的经营管理起到一定作用。     

Long-term cyclability of nanostructured LiFePO4

Amorphous LiFePO₄ was obtained by lithiation of FePO₄ synthesized by spontaneous precipitation from equimolar aqueous solutions of Fe(NH₄)₂(SO₄)₂·6H₂O and NH₄H₂PO₄, using hydrogen peroxide as oxidizing agent. Nano-crystalline LiFePO₄ was obtained by heating amorphous nano-sized LiFePO₄ for different periods of time. The materials were characterized by TG, DTA, X-ray powder diffraction, scanning electron microscopy (SEM) and BET. All materials showed very good electrochemical performance in terms of energy and power density. Upon cycling, a capacity fading affected the materials, thus reducing the electrochemical performance. Nevertheless, the fading decreased upon cycling and after the 200th cycle the cell was able to cycle for more than 500 cycles without further fading.     

水平矩形管内气液两相流界面波特性

<正>气液两相流中界面波的存在对传热、传质、阻力特性及稳定性都有很大影响。前人有关界面波的研究大多偏重于两相流中界面波的类型及其转变,而对其特征参数变化规律(如振幅、波长、频率和速度等)的研究则很少。但界面波对气液两相流流动阻力和流动结构影响机理的深入研究必须以了解界面波的各特性参数为前提,同时界面波有关特性参数的深入研究也可为气液两相流的数学理论化提供实验基础。 本文以气、水为工质,系统研究了水平矩形管内气液两相流的界面波特性。根据界面波在时域、幅域内的不同特征区别出了各种类型的波并给出了相应的波形和流型图。着重研究了界面波各特征量随气液两相流量变化的变化规律。     

基于ADSP-2188的铅酸电池智能管理系统研究

针对铅酸电池单体差异性以及对温度、电流、电压敏感等缺陷,设计基于ADSP-2188的智能管理系统.     

Experimental and Numerical Analysis of the Viscous Fingering Instability of Shear‐Thinning Fluids

Miscible flow displacements in a rectilinear Hele‐Shaw cell of Newtonian as well as rheologically well‐characterized shear‐thinning fluids are examined through experimental measurements and numerical modelling. Water is used as a displacing fluid while the displaced fluid consists of either a reference Newtonian glycerol solution or shear‐thinning solutions of Alcoflood? polymers of different molecular weights. The experimental measurements revealed that the shear‐thinning behaviour of the non‐Newtonian solutions resulted in more complex instability patterns and new finger structures not previously observed in the case of Newtonian displacements are identified and characterized. An analysis of the effects of the rheological behaviour of the shear‐thinning fluids on instability characteristics such as the finger width and finger tip velocity is presented. Numerical simulations using a pseudo‐spectral method are conducted and allowed to compare the predictions of the mathematical model based on an effective Darcy's law with the experimental measurements.     

毛细管中聚合物熔体不稳定流动的研究进展

概述了聚合物熔体在毛细管挤出中典型的不稳定流动现象和不稳定流动的分类，分别叙述了支化聚乙烯型熔体破裂和线型聚乙烯型鲨鱼皮破裂，粘-滑破裂，波动破裂，以及其它异常流动行为的理论研究进展，并讨论了口模尺寸，温度，添加剂，分子量及分子量分布等因素对不稳定流动的影响。     

确定流动汽液平衡釜总压的直接法

本文提出了两种由体系温度(T)及汽液相组成(y,x)推算总压(P)的直接法。对二元体系,如果忽略气相非理想性,计算总压的公式如下: 式中P_1~0、P_2~0分别为组分1、2的饱和蒸汽压,P为在y_1~0组成下的总压。 P=y_1x_1P_1~0+y_2x_2P_2~0 式中:y_1、y_2分别为组分1、2的活度系数,可由图解积分法求得。用T、x、y、P均已知的体系数据,对上述两方法进行验算,结果计算值与实验值吻合。此法可直接确定用流动平衡釜测汽液平衡时的总压;对同时测定了T、x、y、P的体系可进行逐点的P检验。     

Reprint of “Suppressing propylene carbonate decomposition by coating graphite electrode foil with silver”

A method has been developed to suppress the decomposition of propylene carbonate (PC) by coating graphite electrode foil with a layer of silver. Results from electrochemical impedance measurements show that the Ag-coated graphite electrode presents lower charge transfer resistance and faster diffusion of lithium ions in comparison with the virginal one. Cyclic voltammograms and discharge-charge measurements suggest that the decomposition of propylene carbonate and co-intercalation of solvated lithium ions are prevented, and lithium ions can reversibly intercalate into and deintercalate from the Ag-coated graphite electrode. These results indicate that Ag-coating is a good way to improve the electrochemical performance of graphitic carbon in PC-based electrolyte solutions.     

高能量密度水溶性有机液流电池的开发策略

水溶性有机液流电池自2014年出现后发展迅猛,特别是近些年来有机电活性物质的降解和二聚导致的容量衰减问题得到初步解决后,该类液流电池有望作为大规模储能系统的候选者。然而能量密度较低的问题限制了其商业化的进程。对此,主要从增大溶解度、提高电化学窗口和电子的得失数这3个方面详细介绍了5种提高水溶性有机液流电池能量密度的方法——分子结构剪裁、“interaction-mediating”策略的应用、采用聚合物电活性物质、“氧化还原靶向”原理和电极表面的改性,同时对进一步提高水溶性有机液流电池能量密度的策略进行了简要展望。