Synthesis and Characterization of Tetravalent Cerium Complexes with p-Tert-butylcalix[ n ] arenes （ n = 4, 6, 8）

Ａｓａｂｒａｎｃｈｏｆｓｕｐｅｒａｍｏｌｅｃｕｌａｒｃｈｅｍ ｉｓｔｒｙ ,ｌａｎｔｈａｎｉｄｅｃａｌｉｘａｒｅｎｅｃｈｅｍｉｓｔｒｙｈａｓａｔ ｔｒａｃｔｅｄｃｏｎｓｉｄｅｒａｂｌｅｒｅｓｅａｒｃｈｉｎｔｅｒｅｓｔｆｏｒｓｅｖｅｒ ａｌｙｅａｒｓ[1～ 5 ] .Ｉｎｔｈｉｓｒｅｓｐｅｃｔ,Ｈａｒｒｏｗｆｉｅｌｄｅｔａｌ.[6～ 13] ｓｙｎｔｈｅｓｉｚｅｄａｌｏｔｏｆｌａｎｔｈａｎｉｄｅｃａｌ ｉｘａｒｅｎｅｃｏｍｐｌｅｘｅｓ ,ａｎｄｒｅｖｅａｌｅｄｔｈｅｉｒｃｒｙｓｔａｌｓｔｒｕｃｔｕｒｅｓ .Ａｍｏｎｇｓｔｔ…     

氚β射线和~(60)Coγ射线诱发小鼠精细胞显性致死突变及RBE值

本实验用LACA成年雄鼠分别接受0. 19,0. 38,0.66和1. 01Gy的氚水β射线和0. 743,1.592和2.074Gy的~(60)Coγ射线分别连续照射10天。诱发精细胞显性致死突变率分别为8.6％—14.9％和4.4％—30.3％。两种射线的剂量响应关系为线性,根据二条直线斜率之比求出氚的RBE值为2.1。     

Hair mercury levels in relation to fish consumption in a community of the Moroccan Mediterranean coast

Coastal populations with high seafood consumption in the Mediterranean have a significant exposure to dietary methylmercury, and areas where environmental mercury pollution is an issue due to industrial activities are of special concern. The study was undertaken with the aim of assessing methylmercury exposure through fish consumption in a community of north Morocco and characterizing the relevant health risk. Concentrations of total mercury were determined in human hair, a biomarker of methylmercury exposure, and in locally consumed fish by cold vapour atomic absorption spectrophotometry. Based on consumption frequencies reported by the 108 subjects included in the study the weekly intake of methylmercury was estimated and biomarker data were evaluated in relation to the estimated intake and the sociodemographic characteristics of the population. Multiple regression analysis was employed for the interpretation of hair mercury data in relation to fish consumption frequency, gender and the age of individuals. Mercury concentrations in hair ranged from 0.22 to 9.56 µg g^-1 (geometric mean = 1.79 µg g^-1) and were closely related to fish intake. Fisherman and their families consumed fish three to five times per week and were the most exposed population subgroup. A high proportion of women of child-bearing age (50%) had relatively high levels of mercury in their hair (3.08-7.88 µg g^-1).     

超径砂卵石相对密度计算方法

提出了一种计算超径砂卵石填筑相对密度的方法及计算公式,在用相对密度作为填筑标准的控制指标时,采用此方法解决了超径砂卵石填筑质量难以用相对密度评价的问题.     

New polymer synthesis. XXX. Synthesis and thermal behavior of new organometallic polyketones and copolyketones based on diferrocenylidenecycloheptanone

A new interesting category of organometallic polyketones and copolyketones was synthesized via Friedel–Crafts reactions through the polymerization of 2,7‐bis[(2‐ferrocenyl)methylene] cycloheptanone ( II ) with different diacid chlorides. The model compound was synthesized by reacting monomer II with benzoyl chloride and characterized by ¹H‐NMR, IR, and elemental analyses. The polyketones and copolyketones were insoluble in most organic solvents but easily soluble in concentrated H₂SO₄. The thermal properties of these polyketones and copolyketones were evaluated and correlated to their structural units by TGA and DTG measurements and had inherent viscosity of 0.32–0.65 dI g^?1. Moreover, the electrical conductivity of polyketone Va and copolyketone VI was investigated above the temperature range (300–500 K) and followed an Arrhenius equation with activation energy 2.09 eV. Also, the morphological properties of selected example of polyketones were detected by scanning electron microscopy. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2394–2401, 2005     

Errors in Results and Measurement Provisions

The relative and reduced errors of measurement provisions and the relative errors of measurements are considered. Analytical expressions are provided that make it possible to evaluate the errors in question. Conclusions and practical recommendations are given.Translated from Izmeritel’naya Tekhnika, No. 3, pp. 71–72, March, 2005.     

"WEEE"和"RoHS"指令的对应策略

随着“WEEE”和“RoHS”指令实施的日益临近,国内许多企业苦于进展缓慢。本文提出了企业的对应策略。     

溶胶-凝胶法制备ZnO微粉及其电学性质

以柠檬酸和柠檬酸三铵为络合剂,利用溶胶凝胶法制备ZnO微粉。在乙酸锌浓度为0.2mol/L、柠檬酸浓度为0.05mol/L时得到的ZnO微粒粒径较小;在乙酸锌浓度为1.0mol/L、柠檬酸三铵浓度为0.5mol/L、灼烧温度为600℃时得到的ZnO微粒粒径较小。并分别对其性能进行表征,包括激光光散射粒度分析、红外检测、X 射线衍射分析、电学性质测定(阻抗、伏安特性曲线)。     

A rapid microwave-assisted derivatization process for the determination of phenolic acids in brewer’s spent grains

A simple and fast method for the TMS derivatization of phenolic acids in a closed vial using microwave irradiation followed by GC/MS analysis is proposed. A full factorial design was used to investigate the effects of two independent variables, namely, time and power of microwave irradiation, on the yield of silylation reaction. The optimal conditions were tested against the classical heating derivatization procedure. No significant differences were found between the classical heating and microwave-assisted derivatization. Chromatographic separation of the nine phenolic acids examined was achieved in 16 min. The mass spectral fragmentation patterns of the derivatives obtained by the proposed method were identical to those from the classical heating. Four different batches of brewer’s spent grain were extracted and analyzed for the total phenolic acid content. Significant differences between the batches of spent grains were found for all analytes. The total phenolic acid content varied between 2688 and 4884 μg/g.