MAXIMUM ENTROPY DECONVOLUTION OF XPS PEAK

Necessity of XPS spectrum,deconvolution,disadvantages of the traditional Fast Fourier Tranderm decon-volution method(FFT),princtple,method and advantage ofMaximum Entropy Deconvolution Method (MEM) are de-scribed.Criteria for determing the number of data points sam-pled in MEM are the main point disccussed in the paper,someXPS deconvolution applications of our MEM software showthat the MEM makes XPS deconvolution much easier than thetraditional FFT method.     

单输入中立型时滞系统的镇定

本文考虑了单输人中立型时滞系统的镇定问题。利用Byrnes等人提出的中立型时滞系统的模型,我们证明:如果系统是非奇异的,则系统可镇定的充要条件是其谱可镇定。     

低价态原子簇化合物的紫外-可见光谱研究

对一系列低价态双核原子簇化合物的UV-Vis光谱进行了定性研究，尤其是λ＞300nm处，发现过渡金属的d-d电子跃迁行为，并对个别化合物进行初步量子化学处理．     

直扩接收机基带迟早门跟踪环的简化设计

针对要求设计简化、资源有限的设备和系统 ,通过对直扩接收机基带迟早门跟踪环的性能分析 ,在扩频增益比较大时 ,提出了一种简化设计结构 ,用两个由扩频码的部分序列构成的相关器分别替代原来早门和迟门的完全序列相关器。仿真表明该结构在给定足够的相关值情况下 ,性能略有恶化 ,但资源却得到较大节约 ,设计可大大简化。     

多相物质粉末衍射的物相检索

讨论了多相物质粉末衍射的物相检索问题，介绍了XRDS的物相检索软件。这是一种智能型的物相检索程序，考虑了测试数据的不确定度，以及粉末样品和块状样品衍射图谱各自的特点，不仅注意到实际样品中微量物相存在的可能，也注意到块状样品结构有序性的可能。XRDS能够帮助材料工作者同时检出样品中所含的多种物相及其含量，操作简单、结果可靠。     

火灾早期过程特征的红外光谱探测和诊断

提出用CO作为早期火灾探测的观察对象,利用红外光谱法进行气体探测,并在此基础上建立了基于FTIR的试验系统.通过该方法成功获得CO的浓度值.并用时间序列分析方法建立二阶自回归模型,提取出特征参数进行分析,能在较短时间内将真假火灾区分开来.     

Functional copolymer of geraniol and acrylonitrile: Synthesis and characterization

The radical copolymerization of acyclic terpene namely geraniol [GER] with acrylonitrile [AN] in DMF at (70 ± 0.1)°C for 1 h, using benzoylperoxide (BPO) as an initiator has been carried out under inert atmosphere of nitrogen. The kinetic expression for reaction is R_p ∝ [BPO]^0.5 [AN]^1.0 [GER]^1.0. The IR spectrum of the copolymer shows bands at 3432 and at 2244 cm^?1 due to ? OH group of GER and ? CN group of AN, respectively. The ¹³C‐NMR spectrum shows peaks at 73–75 δ ppm and 116–120 δ ppm due to ? OH group of GER and ? CN group of AN, respectively. The thermogravimetric analysis and differential scanning calorimetry study shows that copolymer is thermally stable up to 407°C and has glass transition temperatures (T_g) 56°C. The reactivity ratios r₁ (AN) and r₂ (GER) have been calculated as 0.05 and 0.005, respectively. The Alfrey‐Price Q‐e parameter for GER has been calculated as 0.094 and ?2.0, respectively. The molecular weights of the copolymers have been evaluated by gel‐permeation chromatography. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Reconstruction of reflectance spectra using weighted principal component analysis

The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008     

用核磁共振技术确定岩石孔隙结构的实验研究

目前核磁共振技术对岩石的孔隙结构进行评价还停留在定性评价阶段。虽然多数核磁实验室开展了核磁共振评价孔隙结构的研究工作，建立了转换模型，但由于转换系数无法有效地确定，还不能进行应用。通过对岩心核磁共振T2谱与压汞孔径分布的对比，建立了转换模型系数与孔渗比的关系，同时考虑了顺磁物质对转换系数的影响，提出了确定转换模型系数的方法，为核磁共振技术进行孔隙结构的定量评价提供了新的方法。     

激光角膜矫正术中所用激光波长的选择

用分光光度计测定了12例兔角膜和1例人角膜的吸收光谱,结果表明波长小于300nm的准分子激光和波长在1.88μm～2.64μm,2.36μm～40μm的激光,均可对角膜进行切割并可望用于激光角膜矫正术。