含金属硫化物的氯化丁基橡胶胶料及其硫化胶性能

在氯化丁基橡胶配方中加入硫化镁、硫化钡和硫化锌代替常用的氧化锌可制得高性能的胶料及硫化胶，其综合物理机械性能优化含氧化锌的橡胶。由此制得的橡胶工业制品具有优良的抗老化性能和储存稳定性（25年后其性能保持率为98－99％），因而延长了制品的使用寿命（5－8倍）。     

硫化胶粉/PP共混材料的研究

研究了硫化胶粉/PP共混体系的力学性能、流动性能和热变温度等.结果表明,利用硫化胶粉可以明显改善PP的冲击性能,而且胶粉粒径越小,改善的效果越显著,但共混体系的拉伸强度有所下降.胶粉含量在5%-15%时,共混体系的综合性能较好.     

多糖—用于硫化矿物优先浮选的天然无毒调整剂

进行的吸附试验用来为阐明糊精和硫化矿之间的相互作用。硫化矿如方铅矿和六方硫镍矿，在与Ｐｂ（ＯＨ）２，Ｎｉ（ＯＨ）２等电点一致的ｐＨ值范围内显示了强吸附力，并且认为是化学作用。就硫化铜矿吸附而言属于弱吸附类型，并且遵循不同的模式。有关石墨的吸附研究证实了金属杂质充当吸附中心的化学作用机理，依照已提出的机理，方铅矿与黄铜矿，六方硫镍矿与辉铜矿均取得了选择性分离。     

Effect of Thickness on the Structure and Tribological Properties of MoSx Coating

MoSx coatings were prepared by bipolar-pulse DC unbalanced magnetron-sputtering system with the variation of coating thickness at different Ar pressures.The composition and surface morphology were determined by using energy dispersive X-ray and scanning electron microscopy;the structural characterization was analyzed by X-ray diffraction.The friction and wear properties were investigated by fretting tests in air with less than 10% and 50% relative humidity.At 0.40 Pa pressure,(002) basal plane orientation was formed throughout the coatings.At 0.88 Pa and 1.60 Pa pressures,(002) basal plane orientation was only noticed in the first stage of coating growth(around 0.20 μm in thickness), and then edge orientations with their basal planes perpendicular to the surface would be evolved in the coatings.Humidity has a minor influence on the coatings that have(002) basal plane orientation,whereas the tribological properties of MoSx coatings with edge orientations are greatly affected by humidity.The mechanisms of coating growth and friction and wear processes are discussed.     

低价硫化铝法从氧化铝直接炭还原制铝的动力学研究

低价硫化铝法从氧化铝直接炭还原制铝的动力学过程极为复杂,过程的前期受界面化学反应控制,过程后期受扩散过程控制,并求得不同时期的活化能,反应前期:E1=63.81 kJ/mol(6.67 Pa)、E2=50.82 kJ/mol(66.7 Pa)、E3=54.72 kJ/mol(666.7 Pa)、E4=39.61 kJ/mol(1333 Pa);反应后期:E*1=112.90 kJ/mol(6.67 Pa)、E*2=89.92 kJ/mol(66.7 Pa)、E*3=97.32 kJ/mol(666.7 Pa)、E*4=51.83 kJ/mol(1333 Pa).从动力学的角度提出了反应的较佳条件.温度、真空度的提高一方面可增大反应速率,但另一方面却加大了硫化铝的挥发,仅从增大速率而言,温度应大于1100 ℃,真空度应优于1333 Pa为宜.