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41.
高速非达西流动时元素硫沉积模型研究 总被引:3,自引:2,他引:1
元素硫沉积是含硫气藏开发过程中广泛存在而又必须解决的难题之一。高含硫气藏一旦投入开发,地层压力会逐步下降,使得元素硫溶解度下降而沉积下来,沉积的元素硫会堵塞地层孔隙,降低渗流通道,影响气井产能。考虑了高含硫气体在近井地带作高速非达西流动,建立了硫的沉积模型,并利用该模型对实际气藏进行预测和对比研究,再通过实例计算发现,硫非瞬时平衡沉积比瞬时平衡沉积对地层的伤害更严重,高速非达西流动沉积比达西流动时对地层伤害更严重,认为在开发高含硫气藏时,必须合理选择开发速度,有效防止元素硫沉积。 相似文献
42.
43.
Maciej Winiewski Artur Jakubiak Jan Szymanowski 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,63(3):209-214
Decyl isonicotiniate and decyl nicotiniate permit a rapid extraction of palladium(II) from its hydrochloride solutions. Decyl picoliniate is not a suitable extractant. 4-Octylphenylamine can act as a phase transfer catalyst when its concentration in the organic phase is at least 2·5 × 10?4 M . It seems that the interfacial adsorption of pyridine carboxylates and of 4-octylphenylamine is not the decisive phenomenon in palladium(II) extraction. The negligible protonation of the pyridine-type extractants and the phase transfer catalysis explains well the quick extraction of palladium(II) with the commercial and highly hydrophobic extractant ACORGA CLX-50. 相似文献
44.
45.
制备低硫可膨胀石墨的研究 总被引:18,自引:3,他引:15
研究了以过二硫酸铵作氧化剂低硫可膨胀石墨的制备,找到了在较低温度下,制备低硫可膨胀石墨的最佳条件。即过二硫酸铵和石墨的重量比为15%;反应温度为55℃;反应时间为40min;硫酸浓度为98%;硫酸与石墨的重量比为4∶1,草酸和硝酸(浓度为65%)的重量比为7.5%时,所制得的可膨胀石墨含硫量为0.65%,膨胀容积为200mL/g可膨胀石墨。并且,其终端产品柔性石墨具有优良的力学性能和抗氧化性能。 相似文献
46.
The distribution of neutrons produced by the reaction of 50MeV/u ^12C-ion on a thick Cu target are studied.The neutrons are measured with threshold activation detectors.Al.F,C,Al and In activation samples were used to measure neutrons with energy greater than 7,11,20,50MeV and thermal neutrons,respectively,The fluence rate,energy and angular distributions of neutrons,total neutron yield of 12C-ion and the emission rate in the forward direction of neutrons over 11 and 20MeV were obtained. 相似文献
47.
为分析新型低毒有机磷杀虫剂“1%双硫磷颗粒”投放对河道水质的影响,设置不同药剂投放浓度和不同反应时间的室内试验,以TP、NH3-N及S2-为目标因子,分析该药剂投放后水体污染物浓度。结果表明:不同试验组水样中S2-质量浓度均小于0.02 mg/L,NH3-N质量浓度处于0.029~0.036 mg/L之间,均达到地表水Ⅰ类标准;不同浓度药剂投放1 h后,水体TP质量浓度已达到稳定状态,且在60 h内均保持稳定,药剂投加量与水体TP质量浓度呈显著正相关(R2=0.85);不同处理组的药剂在水体中的TP释放量无明显差异,均在1.06~1.30 mg/g之间。“1%双硫磷颗粒”推荐适宜投放量不会使河道水质恶化到劣Ⅴ类,但增加药剂投放量会增加水体TP污染及富营养化风险。 相似文献
48.
Dynamic light scattering is a suitable method for the investigation of transport properties such as the thermal diffusivity of optically transparent fluids. The main advantages of the method are its quickness, the fact of the thermodynamic state of equilibrium of the sample (gradients are not required), and the relatively simple evaluation of data without the necessity of calibration. However, an insufficient production of intensity of scattered light may be a limiting effect. For that reason the vicinity of the gas-liquid critical point represents the classical range of application. In this paper, it is shown that by means of an appropriate choice of experimental apparatus, measurements are also feasible in an extended range of states. Broad regions around critical points of three pure fluids (sulfur hexafluoride, SF6; ethane, C2H6; nitrous oxide, N2O) over temperature ranges ¦T-T
c¦ of 0.02 to 50 K and density ranges (/c) of 0.2 to 2 were investigated. In this region the thermal diffusivity shows great variations with temperature and density and cannot be described by means of ideal-gas behavior or relations for liquids. The measurements were carried out along the coexistence curve for both phases, along the critical isochore and along some isotherms with TT
c. The measured or calculated density, pressure, and thermal diffusivity data as well as some correlations are presented. 相似文献
49.
为获得铀酰(UO22+)吸附性能高的吸附剂,以蒙脱石(Montmorillonite,MMT)和铁酸盐(ZnFe2O4)为原材料与L-半胱氨酸通过水热反应制备了硫掺杂ZnFe2O4(S-ZnFe2O4)和ZnFe2O4/MMT(S-ZnFe2O4/MMT),采用XRD、FTIR和SEM对S-ZnFe2O4和S-ZnFe2O4/MMT进行了结构表征,研究了pH、接触时间和UO22+初始质量浓度对UO22+吸附效果的影响,结果表明:S-ZnFe2O4呈高分散的纳米颗粒状,并且均匀分布于蒙脱石片层结构表面;S-ZnFe2O4与蒙脱石复合后能明显提高其UO22+吸附性能,最佳吸附pH为6.0;S-ZnFe2O4和S-ZnFe2O4/MMT复合材料对UO22+的最大吸附量分别为51.44 mg/g和68.45 mg/g;吸附符合Langmuir等温吸附模型和伪二阶动力学模型,说明吸附过程属于表面单分子层化学吸附。 相似文献
50.
We have shown that autoxidized polyphenolic nutraceuticals oxidize H2S to polysulfides and thiosulfate and this may convey their cytoprotective effects. Polyphenol reactivity is largely attributed to the B ring, which is usually a form of hydroxyquinone (HQ). Here, we examine the effects of HQs on sulfur metabolism using H2S- and polysulfide-specific fluorophores (AzMC and SSP4, respectively) and thiosulfate sensitive silver nanoparticles (AgNP). In buffer, 1,4-dihydroxybenzene (1,4-DB), 1,4-benzoquinone (1,4-BQ), pyrogallol (PG) and gallic acid (GA) oxidized H2S to polysulfides and thiosulfate, whereas 1,2-DB, 1,3-DB, 1,2-dihydroxy,3,4-benzoquinone and shikimic acid did not. In addition, 1,4-DB, 1,4-BQ, PG and GA also increased polysulfide production in HEK293 cells. In buffer, H2S oxidation by 1,4-DB was oxygen-dependent, partially inhibited by tempol and trolox, and absorbance spectra were consistent with redox cycling between HQ autoxidation and H2S-mediated reduction. Neither 1,2-DB, 1,3-DB, 1,4-DB nor 1,4-BQ reduced polysulfides to H2S in either 21% or 0% oxygen. Epinephrine and norepinephrine also oxidized H2S to polysulfides and thiosulfate; dopamine and tyrosine were ineffective. Polyphenones were also examined, but only 2,5-dihydroxy- and 2,3,4-trihydroxybenzophenones oxidized H2S. These results show that H2S is readily oxidized by specific hydroxyquinones and quinones, most likely through the formation of a semiquinone radical intermediate derived from either reaction of oxygen with the reduced quinones, or from direct reaction between H2S and quinones. We propose that polysulfide production by these reactions contributes to the health-promoting benefits of polyphenolic nutraceuticals. 相似文献