Skeletal Isomerization and Inter—molecular Hydrogen Transfer Reactions in Catalytic Cracking

Bimolecular hydrogen transfer and skeletal isomerization the important secondary reac-tions among catalytic cracking reactions,which affect product yield distribution and product quality,Catalyst properties and operating parameters have great impact on bimolecular hydrogen transfer and skeletal isomerization reactions .Bimolecular hydrogen transfer activity and skeletal isomrization activity of USY-containing catalysts are higher thn that of ZSM-5-containing catalyst.Coke deposition on the active sites of catalyst may suppress bimolecular hydrogen transfer activity and skeletal isomer-ization activity of catlys in different degrees.Short raction time causes a decrease of hydrogen trans-fer reaction,but and increase of skeletal isomerization reaction compared to cracking reaction in catalytic cracking process.     

碱式苦味酸铅针刺药的应用研究

提出了以碱式苦味酸铅为主体的针刺药在组合点火管中的应用，并对其针刺药的点火性能及能量传递进行了讨论，阐明了此类针刺药良好性能和应用价值。     

Augmentation of boiling heat transfer from horizontal cylinder to liquid by movable particles

This paper presents a series of experimental results on a passive augmentation technique of boiling heat transfer by supplying solid particles in liquid. A cylindrical heater 0.88 mm in diameter is placed in saturated water, in which a lot of mobile particles exist, and the nucleate and film boiling heat transfer characteristics are measured. Particle materials used were alumina, glass, and porous alumina, and the diameter ranged from 0.3 mm to 2.5 mm. Particles are fluidized by the occurrence of boiling without any additive power, and the heat transfer is augmented. The maximum augmentation ratio obtained in this experiment reaches about ten times the heat transfer coefficient obtained in liquid alone. The augmentation ratio is mainly affected by the particle material, diameter, and the height of the particle bed set at no boiling condition. The augmentation mechanism is discussed on the basis of the experimental results. © 2001 Scripta Technica, Heat Trans Asian Res, 31(1): 28–41, 2002     

Asymmetric Hydrogenation of Activated Ketones on Platinum: Relevant and Spectator Species

The heterogeneous enantioselective hydrogenation of activated ketones over chirally modified platinum is reviewed with emphasis on identifying the role of the various species observed in this catalytic system. The past years have witnessed a continuous broadening of the scope of this catalytic system including new reactants and modifiers affording over 97% ee. New reaction pathways have been uncovered and the kinetic and mechanistic studies have been faced with a number of complicating factors caused by spectator species and interactions in solution and on the Pt surface. The previously proposed mechanistic models are critically assessed in the light of these new findings.     

分户计量供暖节能住宅户型修正研究

针对多层住宅中不同户型在耗热量上的差异，引入户型体形系数修正各户的计量用热量，以计算和实测方法分析了一栋节能住宅不同围护结构户型的能耗特点，发现山墙、屋面、地面造成的不同户型之间的耗热量差别小于传统建筑；使用面积大的住户山墙造成的户型间耗热量差别小于使用面积小的住户。     

Effect of Pressure Gradient on Heat Transfer of Impinging Submerged Circular Jets

An experimental and numerical study have been carried out to investigate the distribution of radial local heat transfer coefficients of impinging submerged circular jets. Good agreement is achieved between the experimental results and the predicted value. Results show that the outer peak usually occurs at the radial location of r/d= 1.8~2.0, in which transition from laminar to turbulence happens resulting from disappeared pressure gradient abruptly, and that the inner peak appears rigidly at r/d=0.5, where the boundary layer has a minimum thickness because of elevating pressure gradient.     

α-蒎烯催化加氢反应的研究

以FYX - 2G型高压搅拌釜为加氢反应器 ,测定了在不同搅拌器型式和搅拌转速下高压釜的持气量和反应效果 ,认识到α 蒎烯催化加氢是外扩散控制的反应 ,当搅拌转速为 6 0 0r/min时 ,基本上能消除外扩散的影响。考察了Raney镍和Pd/C催化剂、反应温度在 35 3～ 499K ,压力在 4 0～ 10MPa的条件下对α 蒎烯加氢转化率和选择性的影响 ,结果表明Raney镍更适宜于α 蒎烯催化加氢 ,其转化率随温度、压力增加而提高 ,但选择性下降。采用温度 35 3～ 433K、压力 4 0～ 7 0MPa的操作序列 ,克服了α 蒎烯加氢转化率与选择性互为逆向的缺点 ,缩短了反应时间 ,制得了顺反比高达 18 2∶1的蒎烷 ,并且发现加氢反应从温度 433K开始有副产物对烷生成 ,当温度超过 45 6K时 ,加氢过程还出现飞温现象。     

Technology transfer projects in developing countries—furthering the Project Management perspectives

This paper attempts to broaden the analysis of the technology transfer phenomenon by refocusing research attention on the level of performance assessment of technology transfer projects. An holistic evaluation framework based on the considerations of an extended Project Life Cycle model is proposed to overcome some of the shortcomings of conventional approaches to project evaluation. This also reinforces the need for open systems thinking in assessing and managing risk of technology transfer projects. The discussion is based on two case studies which articulate the experiences with two integrated mechanisms of technology transfer used in Algeria from 1965 to 1990: turnkey and “product-in-hand”. The aim is to gain a better understanding of the processes of technology transfer and to contribute to the improvement of associated managerial practices in developing economies.     

CCD相机调制传递函数的测试原理分析

对于CCD相机的空间分辨率特性,通常用调制传递函数来表征.基于调制传递函数理论分析值与具体的实验测试值存在差别,分别对分辨率板在焦平面所成的像与CCD像元之间的偏移量和积分时间内被摄物体与相机的相对运动产生的像移对相机调制传递函数的影响进行了分析.讨论了调制传递函数与对比调制传递函数之间的联系和区别.