粉煤灰对碳硫硅钙石型硫酸盐侵蚀的影响

用粉煤灰等质量替代20%,30%,50%水泥后,将水泥石灰石粉粉煤灰净浆样品置于（5±2）℃的10%（质量分数）硫酸镁溶液中15个月,加速碳硫硅钙石型硫酸盐侵蚀（TSA）.对腐蚀产物进行了红外光谱定性分析和X射线衍射定量分析,通过灰色关联分析研究了粉煤灰对TSA的影响.结果表明：粉煤灰对水泥基材料的TSA影响与其组成、掺量及细度等因素有关;粉煤灰活性指数对碳硫硅钙石形成影响最大,可作为筛选粉煤灰预防TSA破坏的指标;活性指数大于80%的粉煤灰,其掺量达到50%时可显著改善水泥基材料的抗TSA性能.     

石灰石粉混凝土及其硫酸盐侵蚀特性综述

石灰石粉是一种新型的混凝土掺合料,推动绿色混凝土的发展.主要介绍了石灰石粉在混凝土中的应用情况和国内外研究现状,对石灰石粉混凝土的性能做了简要的概述;同时,介绍了掺入石灰石粉对水泥石的TSA破坏机理,并提出了相应的改善措施,在保证混凝土性能不变的情况下,充分有效利用石灰石粉;最后,对其应用前景及研究方向做了简要分析.     

曲古菌素A处理HeLa细胞对其培养基的吸收光谱影响

本研究采集了不同剂量曲古菌素A（TSA）分别处理24h和48h下的人宫颈癌细胞株（HeLa cell）的培养基RPMI1640的紫外吸收光谱。结果显示：细胞培养基分别在233nm和275nm处有特征性的吸收峰。数据的进一步分析发现：不同剂量的TSA在处理细胞时间一致时,培养基的吸收光谱存在明显的差别。即：1）当TSA处理细胞24小时,伴随着用药剂量的增大,细胞培养基在233nm处的吸收值先降后升,275nm处的吸收值同样先降后升：2）当TSA处理细胞48小时,伴随着用药剂量的增大,细胞培养基在233nm处的吸收值越来越低,275nm处的吸收值却越来越高。这一结果反映了培养基中芳香族氨基酸和半胱氨酸残基的含量及比例变化,其变化规律与药物引起细胞的增殖改变有着密切的联系,并为动物实验和临床应用奠定了基础。     

CO2 capture efficiency in post‐combustion using MWNT‐PAA in a packed bed column

The adsorption capacity of polyaspartamide (PAA) and multi‐wall carbon nanotubes with polyaspartamide (MWNT‐PAA) was investigated through a packed bed column with the flowing of flue gas composed of 15 % CO₂, 5 % O₂ and the balance N₂. The adsorption performed at 25 °C, 110 kPa and inlet gas flow rate of 60 mL/min resulted in high CO₂ adsorption capacity of 5.70 and 10.20 mmol‐CO₂/g for PAA and MWNT‐PAA, respectively. The adsorption kinetics was very high, so 7 min were enough for the effluent gas to reach the breakthrough after saturation. The consistency of adsorbents in recurring regeneration was successful through a continuous TSA system of 10 cycle adsorption‐desorption with temperatures of 25–100 °C. The evaluation of heat through differential scanning calorimetry (DSC) resulted in exothermic adsorption with heat release of 45.14 kJ/mol and 124.38 kJ/mol for PAA and MWNT‐PAA, respectively. The heat release was found favourable to promote the desorption as the temperature could rise after adsorption. This is an advantage for energy efficiency, as it depicts the potential of energy recovery. Thus, both adsorbent PAA and MWNT‐PAA were demonstrated to be promising for CO₂ adsorption capture in post‐combustion.     

水性抗菌羟基丙烯酸树脂的制备及性能

以甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)、丙烯酸(AA)、丙烯酸羟丙酯(HPA)为单体,过氧化二苯甲酰(BPO)为引发剂,乙醇为助溶剂,采用半连续溶液聚合法合成得到了水性羟基丙烯酸树脂(hs-WA),再用三乙胺(TEA)中和,最后引入季铵盐抗菌剂3-(甲氧基硅烷基)丙基二甲基十八烷基氯化铵(TSA),合成得到了水性抗菌羟基丙烯酸树脂(hs-WAT)。利用FTIR、1HNMR、接触角、SEM、TG和DSC对样品进行了分析,并采用菌落计数法和抑菌圈法对样品进行了抗菌测试。结果表明:引入TSA反应后,树脂的表面形貌没有改变;水接触角从78.5?增大至87.5?;样品的分解温度范围为299～456℃,热稳定性提高;聚合物链柔韧性增强(Tg=8.3℃)。抗菌性能分析表明:当引入TSA的质量分数为4%(以树脂的固含量计)时,hs-WAT膜对大肠杆菌(革兰氏阴性菌)以及金黄色葡萄球菌(革兰氏阳性菌)的杀灭率达99.9%以上,TSA未发生迁移,合成的聚合物为水性非渗透性接触型抗菌材料。     

Simultaneous identification of structural stiffness and mass parameters based on Bare-bones Gaussian Tree Seeds Algorithm using time-domain data

This paper mainly illustrates the Tree Seeds Algorithm (TSA) to tackle structural damage identification problem. The damage model is simulated by the alterations of both stiffness and mass parameters. The objective function is introduced by minimizing the differences between the measured and calculated acceleration data. To enhance the performance of the standard TSA, two modifications including the bare-bones Gaussian updated mechanism and the withering process are introduced. The modified algorithm is named after the BGTSA. In the numerical simulation part, the BGTSA is firstly used to make comparisons with several state-of-the-art algorithms on the CEC05. Secondly, the BGTSA is utilized to deal with the structural damage identification problem by optimizing the acceleration-based nonlinear objective function. Numerical experiments involving a simply supported beam and a truss are carried out to verify the effectiveness of the proposed algorithm. The final results show that with low amount of acceleration data, the BGTSA can acquire better identification results compared with other evolutionary algorithms. Therefore the proposed algorithm could be viewed as a potential tool to solve the structural damage identification problem.     

Evaluation of damage in composites by using thermoelastic stress analysis: A promising technique to assess the stiffness degradation

The stiffness degradation represents one of the most interesting damage phenomena used for describing the fatigue behaviour of composites. A critical aspect of modelling the damage is represented by the simulation of the whole behaviour of the composite and by the assessment of the actual stiffness for the models validation. In this work, the stiffness degradation of quasi‐isotropic carbon fibre reinforced polymer (CFRP) obtained by automated fibre placement has been assessed by means of thermoelastic stress analysis. The amplitude of temperature signal at the mechanical frequency (thermoelastic signal) was considered as an indicator of material degradation and compared with the data provided by an extensometer. The correlation between thermoelastic and mechanical data allowed to build a new experimental model for evaluating and predicting material stiffness degradation by just using thermoelastic data. The proposed approach seems to be very promising for stiffness degradation assessment of real and complex mechanical components subjected to actual loading conditions.     

Thermococcus siculi HJ21 α - 淀粉酶Asp186定点突变对酶活性的影响

为确定超嗜热古菌Thermococcus siculi HJ21α-淀粉酶(TSA)中特定氨基酸及所在位点与酶活性间的关系,以含TSA基因的pEt-28a-His6质粒为模板,利用定点突变技术,将第186位点的天冬氨酸(Asp)突变为天冬酰胺(Asn),突变子转化至E. coli BL21(DE3)并经IPTG诱导表达,测定突变前后的酶活性,定点突变后的TSA无酶活性;采用DNAStar和Deepview蛋白分析软件,预测突变前后TSA蛋白的二级结构和三级结构,结果表明Thermococcus siculi HJ21α-淀粉酶的186位点对维持TSA的酶活性具有重要意义,它的突变导致酶蛋白二级结构组件及氢键网络的改变。