全文获取类型
收费全文 | 5284篇 |
免费 | 481篇 |
国内免费 | 90篇 |
专业分类
电工技术 | 132篇 |
综合类 | 257篇 |
化学工业 | 3270篇 |
金属工艺 | 103篇 |
机械仪表 | 55篇 |
建筑科学 | 641篇 |
矿业工程 | 70篇 |
能源动力 | 21篇 |
轻工业 | 309篇 |
水利工程 | 81篇 |
石油天然气 | 89篇 |
武器工业 | 35篇 |
无线电 | 108篇 |
一般工业技术 | 578篇 |
冶金工业 | 44篇 |
原子能技术 | 27篇 |
自动化技术 | 35篇 |
出版年
2024年 | 18篇 |
2023年 | 43篇 |
2022年 | 113篇 |
2021年 | 145篇 |
2020年 | 101篇 |
2019年 | 115篇 |
2018年 | 115篇 |
2017年 | 134篇 |
2016年 | 129篇 |
2015年 | 182篇 |
2014年 | 260篇 |
2013年 | 314篇 |
2012年 | 414篇 |
2011年 | 419篇 |
2010年 | 272篇 |
2009年 | 336篇 |
2008年 | 284篇 |
2007年 | 348篇 |
2006年 | 355篇 |
2005年 | 288篇 |
2004年 | 258篇 |
2003年 | 201篇 |
2002年 | 184篇 |
2001年 | 154篇 |
2000年 | 130篇 |
1999年 | 122篇 |
1998年 | 94篇 |
1997年 | 69篇 |
1996年 | 48篇 |
1995年 | 52篇 |
1994年 | 41篇 |
1993年 | 31篇 |
1992年 | 24篇 |
1991年 | 20篇 |
1990年 | 9篇 |
1989年 | 8篇 |
1988年 | 10篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 2篇 |
排序方式: 共有5855条查询结果,搜索用时 62 毫秒
11.
Michael Bratychak Mihailo Bratychak Witold Brostow Olena Shyshchak 《Materials Research Innovations》2002,6(1):24-30
Oligomers containing peroxy groups have been synthesized on the basis of epoxides reacting with tert–butylhydroperoxide in the presence of boron trifluoride etherate. Dependence of reaction rates upon the quantity of catalyst,
temperature and also nature of hydroperoxide has been investigated: A kinetic equation for the process has been formulated
and also a kinetic scheme for the reaction taking into account the presence of boron trifluoride etherate is proposed. Structures
of the synthesized peroxy oligomers have been confirmed by IR- and NMR-spectroscopy. The reaction initiating properties of
the oligomers so synthesized were studied using as the example the styrene polymerization reaction.
Electronic Publication 相似文献
13.
Xiang‐Dan Li Zhen‐Xin Zhong Sang‐Hoon Han Seung Hee Lee Myong‐Hoon Lee 《Polymer International》2005,54(2):406-411
From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry 相似文献
14.
Vatroslav Bubalo Vjekoslav Jerolimov Ivo Bau
i Mladen Andreis Zorica Veksli 《Polymer International》2005,54(5):848-853
The electron‐spin‐resonance (ESR) spin‐probe method, was used to study the heterogeneity of denture resins based on poly(methyl methacrylate). Results for three resins processed by microwave energy, conventional curing and cold curing (depending on the curing procedure and exposed to ageing in various environmental conditions) were compared. All three cured resins were stored over the same time (1200 h) in distilled water at ambient temperature and in artificial saliva at 348 K. The temperature‐dependent ESR spectra of a spin probe dispersed in the denture resins are analyzed in terms of line‐shapes and line‐widths. The appearance of two spectral components was taken as an indication of resin heterogeneity. The results reveal that the cold‐cured resin has a lower local density in comparison with microwave and conventionally cured resin. The amount of residual monomer also contributes to the local motion of polymer segments. The change of denture resins exposed to ageing is influenced both by the structure of the original resin and the ageing conditions. Restricted motion of a spin probe incorporated into the acrylic resins exposed to accelerated ageing suggests additional crosslinking of polymer chains. The differences are observed for all the investigated resins, but the highest change is observed with the cold‐cured resin. The ESR results are accompanied by Tg and Tm measurements. Copyright © 2005 Society of Chemical Industry 相似文献
15.
硫化胶交联结构及其性能 总被引:3,自引:0,他引:3
综合讨论了聚合物/聚合物之间的交联结构及聚合物/填料之间的偶联结构对硫化胶抗硫化返牟性,抗氧老化性及动态疲劳性能的影响。 相似文献
16.
增塑对UV固化型高分子固体电解质性能的影响 总被引:1,自引:0,他引:1
将合成的大分子量的聚乙二醇丙烯酸酯(PEGDA)齐聚物与光引发刑、LiClO4组成光敏体系,与一定比例的碳酸乙烯酯(EC)、碳酸丙烯酯(PC)或其混合物进行混合,经紫外光辐照制得了一种新型的高分子固体电解质膜,考察了增塑刑种类和用量对光固化速率、电导率和机械性能的影响。结果表明,增塑是提高UV固化型高分子固体电解质导电性能的有效方法,在机械性能满足使用要求的条件下,增塑的UV固化型固体电解质的电导率可以高达10^-4S/cm左右。 相似文献
17.
用碳化养护电弧熔炉钢渣制备集料和混凝土 总被引:4,自引:1,他引:3
将电弧熔炉(electric arc furnace,EAF)钢渣和石灰混和制成球状集料,置于密闭容器当中,并通入100%的CO2气体进行碳化,在0.506 6MPa保持2h.通过质量法测定添加质量分数为11.94%石灰的EAF钢渣(下同)集料CO2的吸收率为5%,通过红外光谱(infrared,IR)分析测定CO2的吸收率为13.88%.用碳化的钢渣集料制备混凝土再进行碳化养护,同时利用碎石和河砂为集料制备碳化混凝土作为参比样.用质量法测定2种混凝土的碳化率分别为21.14%和10.57%;用IR法的为13.81%和16.97%.碳化后电弧熔炉钢渣集料内生长着大量簇生的犬牙状碳酸钙晶体. 相似文献
18.
利用阵列感应测井资料反演地层径向电导率 总被引:4,自引:1,他引:3
采用阵列感应测井仪测得的具有不同径向探测深度的5条电导率曲线完成了井中径向电导率分布反演。径向侵入剖面模型由冲洗带、原状地层和从冲洗带到原状地层的过渡带3部分组成。该侵入剖面模型较传统的仅由冲洗带和原状地层构成的台阶状侵入剖面模型更加接近地层径向侵入剖面的真实情况。与台阶状侵入剖面模型相对应的参数模型包括冲洗带电导率、原状地层电导率和侵入半径3个参数。而与含有过渡带的新侵入剖面模型相对应的参数模型除包括冲洗带电导率、原状地层电导率和过渡带中点半径外,还有一个反映过渡带电导率变化的指数N0根据反演得到的过渡带中点半径和指数N可以求出过渡带起点半径和过渡带终点半径。而且根据反演过程中采用的正演响应函数可以计算出任意径向深度处过渡带的电导率值。数值试验结果说明了该方法的正确性,实际资料处理结果说明了该方法的有效性。 相似文献
19.
20.
Finite element analyses (FEA) of thermosets are often performed on the basis of rheological data for fully cured resin. For the FEA of thermosets during curing, a material model is established and a technique is demonstrated, which allows the rheological data of the linear viscoelastic material to be derived. As the moduli are sensitive to conversion, all measured properties are related to temperature and conversion. Therefore the basis for the rheological data has to be a suitable reaction kinetic. Based on the kinetics shear and compression properties are measured independently and modeled mathematically with the focus to gain a formulation, which is suitable for FEA. The considered time constants are in the range between one second and one month as these times are relevant for the investigated relaxation times. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1868–1872, 2003 相似文献