Continuous precipitation of calcium sulfate dihydrate from waste sulfuric acid and lime

Precipitation of calcium sulfate dihydrate, gypsum, from (i) a pure sulfuric acid/lime suspension and (ii) a waste sulfuric acid/lime suspension in a continuous pilot plant in the temperature range from 40 °C to 80 °C was studied. It was observed that in the case of waste sulfuric acid with a high content of Mg²⁺ and Fe²⁺ ions, several hours after the beginning of the precipitation, partial dissolution of the product and modification of the crystals from needle‐ and plate‐like to agglomerated structures occurred. It is suggested that the secondary changes occur due to the increased concentration of Mg²⁺ and Fe²⁺ ions in the reactor. Below 60 °C, and above 70 °C plate‐like and needle‐like single crystals respectively were formed. The mean size (d₅₀) of the crystals was found to increase with increasing temperature and decrease with the initial concentration of lime. Gypsum produced between 70 °C and 80 °C is suitable for further processing for construction plaster. In a precipitation process with pure sulfuric acid only single perfect needle‐like crystals occurred. Copyright © 2005 Society of Chemical Industry     

广州中信商城地下连续墙施工工艺

本文介绍了广州中信商城地下连续墙的施工工艺。该工艺采用膨润土制浆配制方式，施工质量高，效果好。     

旋转导向钻井偏心稳定器横向振动研究

旋转导向钻井偏心稳定器横向振动研究是国家863“可控(闭环)三维轨迹钻井技术”课题研究的部分内容。选取偏心稳定器的心轴作为研究对象,以偏心稳定器心轴连续梁系统的横向振动模型受力分析为基础,根据课题研究中所设计的心轴结构形式,建立了与实际情况较为接近的三铰支点的连续梁系统横向振动方程;并分析了偏心稳定器横向振动对钻井工具和钻具系统的影响,为合理进行心轴设计以及偏心稳定器样机在现场的正确使用和钻井参数的合理选择,提供了科学的理论依据和实用的计算方法。计算实例表明,当钻压范围选择在80~250kN时,215.9mm井眼钻进中的确存在19~20、61~63、162~163r/min前三阶横向共振转速区间,因此在选择钻井参数时应通过钻压与转速的配合,尽可能避开横向共振转速,以保证下部钻具组合系统及作业安全。     

Investigation of Centreline Segregation and Centreline Porosity in CC ‐ Slabs

Improvements of solidification processing in conventional or near net shape casting depend on sophisticated methods of macroscopic examination of central unsoundness and inhomogeneity of the cast material. As long as remarkable deviations referring to the quality features exist between the slab centre and the bulk material such methods should be looked after. Two semi‐macroscopic methods of segregation analysis are discussed in this paper: firstly, the potential of the emission spectral analysis combined with sectioning of a sample and secondly, the computer aided micro‐probe analysis. Both methods are restricted to small local areas. The proneness of elements and steel grades with respect to micro‐ and macrosegregation as well as distribution‐ and segregation coefficients are determined. The effect of a diffusion anneal on homogenisation of segregation is studied. Last not least the precipitation of sulphides, phosphides or carbonitrides is estimated. Ultrasonic detection of the central unsoundness of conventional slabs or thin slabs is a new approach towards a quantitative macroscopic examination. The sample size is 400 mm x 300 mm x 30 mm. To achieve a low ultrasonic noise using a 5 MHz‐transducer the samples are heat treated for grain refinement. “Dog bone porosity”, macroscopic topographical misfit between the upper and lower solidifying shells, periodical corner cracks or systematic transverse centre cracks are detected. Obviously, segregations do not reflect the ultrasonic beam. However, it can be presumed that an interrelation exists between porosity and segregation, although these might be locally apart from each other. This new ultrasonic test of the central unsoundness of continuous cast (c.c.) slabs gives valuable arguments to machine builders and maintenance people to decide on the right concepts for strand guidance, support rollers and secondary cooling. Soft reduction can be optimized and variations in casting speed counteracted by dynamic means. R&D service of this kind can help steelmakers when decisions are impending to build new casting machines or revamp old ones.     

现代电弧炉流程钢液氮控制的试验研究

通过生产试验研究了电弧炉冶炼过程、LF精炼过程及连铸过程钢液氮的控制。研究表明，电弧炉冶炼过程主要是电弧区增氮，LF过程及连铸过程钢液增氮主要是钢液与大气接触，LF供电制度也对钢液吸氮有影响。     

合金钢连铸机生产工艺分析及实践

对新钢特殊钢有限责任公司整个合金钢连铸机的生产工艺进行了分析，提出了提高钢水质量和优化连铸工艺参数的有效措施，使铸坯的质量得到了有效控制和改善。     

碳纤维复合材料柔性连续抽油杆开发及应用

碳纤维柔性连续抽油杆选用高性能碳纤维 ,以环氧树脂胶液为基体材料 ,添加一定配比的固化剂、促进剂和脱模剂 ,采用拉挤成型工艺制成 ,其开发的关键技术是连续成型、连接接头和安全保险装置。现场应用试验表明 ,TXC— 1、TXC— 2、TXC— 3三种规格的碳纤维柔性连续抽油杆能可靠应用于泵挂深度分别为 12 0 0、 180 0、 30 0 0m的直井和斜井中 ,实测比钢抽油杆节电 ,日产油量提高 。节能增产效果显著。     

油气润滑系统在四切分轧制技术上的应用

本文介绍了油气润滑技术的工作原理及特点，阐述了该系统在四切分轧制技术上的应用与延伸。     

微滤膜清洗的研究

用次氯酸钠溶液、氢氧化钠溶液和盐酸溶液对小型微滤膜进行化学清洗试验,比较试验结果认为,用次氯酸钠溶液对受污染的微滤膜清洗更为有效,从而为鄂尔多斯羊绒集团污水处理厂中的大型连续微滤化学清洗提供依据.     

实炉底节能连续式加热炉

轧钢生产使用实炉底连续式加热炉加热钢坯，炉内双纵滑管用耐热耐高温材料，无水冷，起到节约水、电的作用，达到节能增效的目的。