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71.
72.
A novel method for the preparation of short nylon fiber–natural rubber composites was developed in which short fibers chopped to approximately 6 mm were incorporated in the latex stage and processed into sheet form. By this method, mixing cycle time was reduced without compromising the fiber dispersion. Fiber breakage during mixing was reduced. The new composites when compounded with a dry bonding system based on hexamethylenetetramine, resorcinol and hydrated silica (HRH) showed improved modulus, tensile strength and abrasion resistance compared to conventional composites. Tear strength, resilience, and compression set were similar to the conventional composites. SEM analysis indicated better interaction between matrix and fibers in the case of latex master batch. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
73.
The scope of the present work is the application of a particular class of strain energy function, based on the logarithmic strain, for the prediction of the twisting moment and axial force of a rubber circular cylinder under combined extension and torsion. The strain energy function involves four material parameters three of which are determined by fitting published experimental data from simple tensile and compression tests of natural rubber. One of the parameters of the proposed model has physical meaning, and it is equal to one ninth of the initial modulus of elasticity of the material. Hence, the number of unknown parameters is reduced to three. The logarithmic strain energy function is then applied to a combined extension and torsion problem of a rubber circular cylinder to check its performance for more complicated deformations. The results are compared with corresponding experimental and theoretical solutions available in the literature to validate the proposed model. It is found that the proposed strain energy function apart from predicting the common modes of deformations is also capable to determine more complicated types of deformation. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
74.
Morphology of carbon black (CB)‐filled rubber was studied with AFM and SEM and the classification of filler agglomerates, based on their internal structure and filler–matrix interactions, has been proposed. It varies according to the activity of CB and the kind of rubber. It has been shown that fracture of rubber starts either inside filler agglomerates (de‐cohesion) or in a filler–matrix interphase (de‐adhesion) initiating wear of the material. Microscopic observations correlate well with TGA and EPR data of wear debris collected during friction of rubber. The increase of thermal stability of CB and the appearance of additional spin signals, respectively, for elongated samples or debris, are proposed to be associated with de‐cohesion or de‐adhesion of the agglomerates. New approach to the fracture of rubber called “fatal agglomerate concept” is presented. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
75.
橡胶Mooney—Rivlin模型材料系数对轴向刚度影响分析 总被引:4,自引:0,他引:4
在橡胶小变形范围内,采用理论推断的方法,得到在相同硬度下橡胶Mooney—Rivlin模型材料系数由C2/C1决定的关系式。并采用ABAQUS有限元软件分析的方法,结合橡胶轴向刚度常规解,分析了C2/C1不同值对橡胶轴向刚度的影响进行,结果显示其影响呈现一定规律性。 相似文献
76.
从选矿尾矿中回收超细绢云母粉工艺是近几年发展起来的一项资源综合利用新工艺。研究从尾矿的工艺矿物学入手,介绍了尾矿的矿物组成及回收工艺的工作原理,着重探讨了超细绢云母粉在橡胶、塑料、涂料等领域中的应用情况。 相似文献
77.
经过对支座转角组合进行的分析,在研究柔性高墩墩顶转角位移计算方法的基础上,提出了更加严密的支座转角验算修正公式,得出修正后的转角验算公式易于应用的结论,对于保证板式橡胶支座在使用过程中不脱空有重要的意义。 相似文献
78.
The effect of FEF carbon black as filler on the thermal capacity c, diffusivity a, and thermal conductivity λ, of styrene butadiene rubber (SBR) composites in the temperature range 300–420 K was studied. The filler strongly increases the thermal diffusivity, whilst strongly decreasing the thermal capacity and the thermal conductivity (except at high FEF content ≥80 phr). The influence of the filler on the thermoelastic behaviour of the same composites was also investigated. It was found that the thermoelastic temperature change (ΔT) increased with carbon black concentration as well as the entropy change per unit extension. 相似文献
79.
80.
Monomer recycling for vulcanized silicone rubbers in the form of cyclosiloxane monomers. Role of acid buffers 总被引:3,自引:0,他引:3
The KOH-catalyzed depolymerization of vulcanized silicone rubbers to reproduce cyclosiloxane monomers was studied. First, the depolymerization was carried out in toluene with varying amounts of KOH to find that the yield of monomers first increased and then decreased with the increment of KOH, the highest yield was 65% at the molar ratio KOH/(Si–O) UNITS=0.08. At the molar ratio 0.13 in the absence of solvent, the monomers yield was 46%. However, when an acid buffer such as KH2PO4 and KCOOC6H4COOH was added after the KOH-catalyzed depolymerization was over, the product yield was increased remarkably to more than 80%. 相似文献