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31.
CHEN Yong-ping LI Chi-wai ZHANG Chang-kuang 《水动力学研究与进展(B辑)》2006,18(2):148-155
1. INTRODUCTION When wastewater is discharged into rivers, lakes or oceans, it usually leads to the formulation of turbulent jet with a free surface. If the ambient water depth is shallow, the jet will impinge on the water surface and the confinement of f… 相似文献
32.
碳黑对苯乙烯自由基聚合反应影响的研究 总被引:1,自引:0,他引:1
研究了碳黑对苯乙烯单体聚合物反应的影响,结果表明,用过氧化苯甲酰作引发剂,普通碳黑子对苯乙烯的聚合有强烈的阻聚作用,而用偶氮二异丁腈引发聚合物时,普通碳黑的阻聚性很小,当时碳黑进行接枝处理后,接枝碳黑对苯乙烯自由基聚合的影响程度与接枝方法有关,其中过氧化苯甲酰 自由基枝枝碳黑的聚性变化较大。 相似文献
33.
Maher M. Osman Mounir M. Abd El-Malek Aida B. Tadros Atef M. Michael 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,62(1):46-52
4-Amino-3-thio-1,24-triazolidine (L1) and 4-amino-5-thio-1,3,4-thiadiazole (LII) as well as their metal complexes of the general formulae MLI·2H2O and MLIICl (M; Pb(II), Cd(II) and Zn(II)) were prepared. With Sn(II), we obtained Sn(LI)2·2H2O and SnLIICl, respectively. The structures of the compounds were identified through elemental analysis, and IR and UV spectra measurements, in addition to thermal analysis in case of the metal complexes. The antifouling properties of the compounds were tested by their incorporation into paint formulations which were applied to PVC substrates and tested in water from Alexandria western harbour. When the compounds were added at 17·5% by volume, the coated panels were fouled after 3 months of immersion. The addition of 6·7% by volume of tributyltin oxide to 15·8% of the prepared compounds in one formulation elevated the paint efficiency and prevented fouling for 11 months. Paint containing solely tributyltin oxide at the same concentration was inactive against algae. 相似文献
34.
ABSTRACT: The content of phenolic acids in strawberries was determined before and after gamma-irradiation in the dose range 1 to 10 kGy. Fresh whole strawberries were irradiated, acid-base-hydrolyzed, and purified on polyamide columns. The compounds were analyzed by reversed-phase chromatography and detected with a diode-array detector. Dose/concentration relationships were obtained for gallic acid, 4-hydroxybenzoic acid, cinnamic acid, p-coumaric acid, and caffeic acid. Whereas radiolysis of the individual acids in aqueous solutions led to their efficient degradation and to a notable hydroxylation, in the complex matrix of food no hydroxylation products were formed and only the amount of 4-hydroxybenzoic acid was affected by irradiation (build up: 0.68 ± 0.04 mg kg−1 kGy−1 ). 相似文献
35.
研制出了具有保护储层效果的无固相压井液,其基液配方为0.5%LG-1-1+0.4%LG-2+1%小阳离子+0.1%其它。此外还研究开发出了无机盐增溶剂LG-3,加入LG-3可加宽低成本无机盐的使用范围,很大程度地降低压井液配液成本和单井综合成本。该压井液密度在1.0-2.5g/cm^3之间可调,具有无固相、滤失量低、抑制性强等特点,抗温能力在120℃左右。室内性能评价结果表明,无固相压井液对高渗储层岩心的渗透率损害率平均为4.0%,对低渗储层岩心的渗透率损害率平均为2.9%,说明该体系对储层具有很好的保护效果。 相似文献
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Gibbs energies of formation of CoF2 and MnF2 have been measured in the temperature range from 700 to 1100 K using Al2O3-dispersed CaF2 solid electrolyte and Ni+NiF2 as the reference electrode. The dispersed solid electrolyte has higher conductivity than pure CaF2 thus permitting accurate measurements at lower temperatures. However, to prevent reaction between Al2O3 in the solid electrolyte and NiF2 (or CoF2) at the electrode, the dispersed solid electrolyte was coated with pure CaF2, thus creating a composite structure. The free energies of formation of CoF2 and MnF2 are (± 1700) J mol−1; {fx37-1} The third law analysis gives the enthalpy of formation of solid CoF2 as ΔH° (298·15 K) = −672·69 (± 0·1) kJ mol−1, which compares with a value of −671·5 (± 4) kJ mol−1 given in Janaf tables. For solid MnF2, ΔH°(298·15 K) = − 854·97 (± 0·13) kJ mol−1, which is significantly different from a value of −803·3 kJ mol−1 given in the compilation by Barinet al. 相似文献
39.
Qin‐Tao Liu Malcolm R Clench Judith L Kinderlerer 《Journal of the science of food and agriculture》2002,82(5):553-558
Structural isomers of monoacylglycerols (monoglycerides, MAGs) were identified and compared after degradation of butter oil by two strains of Penicillium roquefortii and a commercial lipase from P roquefortii (EC 3.1.1.3) at pH 7.0 and 10 °C. The conditions were selected as they were comparable with those used in the manufacture of blue mould‐ripened cheese. The commercial lipase was selected to compare with the fungal strains in terms of acyl migration. Results showed that the main isomers formed by lipolysis with the commercial lipase were sn‐2 MAGs (64 mol%), whilst spores and emerging mycelia of P roquefortii produced mainly sn‐1(3) MAGs (83–90 mol%). The work reported here may lead to further assessment of different MAG structural isomers as natural preservatives in foods and dairy products. © 2002 Society of Chemical Industry 相似文献
40.
Yu‐Qing Cao Zhan Zhang Yan‐Xin Guo 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(10):1441-1444
A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry 相似文献