全文获取类型
收费全文 | 12334篇 |
免费 | 1465篇 |
国内免费 | 530篇 |
专业分类
电工技术 | 305篇 |
综合类 | 974篇 |
化学工业 | 4055篇 |
金属工艺 | 504篇 |
机械仪表 | 400篇 |
建筑科学 | 576篇 |
矿业工程 | 180篇 |
能源动力 | 332篇 |
轻工业 | 2241篇 |
水利工程 | 297篇 |
石油天然气 | 586篇 |
武器工业 | 79篇 |
无线电 | 817篇 |
一般工业技术 | 1683篇 |
冶金工业 | 473篇 |
原子能技术 | 123篇 |
自动化技术 | 704篇 |
出版年
2024年 | 46篇 |
2023年 | 140篇 |
2022年 | 211篇 |
2021年 | 309篇 |
2020年 | 382篇 |
2019年 | 458篇 |
2018年 | 412篇 |
2017年 | 495篇 |
2016年 | 468篇 |
2015年 | 495篇 |
2014年 | 625篇 |
2013年 | 788篇 |
2012年 | 829篇 |
2011年 | 841篇 |
2010年 | 641篇 |
2009年 | 649篇 |
2008年 | 549篇 |
2007年 | 751篇 |
2006年 | 743篇 |
2005年 | 606篇 |
2004年 | 466篇 |
2003年 | 451篇 |
2002年 | 486篇 |
2001年 | 421篇 |
2000年 | 364篇 |
1999年 | 307篇 |
1998年 | 222篇 |
1997年 | 184篇 |
1996年 | 185篇 |
1995年 | 131篇 |
1994年 | 136篇 |
1993年 | 95篇 |
1992年 | 78篇 |
1991年 | 67篇 |
1990年 | 54篇 |
1989年 | 45篇 |
1988年 | 38篇 |
1987年 | 17篇 |
1986年 | 17篇 |
1985年 | 27篇 |
1984年 | 19篇 |
1983年 | 19篇 |
1982年 | 21篇 |
1980年 | 3篇 |
1977年 | 3篇 |
1966年 | 5篇 |
1961年 | 4篇 |
1959年 | 3篇 |
1956年 | 2篇 |
1951年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
混合型表面活性剂液膜法处理含酚废水研究 总被引:25,自引:1,他引:24
研究了兰-113B=Span-80--煤油NaOH液膜体系处理苯酚废水的最佳操作工用于对高浓度含酚废水进行处理,实验结果表明,混合型表面活性剂各项指标均较好,除酚效率可达99%以上,对内相NaOH的最佳浓度的确定给出了估算方法。 相似文献
32.
Shiro Matsuoka 《Journal of research of the National Institute of Standards and Technology》1997,102(2):213-228
The high frequency end of the relaxation spectrum for polymer molecules involves the rotation of the segmental bonds. This fast relaxation process, however, cannot take place easily in the condensed state crowded by the densely packed conformers, necessitating the slower cooperatively synchronous relaxation. As the temperature is lowered, the domain of cooperativity grows towards the infinite size at the Kauzmann zero entropy temperature, though actually the system deviates from the equilibrium as the glass transition intervenes typically at 50 K above that temperature. The excess enthalpy and entropy drop faster than predicted by the rotational isomeric states which would reach zero only at 0 K. The real ΔCP is greater than that of the RIS value. The actual volume in excess of the crystalline lattice volume, however, points towards zero at 0 K. Thus, a polymer with higher Tg typically exhibits a lower density and modulus in the glassy state. Since the configurational entropy associated with the free volume is proportional to the logarithm of the latter, the Kauzmann temperature can be scaled by ln M, where M is the algebraic average of the conformer molecular weight. The temperature dependence of the most dominant, i.e., the largest equilibrium domain size will result in the Adam-Gibbs and Vogel equations for the characteristic relaxation time. The cooperative domain distribution leads to the relaxation spectrum that follows a power law. The relationship between the characteristic relaxation time and the rate of physical aging is derived. 相似文献
33.
三维有自由表面问题的数值模拟研究 总被引:3,自引:1,他引:2
本文采用求解三维弱可压流动模型及带浮力修正的K-ε两方程湍流模型的方法,用有限差分法数值求解,研究了有密度差的污染物在复杂流场中的对流扩散规律。文中给出一种简单而有效的处理自由面边界的方法,并详细地给出一个三维弱可压的流体动力学计算方法,数值计算表明本文的方法能较好地给出自由面的变化规律、流场的非定常过程及预测了污染物的对流扩散规律。 相似文献
34.
35.
New measurements of the vapor-phase viscosity of phenol were performed from 437 up to 624 K and for densities between 0.006 and 0.023 mol · L–1 in an all-quartz oscillating-disk viscometer with small gaps. Thus, including our own measurements reported earlier, experimental data are available in the temperature range between 376 and 639 K and in the density range from 0.001 up to 0.023 mol · L–1. The data were evaluated with a density series for the viscosity in which only a linear density contribution is included. The values of the second viscosity virial coefficient obtained for phenol as well as for benzene, toluene, and p-xylene were compared with results of the Rainwater-Friend theory and of the modified Enskog theory on the basis of the Lennard-Jones 12-6 potential. The agreement is reasonable, when the potential parameter ratios determined by Bich and Vogel are used. The influence of bound dimers seems to be already taken into account in the three-monomer contribution according to Hoffman and Curtiss.Paper dedicated to Professor Joseph Kestin. 相似文献
36.
37.
不同粒度松散煤体的氧扩散特性实验研究 总被引:1,自引:0,他引:1
以自行研制的煤对氧扩散特性测试装置为实验手段,在常温环境条件下测试了不同粒度松散煤体对氧的自由扩散特性.实验结果表明:煤样粒度的变化对取气腔氧浓度流出曲线的影响表现出2个极限值,煤样粒度在20~100目之间时,取气腔氧气浓度梯度随煤样粒度的增大而增大;当煤样粒度<20目或>100目时,煤样粒度的再变化对氧浓度流出曲线的影响则微乎其微;取气腔氧浓度曲线流形基本符合指数曲线的变化规律. 相似文献
38.
合成2,4-二叔丁基苯酚工业试验 总被引:2,自引:0,他引:2
以离子交换树脂为催化剂,苯酚和甲基叔丁基醚为原料合成2,4-二叔丁基苯酚(简称2,4酚),合成产物经过滤再经间歇真空精馏精制提纯,得到高纯度的2,4酚成品。成品精馏后釜中残液在酸性白土催化剂的作用下通过歧化反应生成对叔丁基苯酚,再经精馏提纯得到成品对叔丁基苯酚。通过工艺优化,使2,4酚、对叔丁基苯酚形成联产生产工艺,降低了生产原料消耗和成本。 相似文献
39.
Akihiko Sakurai Mina Masuda Mikio Sakakibara 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(9):952-958
The removal of phenol by peroxidase‐catalysed polymerization was examined using Coprinus cinereus peroxidase in the presence of surfactants. The non‐ionic surfactants with poly(oxyethene) residues, Triton X‐100, Triton X‐405 and Tween 20, enhanced the phenol removal efficiency at a level similar to high relative molecular mass poly(ethylene glycol) (relative molecular mass 3000). Although the improvement in the removal efficiency was less than that of Triton X‐100, Span 20, sodium lauryl sulfate (SDS) and lauryl trimethylammonium bromide (DTAB) also enhanced the removal efficiency. The requirement of the enzyme for almost 100% removal of 100 mg dm?3 phenol decreased to one‐fourth by the addition of 30 mg dm?3 Triton X‐100. Triton X‐100, Triton X‐405, Tween 20 and DTAB could reactivate the enzyme precipitated with the phenol polymer, leading to the restarting of the phenol removal reaction. Copyright © 2003 Society of Chemical Industry 相似文献
40.
ABSTRACT: The absorbance of 2,2-diphenyl-1-picrylhydrazyl (DPPH) at 517 nm in methanol and acetone decreased by 20 and 35% for 120 min at 25 °C under light, respectively; in the dark it did not change significantly for 150 min. Decomposition of DPPH under 21% oxygen after 90 min under light was significantly higher than that under 1% oxygen. Absorbance of DPPH in pH 4 buffer solution in methanol, and in pH 10 buffer solution in acetone, decreased by 55 and 80%, respectively, under light for 120 min. The evaluation of antioxidant activity by the changes of DPPH absorbance should be carefully interpreted since the absorbance of DPPH at 517 nm is decreased by light, oxygen, pH, and type of solvent in addition to the antioxidant. 相似文献