全文获取类型
收费全文 | 5465篇 |
免费 | 199篇 |
国内免费 | 68篇 |
专业分类
电工技术 | 17篇 |
综合类 | 306篇 |
化学工业 | 3831篇 |
金属工艺 | 29篇 |
机械仪表 | 12篇 |
建筑科学 | 43篇 |
矿业工程 | 9篇 |
能源动力 | 14篇 |
轻工业 | 383篇 |
石油天然气 | 279篇 |
武器工业 | 4篇 |
无线电 | 18篇 |
一般工业技术 | 686篇 |
冶金工业 | 20篇 |
原子能技术 | 74篇 |
自动化技术 | 7篇 |
出版年
2024年 | 4篇 |
2023年 | 19篇 |
2022年 | 23篇 |
2021年 | 51篇 |
2020年 | 51篇 |
2019年 | 55篇 |
2018年 | 33篇 |
2017年 | 70篇 |
2016年 | 72篇 |
2015年 | 90篇 |
2014年 | 114篇 |
2013年 | 186篇 |
2012年 | 319篇 |
2011年 | 316篇 |
2010年 | 296篇 |
2009年 | 316篇 |
2008年 | 293篇 |
2007年 | 370篇 |
2006年 | 474篇 |
2005年 | 360篇 |
2004年 | 331篇 |
2003年 | 340篇 |
2002年 | 268篇 |
2001年 | 226篇 |
2000年 | 192篇 |
1999年 | 184篇 |
1998年 | 135篇 |
1997年 | 131篇 |
1996年 | 67篇 |
1995年 | 66篇 |
1994年 | 62篇 |
1993年 | 62篇 |
1992年 | 31篇 |
1991年 | 29篇 |
1990年 | 35篇 |
1989年 | 12篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 10篇 |
1984年 | 12篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1951年 | 1篇 |
排序方式: 共有5732条查询结果,搜索用时 62 毫秒
21.
22.
23.
24.
已二醇二丙烯酸酯对真丝的接枝改性研究 总被引:2,自引:0,他引:2
研究了用二醇二丙烯酸酯为接枝单体、过硫酸铵(APS)为引发剂对真丝的接枝共聚反应,分析了接枝率的影响素,并测试了改性真丝的主要应用性能。结果表明:乳液和乙醇/水为溶剂的2种体系都能在真丝上获得较高接枝率。对于乙醇/水体系v(乙醇):v(H2O)=1:1,接枝单体20~30g/L,2%甲酸4ml,引发剂APS 0.5g/L,65~70℃接枝60min的接枝率高。改性后真丝的断裂强度、延伸度、吸湿性能都可获得改善,对酸、碱的溶解性提高,但染色性能提高不明显,对泛黄性改善一般。 相似文献
25.
Poly(vinylbenzyltrimethylammonium chloride)‐graft‐cotton cellulose, an anion‐exchange matrix, was synthesized by a mutual radiation‐induced grafting technique with a 60Co γ‐radiation source. The grafted matrix was characterized by grafting yield estimation, elemental analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy. The grafting yield decreased with the increase in the dose rate. However, the grafting yield and nitrogen content of grafted samples increased almost linearly with an increase in the total irradiation dose. To evaluate the performance of the grafted anion‐exchange matrix, the protein adsorption and elution behavior were investigated in a continuous column process under various experimental conditions, with bovine serum albumin used as a model protein. The binding and elution behavior of the anion‐exchange matrix depended on different experimental parameters, such as the grafting yield, ionic strength, pH of the medium, and amount of protein loaded. From a breakthrough curve, the equilibrium binding capacity and elution percentage of the grafted anion‐exchange matrix were estimated to be 40 mg/g and 94%, respectively. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5512–5521, 2006 相似文献
26.
The photografting of methacrylic acid (MAA) on a linear low‐density polyethylene film (thickness = 30 μm) under air and nitrogen atmospheres was investigated at 60°C in mixed solvents consisting of water and an organic solvent, with xanthone as a photoinitiator. The organic solvents used were acetone, methanol, tetrahydrofuran, and dioxane. A maximum percentage of grafting occurred at a certain concentration of the organic solvent in the mixed solvent. This was observed for the systems under both air and nitrogen. The grafting reaction under air exhibited an induction period, but the rate of grafting after the period was greater than that under nitrogen. The formation of poly(ethylene peroxide)s by photoirradiation seemed to be a factor for the accelerated photografting under air. On the basis of attenuated total reflection infrared spectroscopy and scanning electron microscopy of the grafted film, the MAA‐grafted chains of the sample prepared under air tended to penetrate more deeply inside the film than those of the sample prepared under nitrogen. The resulting grafted films exhibited a pH‐responsive character: the grafted films shrank in an acidic medium but swelled in alkaline medium. This was evaluated from measurements of dimensional changes in the grafted films. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 992–998, 2003 相似文献
27.
Nonionic organic contaminants such as phenol, benzene, and toluene from contaminated wastewater on laboratory scale can be effectively sorbed by cellulosic wood pulp sheet incorporated with three polar functional groups. The synthesis was carried out by graft copolymerization reaction of N,N‐dimethylaminoethylmethacrylate with methacrylic acid onto wood pulp. The preparation conditions at which the grafting process proceeds homogeneously are determined. Characterization and some selected properties of the original and grafted wood pulp were evaluated using FTIR and scanning electron microscope, also, the removal of phenol, benzene, and toluene on laboratory scale was investigated by using gas chromatography. It was found that phenol shows the highest removal percent than that of benzene and toluene. The efficiency of removal of the nonionic contaminants is found to be 97%, which shows a great promise for its applicability in the removal of organic contaminates from wastewater. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3589–3595, 2006 相似文献
28.
Mangala Tillekeratne Margaret Jollands Ferenc Cser Sati N. Bhattacharya 《应用聚合物科学杂志》2006,100(4):2652-2658
Polymer/layered‐silicate nanocomposites have gathered momentum as cost‐effective and versatile materials since the middle of the 20th century. Many publications discuss the chemistry of organomodification and properties of nanocomposites, but relatively few deal with the significance of processing conditions. This article takes into account three mixing parameters and discusses the contribution of each toward nanocomposite formation. Organomodified natural sodium‐type bentonite clay was used in this study. The nanocomposites formed were characterized by X‐ray diffraction and mechanical property tests. Response surface regression was used to optimize the tensile modulus. The analysis shows that nanocomposite formation is promoted by a diffusion mechanism and that the interactions of parameters are as important as individual parameters. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2652–2658, 2006 相似文献
29.
A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution 1H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry 相似文献
30.