3-N-丙酰基-2-芳基-5-(3-碘苯基)-1,3,4-(噁)唑啉类化合物的合成及表征

以3-碘苯甲酸为原料，在浓硫酸作用下与乙醇反应制得3-碘苯甲酸乙酯（1），再以无水乙醇为溶剂，在105℃化合物1与80％的水合肼反应8h，制得3-碘苯甲酰肼（2）。在无水乙醇中，在90～95℃化合物2分别与4-甲基苯甲醛、2-氯苯甲醛、4-氯苯甲醛、4-羟基苯甲醛、2，4-二氯苯甲醛、4-甲氧基苯甲醛、3-硝基苯甲醛、4-硝基苯甲醛和4-二甲氨基苯甲醛反应得到相应的酰腙E3（a～i）]。最后化合物3（a～i）分别与丙酸酐脱水环化成了3-M丙酰基-2-芳基-5-（3-碘苯基）-1，3，4-噁唑啉类化合物E4（a～i）]，收率分别为86．2％，70．5％，80．1％，68．2％，62．4％，75．2％，73．2％，70．5％和63．2％。并通过元素分析，IR，^1H NMR和MS对化合物4（a～i）的结构进行了表征。     

溶胶-凝胶法制备Na_2WO_4~-Mn/SiO_2催化剂及其甲烷氧化偶联反应性能的研究

采用溶胶-凝胶法制备了一系列5%Na2WO4-2%Mn/SiO2催化剂;用XRD、XPS、BET、O2-TPD和CO2-TPD等方法对催化剂进行了表征,并考察了对甲烷氧化偶联反应的催化性能。结果表明,与常规浸渍法相比,采用溶胶-凝胶法制备的Na2WO4-Mn/SiO2催化剂中W和Mn的原子浓度在催化剂表面和体相分布较为接近,而且两种制备方法所得的催化剂具有相似的催化性能,Na2WO4与α-方石英之间的相互作用,催化剂释放晶格氧的能力,碱性强弱是影响甲烷氧化偶联活性的关键因素。     

博兴洼陷沙四上亚段高精度层序格架研究

博兴洼陷下第三系沙四上亚段滩坝砂体十分发育，主要是一套砂泥岩的薄互层，横向变化快，在地震剖面上难以识别和描述，用常规的地质研究方法难以预测砂体的分布趋势。本文应用高精度层序地层学的原理和方法，通过测井、岩心资料的综合分析，重点对沙四上亚段进行了高精度层序地层划分，共识别出了5个具有等时意义的水进面（四级层序界面），建立了洼陷内沙四上亚段的四级层序格架，在四级层序格架基础上进行了沉积体系分析，并对层序发育的控制因素进行了探讨。本研究对洼陷内隐蔽油气藏的进一步勘探具有重要的指导意义。     

An MPEG‐4 Compliant Interactive Multimedia Streaming Platform Using Overlay Networks

This paper presents a multimedia streaming platform for efficiently transmitting MPEG‐4 content over IP networks. The platform includes an MPEG‐4 compliant streaming server and client, supporting object‐based representation of multimedia scenes, interactivity, and advanced encoding profiles defined by the ISO standard. For scalability purposes, we employ an application‐layer multicast scheme for media transmission using overlay networks. The overlay network, governed by the central entity of the network distribution manager, is dynamically deployed according to a set of pre‐defined criteria. The overlay network supports both broadcast delivery and video‐on‐demand content. The multimedia streaming platform is standards‐compliant and utilizes widespread multimedia protocols such as MPEG‐4, real‐time transport protocol, real‐time transport control protocol, and real‐time streaming protocol. The design of the overlay network was architected with the goal of transparency to both the streaming server and the client. As a result, many commercial implementations that use industry‐standard protocols can be plugged into the architecture relatively painlessly and can enjoy the benefits of the platform.     

机载高分辨力SAR实时运动补偿的实现

本文详细地分析了载机运动误差与回波相位的关系,提出了基于G4DSP信号处理板的机载SAR实时运动补偿方法,该方法利用G4DSP的四个CPU构成流水线处理器,采用子孔径方法分段提取回波的多普勒调频斜率,然后利用调频斜率的变化计算载机的运动误差,通过相位误差函数与方位数据的时域相乘补偿运动误差。实时信号处理机的实验表明,本文方法能实时和有效的实现机载SAR运动补偿,获得满意的成像质量。     

Ring‐opening polymerization of lactones initiated by diphenylzinc–coinitiator systems

Diphenylzinc, alone or in combination with water and butanone as coinitiators, was used as a polymerization initiator system for a variety of lactones at varying temperatures. The resulting data indicate that the course of the polymerization is greatly influenced by the lactone structure, as well as by the molar ratio of coinitiator to diphenylzinc. When used alone, diphenylzinc exhibited high activity as an initiator in δ‐valerolactone polymerizations, although it was less efficient when used in the β‐butyrolactone and the β‐propiolactone polymerizations. Activity in the polymerization of β‐lactones was increased by adding small amounts of butanone or water. It was also observed that the diphenylzinc–butanone combination was more effective than the diphenylzinc–water mixture in the polymerizations of β‐butyrolactone and β‐propiolactone. Copyright © 2003 Society of Chemical Industry     

HB-3、HB-4型钴钼触媒升温硫化总结

总结了HB - 3,HB - 4型钴钼触媒升温硫化过程及注意事项 ,简单介绍了使用情况 ,并针对出现的问题采取了一定措施     

Biotransformation of l‐menthol by twelve isolates of soil‐borne plant pathogenic fungi (Rhizoctonia solani) and classification of fungi

The microbial transformation of l‐menthol ( 1 ) was investigated by using 12 isolates of soil‐borne plant pathogenic fungi, Rhizoctonia solani (AG‐1‐IA Rs24, Joichi‐2, RRG97‐1; AG‐1‐IB TR22, R147, 110.4; AG‐1‐IC F‐1, F‐4, P‐1; AG‐1‐ID RCP‐1, RCP‐3, and RCP‐7) as a biocatalyst. Rhizoctonia solani F‐1, F‐4 and P‐1 showed 89.7–99.9% yields of converted product from 1 , RCP‐1, RCP‐3, and RCP‐7 26.0–26.9% and the other isolates 0.1–12.0%. In the cases of F‐1, F‐4 and P‐1, substrate 1 was converted to (?)‐(1S,3R,4S,6S)‐6‐hydroxymenthol ( 2 ), (?)‐(1S,3R,4S)‐1‐hydroxymenthol ( 3 ) and (+)‐(1S,3R,4R,6S)‐6,8‐dihydroxymenthol ( 4 ), which was a new compound. Substrate 1 was converted to 2 and/or 3 by RRG97‐1, 110.4, RCP‐1, RCP‐3 and RCP‐7. The structures of the metabolic products were elucidated on the basis of their spectral data. In addition, metabolic pathways of the biotransformation of 1 by Rhizoctonia solani are discussed. Finally, from the main component analysis and the differences in the yields of converted product from 1 , the 12 isolates of Rhizoctonia solani were divided into three groups based on an analysis of the metabolites. Copyright © 2003 Society of Chemical Industry     

Nd3+:Y0.5Gd0.5VO4晶体生长和基本特性

Nd^3 :Y0.5Gd0.5VO4晶体作为一种新的激光材料，可以用中频感应加热提拉法生长。X射线粉末衍射分析表明它的结构与Nd^3 :YVO4晶体结构相同，它的晶格常数介于YVO4和NdVO4晶格常数之间。用ICP光谱法测定晶体中Nd^3 含量为0．8at％，分凝系数为0．8，与Nd^3 :GdVO4晶体中Nd^3 的分凝系数0．78相当；用称重法测定其密度为5．00g／cm^3；用稳态纵向热流法测出其室温热导率为12．5W／mK。实验表明Nd^3 :Y0.5Gd0.5VO4晶体有希望作为高功率ID泵浦激光晶体材料。     

癸二酸二甲酯与1,2,2,6,6-五甲基哌啶醇的酯交换反应

对癸二酸二甲酯与1,2,2,6,6-五甲基哌啶醇的酯交换反应进行了研究;分别考察了四异丙基钛酸酯、氨基锂、氧化二辛基锡3种催化剂的性能;采用氢核磁共振确定了产物的结构;考察了以四异丙基钛酸酯为催化剂时反应温度、反应时间、原料配比和催化剂用量对反应的影响。实验结果表明,四异丙基钛酸酯催化剂的催化效果最好;在癸二酸二甲酯与1,2,2,6,6-五甲基哌啶醇摩尔比1∶1.79、四异丙基钛酸酯催化剂的用量为反应物总质量的0.31%、反应温度180℃、反应时间6h的条件下,所得产物中单(1,2,2,6,6-五甲基-4-哌啶基)癸二酸甲酯(简称单酯)质量分数为23%和双(1,2,2,6,6-五甲基-4-哌啶基)癸二酸酯(简称双酯)质量分数为73%,单双酯质量比为1∶3.17,产物收率为93.3%。该方法可得到理想的单双酯比例及产物收率,具有很好的工业应用前景。