13C n.m.r. study of raw materials for carbon black

¹³C n.m.r. spectroscopy has been applied to investigate a number of coal tar and petroleum-derived carbon black feedstocks. Application of the m>Jm>-modulated spin echo technique is especially rewarding, as this method renders the quaternary carbons directly detectable. Thus the quality of carbon black feedstocks can additionally be gauged on the basis of the contents of quaternary carbons, which is a direct indication of the carbon yield in the carbon black production process.     

Analysis of epoxidized natural rubber. A comparative study of d.s.c., n.m.r., elemental analysis and direct titration methods

A comparative analysis of epoxidized natural rubber samples by ¹H and ¹³C n.m.r., titrimetric, elemental and d.s.c. techniques has been made. Whereas the titrimetric method is only applicable at low epoxy contents (< 15 mol%) both n.m.r. methods give reasonable precision over the compositional range of 20–75 mol%. Elemental analysis appears less reliable. D.s.c. analysis through measurement of m>Tm>_g provides the highest precision of measurement but requires independent calibration by one or more of the primary methods. The epoxy content may also be related to the polymer density.     

The influence of an intermediate MoO3 layer on the solid state reaction of cobalt oxide withγ-Al2O3

In view of the importance for Co_xO_y,-MoO₃/mg src="/content/m608451j26813318/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0">-Al₂O₃ hydrodesulphurization (HDS) catalysts, the reactivity of cobalt oxide layers towards cobalt aluminate formation was investigated on both MoO₃-covered and bare mg src="/content/m608451j26813318/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0">-Al₂O₃ substrates. Co₃O₄/MoO₃/mg src="/content/m608451j26813318/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0">-Al₂O₃ and Co₃O₄/mg src="/content/m608451j26813318/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0">-Al₂O₃ systems were prepared by vapour-deposition of MoO₃ (12 × 10¹⁵ Mo atoms/cm²) and Co (400 × 10¹⁵ Co atoms/cm²) layers onto a mg src="/content/m608451j26813318/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0">-Al₂O₃ substrate, followed by oxidation of the Co layer to Co₃O₄. After annealing at 800°C for 40 h, the interfacial reaction to cobalt aluminate was assessed using Rutherford backscattering spectrometry. The presence of molybdenum oxide appeared to enhance cobalt aluminate formation. The Mo atoms, which spread out over the entire cobalt-containing layer, presumably caused a high defect density, which explains the observed higher reaction rate. The amount of MoO₃ was much too low to stabilize all cobalt atoms by cobalt molybdate formation.     

7.63m特大型焦炉砌筑施工技术及要点

主要针对7.63m特大型焦炉砌筑施工技术,从工程实践效果分析其施工技术在质量、工期、成本等方面收到良好的经济效益和社会效益,现对7.63m特大型焦炉施工技术作简要介绍。     

掺Er^3＋镓磷酸盐玻璃的光学性质

利用熔融淬火法制备了摩尔分数为40．8Ga2O3-58．0NaPO3-1．2Er2O3掺Er^3＋镓磷酸盐玻璃,测试并研究了样品中Er^3＋的吸收光谱、1．5μm发射光谱,根据Judd-Ofelt理论计算了Er^3＋离子强度参量Ωt（t=2,4,6）及自发辐射概率、荧光分支比、自发辐射寿命．结果表明,Er3＋1．5μm发射光谱半峰全宽达到40nm．同时,利用McCumber方法计算了Er^3＋4 I13／2→^4I15／2跃迁的受激发射截面,峰值达到6．10×10^-21cm^2,测定了Er^3＋4I13／2能级荧光寿命为4．88ms,^4I13／2能级量子效率为56．3％．     

缺失数据下m相依样本的大样本性质

讨论了缺失数据在随机补充方式下均值的估计,证明了估计的相合性和渐进正态性,并给出了经验似然比统计量的渐进分布．     

住宅设计原理——“住”的思考

居住类建筑一直是建筑设计人员关注的重点,关于"住"的思考人们也从未停歇过,将结合一些流行的住宅设计观点展开对于"住"的思考.     

认知无线电多址接入系统的研究

针对认知无线电(Cognitive Radio)频谱不连续,随机性和变化性大,以及TDMA,FDMA,CDMA不适用的问题,提出了一个基于变换域通信(Transform Domain Communication System)平台的认知无线电多址接入系统.该系统发射机通过将非空闲的频谱幅度置0,实现对授权用户的躲避;采用m状态序列产生的伪随机相位矢量,生成近似正交的调制基函数实现用户的多址接入;接收端通过本地基函数与接收信号相关估计出原始数据,并理论分析了系统的误码率.仿真表明,系统的检测概率,多址接入的用户数以及收发两端基函数的不一致会影响系统的性能.该系统能利用非连续频谱,并且基函数能够自适应变化,适合认知无线电。     

50000m3外浮顶储罐施工方法探讨

本文根据我公司在新疆油田公司油气储运公司承建的50000m~3外浮顶储罐建设工程实践,借鉴国内外大型储罐建造技术,结合我公司成熟的储罐建造经验,探讨建造大型外浮顶储罐的一种施工方法——外脚手架正装法,同时介绍工厂预制和现场自动化焊接技术,并结合工期控制等问题论述该施工方法的特点。     

Activation of Ni/A12O3 catalysts through modification of the Al2O3 support

The effect of alumina pretreatment on the performance of alumina supported nickel catalysts was demonstrated in gas phase hydrogenation of toluene to methylcyclohexane. The state of the alumina was changed from pure mg src="/content/p873708085vu625m/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0"> to pure mg src="/content/p873708085vu625m/xxlarge952.gif" alt="theta" align="BASELINE" BORDER="0"> phase through various heat treatments in air. The catalysts were prepared from vapor phase by saturating the accessible binding sites on the pretreated alumina with the nickel precursor. The highest number of active sites for hydrogenation was observed for catalysts prepared on alumina having an incomplete phase transition and a mg src="/content/p873708085vu625m/xxlarge952.gif" alt="theta" align="BASELINE" BORDER="0">/mg src="/content/p873708085vu625m/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0"> alumina phase ratio between 0.5 and 10. Results from temperature programmed desorption (TPD) studies revealed that a maximum in weakly chemisorbed hydrogen as well as in total amount of desorbed hydrogen was found for the same catalysts. By hydrogen chemisorption studies the total hydrogen uptake was found to correlate with the observed hydrogenation maximum. It is suggested that both the chemical and physical properties of the alumina influence the activity. An optimal metal-support interaction and structural defects on the alumina due to the phase transition can explain the observed maximum in the number of active sites and in hydrogen uptake.