Ermüdungsverhalten und Dauerfestigkeit von Graphit und Aluminium – infiltriertem Graphit

Fatigue behaviour and endurance limit of graphite and of aluminium‐infiltrated graphite Fatigue properties of polycrystalline, isotropic graphite FU2590 and of FU2590 infiltrated with AlSi7Mg (FU2590/AlSi7Mg) were investigated in reversed bending tests at 25 Hz at numbers of cycles below 10⁷ and in tension‐compression tests at 20 kHz below 10⁹ cycles. The open porosity of Graphite (10‐11 Vol.‐%) was infiltrated with the aluminium alloy using the squeeze casting infiltration method, which led to an increase of the bending strength by 50 %, increase of tensile strength by 30 % and increase of stiffness by 15 %. Fully reversed tension‐compression loading of FU2590 delivers a mean endurance limit at 10⁹ cycles at the normalized maximum stresses (i.e. maximum tension stress of a cycle divided by the static strength) of 0,65±0,03. Mean numbers of cycles to failure of 10⁴ were found in fully reversed bending tests at the normalized maximum stress of 0,78. The infiltrated material shows approximately 30 % higher cyclic strength in reversed bending tests, and the mean endurance limit under tension compression loading increases by 15 %. The increased endurance limit of the infiltrated material is caused by the increased stiffness. The increased toughness of graphite due to the infiltration with aluminium is of additional beneficial influence at the higher cyclic stresses investigated in reversed bending tests and in static tests.     

Phase equilibria of quasi-binary systems consisting of multicomponent polymers 1 and 2. IV: Poly(ethylene oxide)/poly(propylene oxide) systems

To confirm the reliability of the theory of phase equibria of multicomponent polymer 1/multicomponent polymer 2 systems (i.e. quasi-binary systems) and the method of computer experiment based on this theory (Brit. Polym. J., 23 (1990)285; 23 (1990)299; Polym. Int., 29 (1992)219), could point curves (CPC), two-phase volume ratios ( R ) and critical solution points (CSP) have been determined experimentally for the quasi-binary mixtures of poly(ethylene oxide) (M¯_w = 647, M¯_w/M¯_n = 1.15; M¯_w and M¯_n, the weight-average and numberaverage molecular weights, respectively) and poly(propylene oxide) (M¯_w = 2028, M¯_w/M¯_n = 1.08; and M_w = 2987, M_w/M_n = 1.13). The hydroxyl end groups of both polymers were methoxylated in advance by the Cooper & Booth method (Polymer, 18 (1977)164). The thermodynamic interaction parameter between both polymers, χ₁₂, and the concentration dependence parameters for the above quasi-binary systems were determined by the method proposed in a previous paper (Brit. Polym. J., 23 (1990)299). CPC, R and CSP values calculated on the basis of the theory are in good agreement with the values determined experimentally.     

孔型热轧时轧制力的实用计算公式

采用修正系数法,利用板材在带刻槽的冲头进行深冲与平面冲头下深冲时的接触压力的比值确定孔型影响系数,进而推导出孔型热轧时轧制力的实用计算公式.     

用超声处理在石墨表面形成梯度孔洞

研究了超声处理对石墨表面状况的影响。超声处理初期，增加超声处理时间使石墨显气孔率增加，表面孔洞数量增多，尺寸变大；超声处理5min后，超声处理时间增加，显气孔率和孔洞状态基本不变。用超声处理能在石墨表面内层附近形成比较理想的梯度分布孔洞。     

膨胀石墨对各种油类的吸附动力学

通过对吸附率(有效吸附系数)Ks和饱和吸附量msat的测量,描述了粘度为0.001 Pa·s～0.850 Pa·s的各种油类在膨胀石墨柱中的吸附动力学,发现吸附率Ks对油类粘度有很强的相关性.吸入膨胀石墨柱中的饱和吸附量msat几乎恒定在50kg/kg,该值略低于由膨胀石墨块直接浸渍在油中测得的吸附容量,这是由于所吸附的油沿膨胀石墨柱高度存在重力梯度.     

Effect of Calcium Lactate, 4-Hexyl Resorcinol and Vacuum Packing on Physico-chemical, Sensory and Microbiological Qualities of Minimally Processed Litchi (Litchi chinensis Sonn.)

Litchi (Litchi chinensis Sonn.) fruits are very susceptible to pericarp browning which adversely affects consumer acceptability even though the aril portion remains in excellent condition. Litchi arils (litchis) were treated with a solution containing 0–2% (w/v) calcium lactate (CL), 0–0.02% (w/v) 4‐hexyl resorcinol (4‐HR) and 1% potassium sorbate. The pH of solution was adjusted to 4.0 with citric acid. Treated litchis were packed in polystyrene trays, over‐wrapped with polypropylene film, vacuum‐packed (0, 47409.3, 94831.9 Pa) and stored at 4 ± 2 °C. Drip losses, pH, total soluble solids (TSS), sensory attributes and microbiological quality of stored samples were estimated. A four‐factor, three‐level experimental design (D₆ Hokes design) with 19 experiments was chosen. Mathematical models were developed to analyse and predict the effect of CL, 4‐HR, in‐package vacuum and storage time on the responses. TSS, pH and sensory scores decreased significantly (P 0.01), whereas drip losses and microbial count increased significantly (P 0.01) with time. Drip loss was significantly (P 0.1) reduced by addition of CL. 4‐HR prevented browning and changes in colour score during storage were significantly less. Vacuum in packages exerted significant (P 0.01) effect over pH, TSS, sensory and microbiological qualities of minimally processed litchis.     

Tearing, folding and deformation of a carbon-carbon sp-bonded network

A monolayer and a few layers of carbon sp²-bonded networks were torn and folded by the tip of an atomic force microscope at the steps on newly cleaved highly oriented pyrolytic graphite. It was found that the preferential breaking directions and folding axes are along the symmetry directions of the graphite hexagonal structure. Depending on the force exerted by the tip, breaking may occur along other directions. The torn part of the graphene sheet can even be stretched and deformed, and does not resume its original shape after release from the tip.     

石墨电极高温抗氧化技术研究现状

概述石墨电极抗氧化技术的研究现状，重点介绍选择抗氧化涂层体系的要求及涂层制备方法，包括包埋浸渗法、化学气相沉积法、等离子喷涂法及溶胶--凝胶法．展望了石墨电极材料高温抗氧化涂层研究的方向．     

无硫高抗氧化性可膨胀石墨的制备研究

用HNO3和KMnO4做氧化剂,H3PO4做辅助插层剂,磷酸盐做浸渍插层剂制备了无S高抗氧化性可膨胀石墨,用正交实验法分析并确定了制备的最佳工艺,得到的可膨胀石墨膨胀倍数达到320mL·g-1,不含S,且高温抗氧化性能得到明显提高.     

A Simple Quasi-2D Numerical Model of a Thermogage Furnace

A simple quasi-2D model for the temperature distribution in a graphite tube furnace is presented. The model is used to estimate the temperature gradients in the furnace at temperatures above which contact sensors can be used, and to assist in the redesign of the furnace heater element to improve the temperature gradients. The Thermogage graphite tube furnace is commonly used in many NMIs as a blackbody source for radiation thermometer calibration and as a spectral irradiance standard. Although the design is robust, easy to operate and can change temperature rapidly, it is limited by its effective emissivity of typically 99.5–99.8%. At NMIA, the temperature gradient along the tube is assessed using thermocouples up to about 1,500°C, and the blackbody emissivity is calculated from this. However, at higher operating temperatures (up to 2,900°C), it is impractical to measure the gradient, and we propose to numerically model the temperature distributions used to calculate emissivity. In another paper at this conference, the model is used to design an optimized heater tube with improved temperature gradients. In the model presented here, the 2-D temperature distribution is simplified to separate the axial and radial temperature distributions within the heater tube and the surrounding insulation. Literature data for the temperature dependence of the electrical and thermal conductivities of the graphite tube were coupled to models for the thermal conductivity of the felt insulation, particularly including the effects of allowing for a gas mixture in the insulation. Experimental measurements of the temperature profile up to 1,500°C and radial heat fluxes up to 2,200°C were compared to the theoretical predictions of the model and good agreement was obtained.