ABR处理农村生活污水填料选择的研究

采用厌氧折流板反应器(ABR)处理农村生活污水,并选择出适合农村生活污水处理的ABR填料。以立体弹性填料、纤维球填料和鲍尔环填料作为ABR填料,以无填料ABR为对照实验装置,考察了填料对ABR处理效果和生物相的影响,并对各填料ABR工程造价进行了分析。研究结果表明:装填立体弹性填料、纤维球填料和鲍尔环填料后,ABR对COD、SCOD和SS的去除率均有一定程度的提高;装填填料ABR中微生物种类和数量均多于无填料ABR;立体弹性填料的造价分别约为纤维球填料和鲍尔环填料的1/8和1/15。因此,立体弹性填料最适合作为ABR处理农村生活污水用填料,装置稳定后,出水COD、SCOD和SS的平均浓度分别为87.42、49.61和13.20 mg/L,平均去除率分别为59.04%、60.05%和84.12%。     

城市雨水径流多填料优化组合快速渗蓄试验研究

通过雨水径流渗蓄处理系统的填料筛选及多填料分层组合渗蓄处理径流的效能试验,分析了陶粒、稀土瓷砂、沸石、石英砂对城市雨水径流主要污染物COD及重金属Pb、Zn的吸附性能,研究了多填料优化组合快速渗蓄系统对径流污染物的处理效能。结果表明:陶粒、稀土瓷砂、沸石较石英砂具有更好的径流有机物及重金属污染物的吸附、离子交换等性能。将陶粒、稀土瓷砂、沸石组合作为径流渗蓄池的填料,3种填料各填装一层,每层厚度均为30 cm,则自上而下填料不同的填装组合方式,会导致径流渗蓄处理的效果有明显差异。渗蓄池填料自上而下的最佳分层组合为陶粒-稀土瓷砂-沸石,此时,径流COD、SS的渗蓄去除率分别高达94.82%、97.82%,对Pb、Zn的去除效率分别达到81.05%、75.64%,处理出水的COD约为50mg/L、SS约为25 mg/L、Pb、Zn浓度均约为0.13mg/L。对城市雨水径流的处理,该多填料优化组合快速渗蓄池较传统石英砂快滤池更高效。     

导热填料对HDPE/石蜡定形相变材料性能的影响

采用熔融共混技术,在高密度聚乙烯（HDPE）/石蜡定形相变材料中添加普通石墨、氧化膨胀石墨、超声膨胀石墨以及膨胀石墨（EG）4种导热填料制备导热定形相变材料（PCM）。SEM图表明导热填料可以与HDPE、石蜡均匀混合。添加导热填料后定形相变材料的渗漏率有增大的趋势,但添加普通石墨和超声膨胀石墨时,渗漏率随导热填料含量的增加而增加,添加氧化膨胀石墨和EG时,PCM的渗漏率随导热填料含量的增加而降低。定形相变材料中添加导热填料时其热导率有显著提高。添加EG时,定形相变材料的热导率提高最多,提高率达144.7%。     

Effects of various fillers on sintering,microstructures and properties of Ca-Ba-Al-B-Si-O glass/ceramic composites简

Low-temperature sintering and properties of LTCC （low temperature co-fired ceramics） materials based on CaO-BaO-Al2O3-B2O3-SiO2 glass and various fillers such as Al2O3, silica glass, christobalite, AlN, ZrO2, MgO-SiO2, TiO2 were investigated. The results show that densification, crystallization, microstructures and dielectric properties of the composites are found to strongly depend on the type of filler. The densification process of glass/ceramic composites with various fillers is mainly from 600 ℃ to 925 ℃, and the initial compacting temperature of samples is 600 ℃. The initial rapid densification of samples starts at its glass softening temperature. LTCC compositions containing Al2O3, silica glass, AlN and MgO-SiO2 fillers start to have the crystallization peaks at 890, 903, 869 and 844 ℃, respectively. The crystallization peaks are believed as correlated to the crystallization of CaAl2SiO8, β-SiO2, Ca2Al2SiO7 and β-SiO2. The composite ceramic with Al2O3, silica glass and TiO2 ceramic have a better dense structure and better smooth fracture surface. Sample for Al2O3 has the lowest dielectric loss tanδ value of 0.00091, whereas the sample for MgO.SiO, has the highest dielectric loss tanδ value of 0.02576. The sample for TiO2 has the highest dielectric constant value of 14.46, whereas the sample for AIN has the lowest dielectric constant value of 4.61.     

一类非线性微分差分方程整函数解

选取炭黑、谷壳灰、绢云母、蒙脱土、凹凸棒石和硅灰石等6种不同形态的无机填料,采用液态成型工艺,制备了无机填料／丁腈橡胶硫化胶,研究了无机填料对丁腈橡胶的力学性能、交联密度、耐燃料B性、耐油性、耐热老化性和微观形貌等特性的影响。结果表明：加入炭黑后,硫化胶的综合性能最佳;加入蒙脱土后,硫化胶的交联密度增至2．49×10^-4mol/cm3,三维交联程度增幅最大;加入凹凸棒石后,硫化胶在燃料B中质量变化率、体积变化率降至同比最低,对耐燃料B性能改善幅度最大;加入硅灰石后,硫化胶在油性环境中的质量、体积变化率、硬度变化最小,对耐油性改善最多;加入绢云母后,硫化胶在热空气氛围下质量变化率、体积变化率和硬度变化同比最小,对耐热老化性能改善幅度最大。     

Impact of sand and filler materials on the hydration behavior of calcium aluminate cement

In earlier work, we have observed discrepancies relating to the early hydration of calcium aluminate cement (CAC) when comparing data from heat flow calorimetry of CAC paste with results from mortar strength tests using the crushing method. Here, we investigated on this phenomenon and found that the sand which is used as a filler exerts a major influence on CAC hydration resulting in acceleration. Furthermore, in particular fine filler materials such as, for example, microsilica, fine limestone powder, and especially α- and γ-Al₂O₃ also produced a strong hydration accelerating effect which is dependent on their specific surface area. The mechanism underlying the acceleration is that under alkaline conditions their negative surface charge attracts calcium ions as was confirmed via inductively coupled plasma atomic emission measurements. Such a layer generates favourable conditions for the nucleation of CAC hydration products (C-A-H phases). The resulting crystalline hydrates which form on the surface of the filler particles submerged in CAC cement pore solution were visualized via SEM imaging. This way, specifically selected fillers can significantly accelerate CAC hydration and save precious lithium salts which are commonly used to boost the early strength of CAC.     

填料强化A/O工艺处理小城镇污水的实验研究

通过向模拟A/O生化池中投加填料强化该工艺处理小城镇污水的处理效果。结果表明,当O段溶解氧的质量浓度控制在2~3 mg/L,温度控制在28℃,进水p H在7.2~7.8的条件下,该工艺的优化水力停留时间为8 h、污泥回流体积比为20%,模拟装置在该优化工况下运行时,对COD、NH₄⁺-N及TP的平均去除率分别为91.1%、96.3%、73.3%。为提高除磷效果,增加后置化学辅助除磷后,TP平均去除率可达86%,出水中COD、NH(4)⁺-N含量均能达到GB 18918-2002的一级A标准,TP含量能达到一级B标准,去除效果较好。     

填料粒子成型对泡沫铝合金孔结构的影响

在实验的基础上 ,绘制出填料粒子成型时的体积与泡沫铝合金的孔隙率相对应的变化曲线 ,并应用力学的基本原理对泡沫铝合金孔结构的成形机理进行了研究。确定填料粒子成型时的体积变化应在 0 %～ 12 %之间 (此时泡沫铝合金的孔隙率应在 41.6 %～ 47.6 %之间 ) ,才能稳定填料粒子尺寸 ,从而更好地控制泡沫铝合金的孔径尺寸 ,提高成型质量 ,稳定泡沫铝合金的使用性能。     

Cr与B对镍基高温钎料在Cf/SiC陶瓷基复合材料上润湿性的影响

研究了Cr和B元素对镍基高温钎料在3D-Cf/SiC陶瓷基复合材料上的润湿性的影响.试验结果发现,在真空度小于10-3 Pa,工作温度1100 ℃,保温时间10 min条件下,当钎料中的Cr元素含量为15%,B元素含量为0.6%时,镍基钎料在Cf/SiC上的润湿角为10°,然而B元素含量增加到2.4%后,润湿角增大到62°,表明钎料中的元素B降低钎料在Cf/SiC上的润湿性.钎料中的活性元素Cr对润湿有重要影响.镍基钎料在Cf/SiC上的润湿过程属于反应润湿,润湿界面生成多种碳化物和硅化物.采用扫描电镜与能谱仪分析界面的微观结构与成分,通过X射线衍射仪检测界面产物.     

BNi—2钎焊条的真空吸铸工艺

研究了ＢＮｉ－２钎焊条真空吸铸原理，并由试验得出：当ＢＮｉ－２合金加热到１５００℃，真空控制阀门开口为φ６ｍｍ以上，真空度５０ｋＰａ，铸型预热温度５００℃，并用φ内２ｍｍ×５００ｍｍ石英管进行真空吸铸时，吸铸高度可达到４０ｃｍ以上。