Monoacylglycerols derived from butter oil by Penicillium roquefortii in suspension cultures

Structural isomers of monoacylglycerols (monoglycerides, MAGs) were identified and compared after degradation of butter oil by two strains of Penicillium roquefortii and a commercial lipase from P roquefortii (EC 3.1.1.3) at pH 7.0 and 10 °C. The conditions were selected as they were comparable with those used in the manufacture of blue mould‐ripened cheese. The commercial lipase was selected to compare with the fungal strains in terms of acyl migration. Results showed that the main isomers formed by lipolysis with the commercial lipase were sn‐2 MAGs (64 mol%), whilst spores and emerging mycelia of P roquefortii produced mainly sn‐1(3) MAGs (83–90 mol%). The work reported here may lead to further assessment of different MAG structural isomers as natural preservatives in foods and dairy products. © 2002 Society of Chemical Industry     

液化天然气供气站的工艺设计

〗LNG供气站的设计核心是工艺设计，设计中应注意以下几点：正确处理技术先进性与经济合理性的关系，综合权衡设置费与运营费的比例，力求项目全寿命费用最低；大多数城市LNG供气站均利用空气气化LNG，单罐容积为100 m³的真空压力式储罐广泛用于储存量为1200 m³以下的LNG供气站；为正确设置储罐安全阀的开启压力和排放压力，必须根据储罐的最高工作压力按照规范正确确定储罐的设计压力；储罐上2套独立的液位计和高、低限报警自动切断装置可确保储罐安全运行；空温式气化器的气化能力按用气城市高峰小时计算流量的1.3~1.5倍确定，为便于自然化霜应设置2套空温式气化器切换使用；空温式气化器出口串接水浴式加热器可提高冬季或雨天出口天然气温度，保护碳钢管道并降低供销差；LNG储罐区应设置围堰，消防用水量为喷淋与水枪用水量之和。最后建议，必须尽快颁布国家LNG设计规范，以提高我国的LNG设计水平。     

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本文应用天然气中甲烷、乙烷的碳同位素,甲烷的氢同位素,汞含量及天然气成分等指标,探讨了四川盆地天然气成因分类;并结合地质情况对气源层进行了探讨。     

Numerical modelling of the propagation of fast landslides using the finite element method

This paper proposes a two‐dimensional (2D) model for the analysis of the propagation of fast landslides involving a fluidized material such as debris and mud flows, flowslides and avalanching flows. The model is based on the Navier–Stokes depth‐integrated equations. To incorporate the effect of steep slopes and centrifugal forces due to the high velocities characterizing the flowslides and the bed curvature, a curvilinear system of reference is used. The corresponding equations of motion are complemented by depth‐averaged constitutive equations and bed friction laws. The resulting set of differential equations are solved using the two‐step Taylor–Galerkin algorithm. This algorithm has been used by the authors to solve hydraulic and dam‐break problems using the finite element method. Owing to the importance of the source term compared to the advection component, the proposed algorithm follows a splitting scheme using a fourth‐order Runge–Kutta method for integrating the friction and slope components. The performance of the overall approach has been checked in a number of examples. The analysis of the results provides insights into the key elements of the model and shows the adequacy of the method to solve real problems where merging and splitting of the flow occur. Copyright © 2004 John Wiley & Sons, Ltd.     

超声波流量计计量系统性能的主要影响因素

随着我国天然气工业的发展，已有大量超声波流量计用于高压、大流量的天然气计量。尽管我国已于2001年颁布并实施了气体超声波流量计使用方面的国家标准GB/T18604-2001，但是随着超声波流量计越来越广泛的使用，国内外对超声波流量计计量性能的影响因素已有了进一步的研究；而且，目前我国超声波流量计在天然气计量中的应用效果也还需要进一步改善。因此，根据目前国、内外最新研究成果，对噪声、脏污、压力及温度测量对超声波流量计计量系统性能的主要影响因素以及控制对策进行了分析探讨，以期改变虽经实验室检定合格、但用于现场却不能达到预期计量性能效果的情况，使超声波流量计在现场能够得到更好的应用。     

生态平衡的伦理学意蕴解读

20世纪以来，人类采用技术工程治理、法律制裁和经济惩罚等措施，一定意义上改善了局部的生态环境，但是未能遏制住全球环境问题的恶化态势。生态危机的根本解决，关键在于人类自身必须进行深刻的利益观念和价值观念的变革。重新审视人与自然界的关系，对自然进行伦理关怀，寻求和建立以保护地球环境和人类生存与可持续发展的生态平衡理念。     

库车坳陷北带断裂输导天然气效率评价

在断裂输导天然气能力影响因素分析基础上,建立了断裂输导天然气能力评价参数.利用此评价参数对中国24个以断裂为主要输导通道的大中型气田断裂输导天然气能力进行了研究,并通过其天然气聚集效率和断裂输导天然气能力评价参数之间的关系研究得到:高效、中效和低效断裂输导天然气能力评价参数值应分别为大于250×10-4、250×10-4～25×10-4和小于25×10-4.根据库车坳陷北带断裂输导特征,对其下白垩统顶部断裂输导天然气效率进行了研究,得到库车坳陷北带下白垩统顶部高效断裂输导天然气区主要分布在大北1井周围、克拉1、2、3、4井周围和东秋5井-迪那2-依南2井周围3个地区,中、低效断裂输导天然气区围绕高效断裂输导天然气区分布.目前在该区发现的5个气田皆分布在高效断裂输导天然气分布区,表明高效断裂输导应是库车坳陷北带天然气成藏的重要条件.     

Effect of surfactants and liquid hydrocarbons on gas hydrate formation rate and storage capacity

Hydrate formation rate plays an important role in making hydrates for the storage and transport of natural gas. Micellar surfactant solutions were found to increase gas hydrate formation rate and storage capacity. With the presence of surfactant, hydrate could form quickly in a quiescent system and the energy costs of hydrate formation reduced. Surfactants (an anionic surfactant, a non‐ionic surfactant and their mixtures) and liquid hydrocarbons (cyclopentane and methylcyclohexane) were used to improve hydrate formation. The experiments of hydrate formation were carried out in the pressure range 3.69–6.82 MPa and the temperature range 274.05–277.55 K. The experimental pressures were kept constant during hydrate formation in each experimental run. The effect of anionic surfactant (sodium dodecyl sulphate (SDS)) on natural gas storage in hydrates is more pronounced compared to a non‐ionic surfactant (dodecyl polysaccharide glycoside (DPG)). The induction time of hydrate formation was reduced with the presence of cyclopentane (CP). Cyclopentane and methylcyclohexane (MCH) could increase hydrate formation rate, but reduced hydrate storage capacity The higher methylcyclohexane concentration, the lower the hydrate storage capacity. Copyright © 2003 John Wiley & Sons, Ltd.     

Preparation and Properties of Rare Earth Modified Carbon Black/Natural Rubber Composites

The oxides Eu, Ho, Er and Dy were used to prepare the hydroxides of rare earth modified carbon black. Then natural rubber latex （NRL） was added into the reactor. The system reacted at 85 ℃ with stirring for 1 h to prepare powdered HAF-Ln（OH）3/NR composites. The effects of the kind and content of Ln on the particle size distribution of P [ NR/HAF-Ln （OH）3 ] and mechanical properties of its vulcanizate were studied respectively. It is found that rare earth can help to get the powder of the composite, the product particle with a diameter less than 0.9mm will be get when the composites containing the compound of Ho, Er and Dy with dosage of 1.0, 1.0, O. 5 percent, respectively. The adding of Ln can improve the tensile strength and tear strength of the vulcanizate effectively, what＇s more, Er and Dy can decrease the permanent set of vulcanizate significantly. The SEM studies shows that P[ NR/HAF-Dy （OH）3 ] vulcanizate shows superior mechanical properties that depend primarily on the absence of free carbon black, the fine dispersion of carbon black in the rubber matrix and better polymer-filler interaction.     

Performance of natural‐fiber–plastic composites under stress for outdoor applications: Effect of moisture,temperature, and ultraviolet light exposure

The effects of moisture, temperature, and ultraviolet (UV) light on performance of natural‐fiber–plastic composites (NFPC) were assessed. We conducted short‐term tests in the laboratory and long‐term tests under natural exposure and measured changes in mechanical properties and color in samples of the composite. Chemical changes of the composite's materials were measured by X‐ray photoelectron spectroscopy to elucidate the mechanisms of chemical transformations on the material surface. Relative humidity highly affected the modulus of rupture (MOR) and the modulus of elasticity (MOE), and had a greater effect than temperature and UV exposure on performance of the composite. The lightness of the composite was increased by the UV effect in the short‐ and the long‐term tests. The X‐ray photoelectron spectroscopy (XPS) analysis suggested that the composite was protected by the UV absorber. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 2570–2577, 2006